{ "ANCILLARIES": { "hL": { "A": [ -50841.33322557986, -132.5417805049068, 3.458693990299631, -0.019551144702783244, 6.18806277382768e-05, -1.1652802244190162e-07, 1.209099525332497e-10, -5.359410246559582e-14 ], "B": [ 1, -0.002098055760926937 ], "Tmax": 470.96, "Tmin": 162.68, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 376.1921397746819, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 22529.799273566194, 285.57717288283146, -4.237596491274551, 0.024367440141361194, -7.970383920906044e-05, 1.530492608930979e-07, -1.617923180699034e-10, 7.355822431190102e-14 ], "B": [ 1, -0.002095861642444481 ], "Tmax": 470.96, "Tmin": 162.68, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 753.0558075012577, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pS": { "T_r": 471.06, "Tmax": 471.05, "Tmin": 162.68, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.025840508063401657, "n": [ 0.002488999538674866, 0.17252290950983326, -6.293222945340061, -0.07387863714475532, -3.286105292292795, 2.274584153170513 ], "reducing_value": 4394000.0, "t": [ 0.002, 0.901, 0.973, 2.808, 4.144, 16.732 ], "type": "pL", "using_tau_r": true }, "rhoL": { "T_r": 471.06, "Tmax": 471.05, "Tmin": 162.68, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.032682517991688975, "n": [ 0.1369999075358185, 2.5657629003804248, -0.5933415750742217, 0.7576689326270665, -0.21901132344678031, 0.21836410566455441 ], "reducing_value": 4113.0394269407725, "t": [ 0.128, 0.465, 0.948, 1.743, 2.364, 7.362 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 471.06, "Tmax": 471.05, "Tmin": 162.68, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.1730324085996715, "n": [ -0.19338479907103712, 20.681546570974632, -24.441568955282317, -1.761137580982086, -9.939134168011334, 7.889769508867816 ], "reducing_value": 4113.0394269407725, "t": [ 0.078, 0.408, 0.422, 1.519, 5.592, 7.237 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -271.0095848375113, 1.1060296729463122, 0.003590965795991407, -4.430954717863458e-05, 1.7476315792923916e-07, -3.6335044518362377e-10, 3.965253966966378e-13, -1.7976775795849226e-16 ], "B": [ 1, -0.002102901184744149 ], "Tmax": 470.96, "Tmin": 162.68, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.7147189806249532, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 947.9264016357921, -12.590301232522643, 0.08346172632182036, -0.0003362423583102211, 8.530939676743401e-07, -1.3351045443501557e-09, 1.1786285055586815e-12, -4.481347029775152e-16 ], "B": [ 1, -0.0020882238729846023 ], "Tmax": 470.96, "Tmin": 162.68, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.8122024441780393, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 471.11, "a": [ 0.06212 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.247 ] } }, "EOS": [ { "BibTeX_CP0": "Jacobsen-FPE-1992", "BibTeX_EOS": "Jacobsen-FPE-1992", "STATES": { "hs_anchor": { "T": 518.221, "T_units": "K", "hmolar": 65131.11263418206, "hmolar_units": "J/mol", "p": 7090353.600671449, "p_units": "Pa", "rhomolar": 3629.6658, "rhomolar_units": "mol/m^3", "smolar": 230.09864593329712, "smolar_units": "J/mol/K" }, "reducing": { "T": 471.11, "T_units": "K", "hmolar": 58886.42675151331, "hmolar_units": "J/mol", "p": 4394000, "p_units": "Pa", "rhomolar": 4032.962, "rhomolar_units": "mol/m^3", "smolar": 218.87355768891422, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 162.68, "T_units": "K", "hmolar": 15035.44175882879, "hmolar_units": "J/mol", "p": 6.510089834177898, "p_units": "Pa", "rhomolar": 12874.405675061947, "rhomolar_units": "mol/m^3", "smolar": 79.29963464992309, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 162.68, "T_units": "K", "hmolar": 46276.015756172055, "hmolar_units": "J/mol", "p": 6.510089834177898, "p_units": "Pa", "rhomolar": 0.004813357080234425, "rhomolar_units": "mol/m^3", "smolar": 271.3365798363174, "smolar_units": "J/mol/K" } }, "T_max": 625, "T_max_units": "K", "Ttriple": 162.68, "Ttriple_units": "K", "acentric": 0.1887506482528083, "acentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298, "Tc": 471.11, "cp_over_R": 4.00564923248634, "type": "IdealGasHelmholtzCP0Constant" }, { "T0": 298, "Tc": 471.11, "c": [ 0.0002228874581905608 ], "t": [ 1 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "n": [ 1, 2, 1, 2, 1, 2 ], "t": [ 3.313613168898983, 2.586756086688884, 1.634512228566577, 1.215500498821931, 1.06738046316147, 0.7360191462715714 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -20.0312014458899, "a2": 12.6387040144928, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 2, 3, 3, 4, 4, 5, 5, 5, 6, 8, 1, 1, 2, 2, 2, 3, 4, 6, 10, 3, 5, 8, 9, 9 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 2, 2, 2, 2, 2, 2, 2, 2, 2, 4, 6, 6, 6, 6 ], "n": [ 1.25993633881, -2.60818574641, 0.00982122542463, -1.06085385839, 1.2282036351, 0.118000776439, -0.000698956926463, -0.0355428373358, 0.00197169579643, -0.00848363012252, 0.00417997567653, -0.000242772533848, 0.00313371368974, 3.96182646586e-06, 0.339736319502, -0.203010634531, -0.1060178599, 0.45156488259, -0.339265767612, 0.114338523359, 0.0319537833995, 0.036790825978, -9.61768948364e-06, 0.00246717966418, -0.00167030256045, 0.00240710110806, 0.00156214678738, -0.00323352596704 ], "t": [ 0.5, 1.5, 5, 1, 1.5, 0, 5, 2, 3, 1, 2, 4, 1, 4, 5, 6, 3.5, 5.5, 7.5, 3, 2.5, 5, 1.5, 11, 9, 13, 5, 9 ], "type": "ResidualHelmholtzPower" } ], "critical_region_splines": { "T_max": 471.06, "T_min": 471.059233646828, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -4.043954354486559e-06, 471.07663294370076 ], "cV": [ 0.0, 0.0, 2.3593786652777144e-06, 471.05029578252663 ], "rhomolar_max": 4302.545317673531, "rhomolar_min": 3788.227991064693 }, "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.137368, "molar_mass_units": "kg/mol", "p_max": 100000000, "p_max_units": "Pa", "pseudo_pure": false }, { "BibTeX_CP0": "Jacobsen-FPE-1992", "BibTeX_EOS": "Span-IJT-2003C", "STATES": { "reducing": { "T": 471.06, "T_units": "K", "hmolar": 58731.15320314559, "hmolar_units": "J/mol", "p": 4394000, "p_units": "Pa", "rhomolar": 4113.039426940773, "rhomolar_units": "mol/m^3", "smolar": 218.54567014707027, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 162.68, "T_units": "K", "p": 0.006691548080564487, "p_units": "Pa", "rhomolar": 12962.580254202647, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 162.68, "T_units": "K", "p": 0.006691548080564487, "p_units": "Pa", "rhomolar": 0.0049471885961455235, "rhomolar_units": "mol/m^3" } }, "T_max": 625, "T_max_units": "K", "Ttriple": 162.68, "Ttriple_units": "K", "acentric": 0.1887506482528083, "acentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298, "Tc": 471.11, "cp_over_R": 4.00564923248634, "type": "IdealGasHelmholtzCP0Constant" }, { "T0": 298, "Tc": 471.11, "c": [ 0.0002228874581905608 ], "t": [ 1 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "n": [ 1, 2, 1, 2, 1, 2 ], "t": [ 3.313613168898983, 2.586756086688884, 1.634512228566577, 1.215500498821931, 1.06738046316147, 0.7360191462715714 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -19.9828934089637, "a2": 12.619996028432, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 3, 7, 1, 2, 5, 1, 1, 4, 2 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 2, 2, 2, 3 ], "n": [ 1.0656383, -3.2495206, 0.87823894, 0.087611569, 0.00029950049, 0.42896949, 0.70828452, -0.017391823, -0.37626522, 0.011605284, -0.089550567, -0.030063991 ], "t": [ 0.25, 1.25, 1.5, 0.25, 0.875, 2.375, 2, 2.125, 3.5, 6.5, 4.75, 12.5 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.137368, "molar_mass_units": "kg/mol", "p_max": 100000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=6149", "ALIASES": [], "CAS": "75-69-4", "CHEMSPIDER_ID": 6149, "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 1, "GWP100": 4750.0, "GWP20": 6730.0, "GWP500": 1620.0, "HH": 1, "Name": "R11", "ODP": 1.0, "PH": 0 }, "FORMULA": "C_{1}Cl_{3}F_{1}", "INCHI_KEY": "CYRMSUTZVYGINF-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/CCl3F/c2-1(3,4)5", "NAME": "R11", "REFPROP_NAME": "R11", "SMILES": "C(F)(Cl)(Cl)Cl" }, "STATES": { "critical": { "T": 471.06, "T_units": "K", "hmolar": 58726.18234222236, "hmolar_units": "J/mol", "p": 4394000.0, "p_units": "Pa", "rhomolar": 4113.0394269407725, "rhomolar_units": "mol/m^3", "smolar": 218.53673209367506, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 162.68, "T_units": "K", "hmolar": 15035.44175882879, "hmolar_units": "J/mol", "p": 6.510089834177898, "p_units": "Pa", "rhomolar": 12874.405675061947, "rhomolar_units": "mol/m^3", "smolar": 79.29963464992309, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 162.68, "T_units": "K", "hmolar": 46276.015756172055, "hmolar_units": "J/mol", "p": 6.510089834177898, "p_units": "Pa", "rhomolar": 0.004813357080234425, "rhomolar_units": "mol/m^3", "smolar": 271.3365798363174, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "McLinden-IJR-2000", "f_int": { "T_reducing": 1.0, "T_reducing_units": "K", "a": [ 0.0014 ], "t": [ 0 ] }, "psi": { "a": [ 1.0724, -0.022672 ], "rhomolar_reducing": 4032.962, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "q_D": 1999999999.9999998, "q_D_units": "m", "reference_fluid": "R134a", "type": "ECS" }, "viscosity": { "BibTeX": "Klein-IJR-1997", "epsilon_over_k": 363.61, "epsilon_over_k_units": "K", "psi": { "a": [ 1.171, -0.0592 ], "rhomolar_reducing": 4032.962, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "reference_fluid": "R134a", "sigma_eta": 5.447e-10, "sigma_eta_units": "m", "type": "ECS" } } }