{ "ANCILLARIES": { "hL": { "A": [ -55668.8090852956, 368.35001041805685, -1.715364074375054, 0.007769512340061115, -2.2428609487675068e-05, 3.3867519869140485e-08, -2.0633816276371996e-11, -1.471962594571584e-15 ], "B": [ 1, -0.002565097105751381 ], "Tmax": 385.02, "Tmin": 116.099, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 327.6380858693019, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 35799.34068934325, -181.02878811870056, -0.05013739835442652, 0.0059327247423719654, -3.9223538313429226e-05, 1.2287857719267456e-07, -1.9486260882896318e-10, 1.274176769532928e-13 ], "B": [ 1, -0.0025639656315226606 ], "Tmax": 385.02, "Tmin": 116.099, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 673.8180560738604, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pS": { "T_r": 385.12, "Tmax": 385.11999999999927, "Tmin": 116.09900000000002, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02538001083745023, "n": [ -0.4180899251614923, -6.821426208906223, 1.4450198472690974, -1.4837613030063526, -2.1731387101462754, -5.72739817030707 ], "reducing_value": 4136100.0000000005, "t": [ 0.894, 1.009, 1.274, 3.0, 4.927, 19.696 ], "type": "pL", "using_tau_r": true }, "rhoL": { "T_r": 385.12, "Tmax": 385.11999999999927, "Tmin": 116.09900000000002, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.729903640409435, "n": [ 2.6029953147390845, -1.289157172326326, 1.8650658616334526, -0.7403291941448226, 24.389351468278143, -67.79326638866661 ], "reducing_value": 4672.781255944357, "t": [ 0.391, 0.803, 1.301, 2.566, 12.555, 16.134 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 385.12, "Tmax": 385.11999999999927, "Tmin": 116.09900000000002, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.21720112949432657, "n": [ -7.9660647155295505, 23.959910083444367, -23.82796401904973, 3.215927599962643, -4.437766797843962, -3.5598094489847374 ], "reducing_value": 4672.781255944357, "t": [ 0.499, 0.743, 0.857, 1.368, 3.716, 14.833 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -399.34791705934134, 5.568361636769254, -0.046339875196142286, 0.00025500224150949106, -8.895819206841682e-07, 1.8874920035422176e-09, -2.227593103042065e-12, 1.1207759500497982e-15 ], "B": [ 1, -0.002545252954245469 ], "Tmax": 385.02, "Tmin": 116.099, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.0495362933751515, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1189.8511472547534, -22.42705329174087, 0.20987736285672465, -0.0011743356947320875, 4.076570423366419e-06, -8.618976009734379e-09, 1.0177039909482674e-11, -5.145265776583788e-15 ], "B": [ 1, -0.00252398064665209 ], "Tmax": 385.02, "Tmin": 116.099, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.4871545581781467, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 385.12, "a": [ -0.000124, 0.05662 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 0.4318, 1.263 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Marx-BOOK-1992", "STATES": { "hs_anchor": { "T": 423.63200000000006, "T_units": "K", "hmolar": 46869.32316299001, "hmolar_units": "J/mol", "p": 6687504.662641632, "p_units": "Pa", "rhomolar": 4205.503130349922, "rhomolar_units": "mol/m^3", "smolar": 183.2184179764191, "smolar_units": "J/mol/K" }, "reducing": { "T": 385.12, "T_units": "K", "hmolar": 42052.91347915859, "hmolar_units": "J/mol", "p": 4136100.000000001, "p_units": "Pa", "rhomolar": 4672.781255944357, "rhomolar_units": "mol/m^3", "smolar": 172.70841305203066, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 116.099, "T_units": "K", "hmolar": 8020.442319444062, "hmolar_units": "J/mol", "p": 0.2425508006881145, "p_units": "Pa", "rhomolar": 15125.291310337965, "rhomolar_units": "mol/m^3", "smolar": 33.61931902572065, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 116.099, "T_units": "K", "hmolar": 34244.086028937934, "hmolar_units": "J/mol", "p": 0.2425509467011643, "p_units": "Pa", "rhomolar": 0.00025126989486966376, "rhomolar_units": "mol/m^3", "smolar": 259.4924162881792, "smolar_units": "J/mol/K" } }, "T_max": 525, "T_max_units": "K", "Ttriple": 116.099, "Ttriple_units": "K", "acentric": 0.1794783173435512, "acentric_units": "-", "alpha0": [ { "a1": 10.0100905, "a2": -4.66434985, "type": "IdealGasHelmholtzLead" }, { "a": 3.00361975, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 3.16062357, 0.371258136, 3.56226039, 2.12152336 ], "t": [ 3.72204562, 6.30985083, 1.78037889, 1.07087607 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -24.7279903483588, "a2": 14.0673715241366, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 4, 6, 8, 1, 1, 5, 7, 12, 12, 14, 1, 9, 1, 1, 3, 3, 5, 9 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 1, 2, 2, 3, 3, 3, 3, 3, 4 ], "n": [ 2.075343402, -2.962525996, 0.01001589616, 0.01781347612, 0.02556929157, 0.002352142637, -8.495553314e-05, -0.01535945599, -0.2108816776, -0.01654228806, -0.0118131613, -4.16029583e-05, 2.784861664e-05, 1.618686433e-06, -0.1064614686, 0.0009369665207, 0.02590095447, -0.04347025025, 0.1012308449, -0.1100003438, -0.003361012009, 0.0003789190008 ], "t": [ 0.5, 1, 2, 2.5, -0.5, 0, 0, -0.5, 1.5, 2.5, -0.5, 0, 0.5, -0.5, 4, 4, 2, 4, 12, 14, 0, 14 ], "type": "ResidualHelmholtzPower" } ], "critical_region_splines": { "T_max": 385.12, "T_min": 385.11941673548023, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -1.583911139375003e-05, 385.1940127028315 ], "cV": [ 0.0, 0.0, 1.5981068543804365e-05, 385.04532396245855 ], "rhomolar_max": 4709.605576782584, "rhomolar_min": 4636.284039366143 }, "gas_constant": 8.314471, "gas_constant_units": "J/mol/K", "molar_mass": 0.120913, "molar_mass_units": "kg/mol", "p_max": 200000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=6151", "ALIASES": [], "CAS": "75-71-8", "CHEMSPIDER_ID": 6151, "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 1, "GWP100": 10900.0, "GWP20": 11000.0, "GWP500": 5200.0, "HH": 1, "Name": "R12", "ODP": 1.0, "PH": 0 }, "FORMULA": "C_{1}Cl_{2}F_{2}", "INCHI_KEY": "PXBRQCKWGAHEHS-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/CCl2F2/c2-1(3,4)5", "NAME": "R12", "REFPROP_NAME": "R12", "SMILES": "C(F)(F)(Cl)Cl" }, "STATES": { "critical": { "T": 385.12, "T_units": "K", "hmolar": 42048.946785321656, "hmolar_units": "J/mol", "p": 4136100.000000001, "p_units": "Pa", "rhomolar": 4672.781255944357, "rhomolar_units": "mol/m^3", "smolar": 172.69971439232123, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 116.099, "T_units": "K", "hmolar": 8020.442319444062, "hmolar_units": "J/mol", "p": 0.2425508006881145, "p_units": "Pa", "rhomolar": 15125.291310337965, "rhomolar_units": "mol/m^3", "smolar": 33.61931902572065, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 116.099, "T_units": "K", "hmolar": 34244.086028937934, "hmolar_units": "J/mol", "p": 0.2425509467011643, "p_units": "Pa", "rhomolar": 0.00025126989486966376, "rhomolar_units": "mol/m^3", "smolar": 259.4924162881792, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "McLinden-IJR-2000", "f_int": { "T_reducing": 1.0, "T_reducing_units": "K", "a": [ 0.001344 ], "t": [ 0 ] }, "psi": { "a": [ 0.991, 0.0029509 ], "rhomolar_reducing": 4672.781255944357, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "q_D": 1999999999.9999998, "q_D_units": "m", "reference_fluid": "R134a", "type": "ECS" }, "viscosity": { "BibTeX": "Klein-IJR-1997", "epsilon_over_k": 297.24, "epsilon_over_k_units": "K", "psi": { "a": [ 1.087, -0.0379 ], "rhomolar_reducing": 4672.781255944357, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "reference_fluid": "R134a", "sigma_eta": 5.185999999999999e-10, "sigma_eta_units": "m", "type": "ECS" } } }