{ "ANCILLARIES": { "hL": { "A": [ -43449.07410119944, 213.1260789486956, -0.1621225972975116, -0.0019815760230164946, 1.3632677369658302e-05, -4.4492478844355654e-08, 7.329895102645116e-11, -5.0389419188956387e-14 ], "B": [ 1, -0.002707029026648199 ], "Tmax": 364.111, "Tmin": 87.953, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 242.41546040908725, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 28438.115081306332, -82.14137089960388, -0.925630290843053, 0.010862874538450237, -5.7435584451115496e-05, 1.6664298300451552e-07, -2.57458516201508e-10, 1.6831999323158112e-13 ], "B": [ 1, -0.0027056535081215172 ], "Tmax": 364.111, "Tmin": 87.953, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 553.9157403966058, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "Reeves-JCP-1964", "T_m": 88.05999999999997, "_note": "Modified coefficients to make minimum state agree with triple point", "parts": [ { "T_0": 87.953, "T_max": 129, "T_min": 87.953, "a": 319600000.0, "c": 2.821, "p_0": 0.0007471728686974104 }, { "T_0": 109.6, "T_max": 145.3, "T_min": 129, "a": 306400000.0, "c": 3.871, "p_0": 445000000.0 } ], "type": "Simon" }, "pS": { "T_r": 364.211, "Tmax": 364.2109999999991, "Tmin": 87.95300000000002, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02358382509746182, "n": [ -6.15754746767542, 0.8043847738472081, -2.629218877933464, -20.055797246021456, 23.93889034404838, -5.927221357425409 ], "reducing_value": 4555000.0, "t": [ 0.985, 1.914, 3.354, 8.871, 9.472, 12.201 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 364.211, "Tmax": 364.2109999999991, "Tmin": 87.95300000000002, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.15187793211883793, "n": [ 1.1500616940414559, 0.7037673936905474, 0.6950815609799416, 1.8850870474961088, -2.1702211585216302, 2.21238242151199 ], "reducing_value": 5457.0, "t": [ 0.286, 0.521, 0.701, 5.657, 6.864, 15.279 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 364.211, "Tmax": 364.2109999999991, "Tmin": 87.95300000000002, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.931595165746768, "n": [ -5.13562614673855, 4.2053374767917395, -8.021462611933476, 4.971018368148577, -4.664302402572978, -1.7964631156271889 ], "reducing_value": 5457.0, "t": [ 0.42, 0.56, 1.051, 1.479, 3.598, 16.862 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -330.29345430748015, 4.474061492592662, -0.03653294079021332, 0.00020407925887916563, -7.416256704980198e-07, 1.6682068981045696e-09, -2.1125614801394966e-12, 1.1487831725277089e-15 ], "B": [ 1, -0.002678059496800993 ], "Tmax": 364.111, "Tmin": 87.953, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.8619163751196712, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1209.3598590436613, -25.536345223765522, 0.2708371575305057, -0.0017198894428695453, 6.7652125945527675e-06, -1.6161377016041794e-08, 2.148962075653635e-11, -1.2197694672184799e-14 ], "B": [ 1, -0.002531373243792789 ], "Tmax": 364.111, "Tmin": 87.953, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.8299697075697434, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 364.211, "a": [ 0.05268 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.186 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Lemmon-PROPYLENE-2013", "STATES": { "hs_anchor": { "T": 400.63210000000004, "T_units": "K", "hmolar": 26645.377075672735, "hmolar_units": "J/mol", "p": 7310423.5406166725, "p_units": "Pa", "rhomolar": 4911.3, "rhomolar_units": "mol/m^3", "smolar": 93.4240661363609, "smolar_units": "J/mol/K" }, "reducing": { "T": 364.211, "T_units": "K", "hmolar": 22351.811824531174, "hmolar_units": "J/mol", "p": 4555000, "p_units": "Pa", "rhomolar": 5457, "rhomolar_units": "mol/m^3", "smolar": 83.56799538032779, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 87.953, "T_units": "K", "hmolar": -8389.974818153365, "hmolar_units": "J/mol", "p": 0.0007469480313533406, "p_units": "Pa", "rhomolar": 18254.562780551245, "rhomolar_units": "mol/m^3", "smolar": -59.75246708119243, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 87.953, "T_units": "K", "hmolar": 16247.981438019186, "hmolar_units": "J/mol", "p": 0.0007469480313533406, "p_units": "Pa", "rhomolar": 1.0217291002947073e-06, "rhomolar_units": "mol/m^3", "smolar": 220.37392151467708, "smolar_units": "J/mol/K" } }, "T_max": 575, "T_max_units": "K", "Ttriple": 87.953, "Ttriple_units": "K", "acentric": 0.146, "acentric_units": "-", "alpha0": [ { "a1": 4.9916462, "a2": -0.1709449, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 1.544, 4.013, 8.923, 6.02 ], "t": [ 0.8895942187358427, 2.671528317376466, 5.304617378387802, 11.85301926630442 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -10.1739741651451, "a2": 4.53493517654279, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 4, 1, 1, 2, 2, 3, 1, 1, 3, 2, 2, 8 ], "l": [ 0, 0, 0, 0, 0, 0, 1, 2, 2, 1, 2, 1 ], "n": [ 0.04341002, 1.136592, -0.8528611, 0.5216669, -1.382953, 0.1214347, -0.5984662, -1.391883, -1.008434, 0.1961249, -0.360693, -0.002407175 ], "t": [ 1, 0.205, 0.56, 0.676, 1, 0.5, 1, 1.94, 2, 1, 2.66, 0.83 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 0.77, 0.83, 0.607, 0.4, 0.66, 0.07, 3.1, 387, 41 ], "d": [ 1, 1, 2, 3, 3, 2, 1, 2, 3 ], "epsilon": [ 0.78, 0.82, 1.94, 0.69, 1.96, 1.3, 0.38, 0.91, 0.7 ], "eta": [ 1.07, 0.66, 1.2, 1.12, 1.47, 1.93, 3.3, 15.4, 6 ], "gamma": [ 1.21, 1.08, 0.83, 0.56, 1.22, 1.81, 1.54, 1.12, 1.4 ], "n": [ 0.7432121, 0.1475162, -0.02503391, -0.2734409, 0.006378889, 0.0150294, -0.03162971, -0.04107194, -1.190241 ], "t": [ 1.6, 2.5, 3, 2.5, 2.72, 4, 4, 1, 4 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 364.211, "T_min": 364.21077733486237, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -3.6652101077273866e-06, 364.2310010515579 ], "cV": [ 0.0, 0.0, 3.951799999729862e-06, 364.1894350274015 ], "rhomolar_max": 5517.750988646923, "rhomolar_min": 5400.654755394478 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.04207974, "molar_mass_units": "kg/mol", "p_max": 1000000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=7954", "ALIASES": [ "propylene", "PROPYLENE", "PROPYLEN", "R1270" ], "CAS": "115-07-1", "CHEMSPIDER_ID": 7954, "ENVIRONMENTAL": { "ASHRAE34": "A3", "FH": 4, "GWP100": 3.1, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "Propylene", "ODP": -1.0, "PH": 1 }, "FORMULA": "C_{3}H_{6}", "INCHI_KEY": "QQONPFPTGQHPMA-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/C3H6/c1-3-2/h3H,1H2,2H3", "NAME": "Propylene", "REFPROP_NAME": "PROPYLEN", "SMILES": "CC=C" }, "STATES": { "critical": { "T": 364.211, "T_units": "K", "hmolar": 22348.096116413064, "hmolar_units": "J/mol", "p": 4555000.0, "p_units": "Pa", "rhomolar": 5457.0, "rhomolar_units": "mol/m^3", "smolar": 83.55933414502688, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 87.953, "T_units": "K", "hmolar": -8389.974818153365, "hmolar_units": "J/mol", "p": 0.0007469480313533406, "p_units": "Pa", "rhomolar": 18254.562780551245, "rhomolar_units": "mol/m^3", "smolar": -59.75246708119243, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 87.953, "T_units": "K", "hmolar": 16247.981438019186, "hmolar_units": "J/mol", "p": 0.0007469480313533406, "p_units": "Pa", "rhomolar": 1.0217291002947073e-06, "rhomolar_units": "mol/m^3", "smolar": 220.37392151467708, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Huber-IECR-2003", "f_int": { "T_reducing": 1.0, "T_reducing_units": "K", "a": [ 0.00109939, 3.72539e-07 ], "t": [ 0, 1 ] }, "psi": { "a": [ 1.3521, -0.123177 ], "rhomolar_reducing": 5309.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "q_D": 1999999999.9999998, "q_D_units": "m", "reference_fluid": "Propane", "type": "ECS" }, "viscosity": { "BibTeX": "Huber-IECR-2003", "epsilon_over_k": 298.9, "epsilon_over_k_units": "K", "psi": { "a": [ 1.33962, -0.256307, 0.0468211 ], "rhomolar_reducing": 5309.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1, 2 ] }, "reference_fluid": "Propane", "sigma_eta": 4.678e-10, "sigma_eta_units": "m", "type": "ECS" } } }