{ "ALIASES": [], "ANCILLARIES": { "hL": { "A": [ -39529.17244918648, 766.4862441651549, -8.72073120591565, 0.0584469082178831, -0.00018840687841603927, 8.952174605196958e-08, 9.753309913432768e-10, -1.8004523391706558e-12 ], "B": [ 1, -0.004360002461028179 ], "Tmax": 227.41, "Tmin": 120.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 72.86598917025731, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -14829.4949808947, 1469.0894624632112, -32.57524816765149, 0.3698709215006086, -0.0024638309242990147, 9.685143148916862e-06, -2.086112266671322e-08, 1.9067862669238816e-11 ], "B": [ 1, -0.0043580233375961255 ], "Tmax": 227.41, "Tmin": 120.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 147.2538481706497, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 227.51, "Tmax": 227.5, "Tmin": 120.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.002282347612714286, "n": [ 0.04320524355479352, -0.08138636451472522, 0.14428668233243508, -1.587068436457817, -4.5171616562403365, -2.7541765705090198 ], "reducing_value": 3750000.0, "t": [ 0.058, 0.136, 0.36, 0.8333333333333334, 1.0, 3.8333333333333335 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 227.51, "Tmax": 227.5, "Tmin": 120.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.007415329886240052, "n": [ 0.08662606349248056, -0.0813486384851997, -7.785956892747065, 1.8982297803059163, -2.3849179775668956, -1.1791347960249259 ], "reducing_value": 3750000.0, "t": [ 0.07100000000000001, 0.082, 1.0, 1.1666666666666667, 3.5, 6.833333333333333 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 227.51, "Tmax": 227.5, "Tmin": 120.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.008033101254423247, "n": [ 129.2110005451294, 8780.472954819723, -3507.774533268308, -5406.157576410963, 6.638240696847442, 0.27973697758760946 ], "reducing_value": 7109.419400000001, "t": [ 0.055, 0.111, 0.1, 0.117, 0.39499999999999996, 2.5 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 227.51, "Tmax": 227.5, "Tmin": 120.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.01282821699449821, "n": [ -59.51239487319891, 74.31936386072647, -38153.79585178045, 48521.17526050439, -10387.203195536424, -4.015512941871523 ], "reducing_value": 7109.419400000001, "t": [ 0.1, 0.113, 0.373, 0.3755, 0.38449999999999995, 4.0 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -485.1184443597629, 13.991104074458953, -0.20653313187966446, 0.0018027227267794455, -9.502578854451281e-06, 2.9715130572758372e-08, -5.070616426205118e-11, 3.6180737155322254e-14 ], "B": [ 1, -0.0043582909820336305 ], "Tmax": 227.41, "Tmin": 120.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.33688104002431807, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 812.0646858368217, -20.044357508495647, 0.23574633252051216, -0.0015847685142849144, 6.085131156427458e-06, -1.1911545607402549e-08, 6.82142020479459e-12, 6.9621459328744455e-15 ], "B": [ 1, -0.0043573544587015185 ], "Tmax": 227.41, "Tmin": 120.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.6616879045922106, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 227.51, "a": [ 0.0423 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.24 ] } }, "CAS": "75-73-0", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": -1, "GWP100": 7390.0, "GWP20": 5210.0, "GWP500": 11200.0, "HH": -1, "Name": "R14", "ODP": -1.0, "PH": -1 }, "EOS": [ { "BibTeX_CP0": "Platzer-BOOK-1990", "BibTeX_EOS": "Platzer-BOOK-1990", "STATES": { "hs_anchor": { "T": 250.26100000000002, "T_units": "K", "hmolar": 30615.738111572387, "hmolar_units": "J/mol", "p": 6118662.656716034, "p_units": "Pa", "rhomolar": 6398.47746, "rhomolar_units": "mol/m^3", "smolar": 96.59960842471958, "smolar_units": "J/mol/K" }, "reducing": { "T": 227.51, "T_units": "K", "hmolar": 28516.561403186173, "hmolar_units": "J/mol", "p": 3750000, "p_units": "Pa", "rhomolar": 7109.4194, "rhomolar_units": "mol/m^3", "smolar": 89.25370815392982, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 120.0, "T_units": "K", "hmolar": 16549.553703538702, "hmolar_units": "J/mol", "p": 11294.328999961177, "p_units": "Pa", "rhomolar": 19669.032618774767, "rhomolar_units": "mol/m^3", "smolar": 23.955020384298734, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 120.0, "T_units": "K", "hmolar": 29449.987374662433, "hmolar_units": "J/mol", "p": 11294.387368850012, "p_units": "Pa", "rhomolar": 11.391298650498788, "rhomolar_units": "mol/m^3", "smolar": 131.45859164284022, "smolar_units": "J/mol/K" } }, "T_max": 623, "T_max_units": "K", "Ttriple": 89.54, "Ttriple_units": "K", "accentric": 0.1785, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 227.51, "c": [ 3.946282613411975, -0.008858129431283382, 0.0001393877086940782, -3.005436298807747e-07, 2.050274501811892e-10 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -14.8563435687485, "a2": 20.1558709204447, "reference": "OTH", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ 1.03999039734947, -2.4579202542559, 0.799614558381524, -0.749498955282594, 0.152177772596398, -0.293408332036298, 0.717794503774445, -0.0426467444751902, 0.226562749725952, -0.39109169477402, -0.0257394805543082, 0.0554844886106659, 0.00610988262947185, -0.33469874882651, 0.586690904512625, -0.147068929694523 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 0.99832625, 0.99832625, 0.99832625, 0.99832625, 0.99832625, 0.99832625 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ -0.190315426348019, 0.716157134745809, -0.703161905301754, 0.33469874882651, -0.586690904512625, 0.147068929694523 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "critical_region_splines": { "T_max": 227.51, "T_min": 226.4221608783466, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ -3.276091146712226e-11, 4.7283262023474423e-07, -0.0017555435908659005, 227.86433767755432 ], "cV": [ 4.0498841128300184e-11, -1.0634186146259112e-06, 0.008979676508857887, 202.86623067561814 ], "rhomolar_max": 9048.167089998266, "rhomolar_min": 5136.725032287401 }, "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.0880046, "molar_mass_units": "kg/mol", "p_max": 51000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R14", "REFPROP_NAME": "R14", "STATES": { "critical": { "T": 227.51, "T_units": "K", "p": 3750000.0, "p_units": "Pa", "rhomolar": 7109.4194, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 120.0, "T_units": "K", "hmolar": 16549.553703538702, "hmolar_units": "J/mol", "p": 11294.328999961177, "p_units": "Pa", "rhomolar": 19669.032618774767, "rhomolar_units": "mol/m^3", "smolar": 23.955020384298734, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 120.0, "T_units": "K", "hmolar": 29449.987374662433, "hmolar_units": "J/mol", "p": 11294.387368850012, "p_units": "Pa", "rhomolar": 11.391298650498788, "rhomolar_units": "mol/m^3", "smolar": 131.45859164284022, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Huber-IECR-2003", "f_int": { "T_reducing": 1.0, "T_reducing_units": "K", "a": [ 0.00119864, 1.90048e-07 ], "t": [ 0, 1 ] }, "psi": { "a": [ 1.0442, 0.0 ], "rhomolar_reducing": 7109.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "q_D": 4413724919.008148, "q_D_units": "m", "reference_fluid": "Nitrogen", "type": "ECS" }, "viscosity": { "BibTeX": "Huber-IECR-2003", "epsilon_over_k": 164.44, "epsilon_over_k_units": "K", "psi": { "a": [ 1.10941, -0.0630268, 0.0 ], "rhomolar_reducing": 7109.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1, 2 ] }, "reference_fluid": "Nitrogen", "sigma_eta": 4.543e-10, "sigma_eta_units": "m", "type": "ECS" } } }