{ "ANCILLARIES": { "hL": { "A": [ -677.5566820079869, -72.92398390275562, 16.609312097081673, -1.3837940315364519, 0.06742689827780095, -0.0019430645463630017, 3.060467516625815e-05, -2.0463271502522004e-07 ], "B": [ 1, -0.02996809931467017 ], "Tmax": 32.838, "Tmin": 13.8033, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 1.8839993644426443, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 10.607308395792497, 259.1633993475281, -41.02588711557568, 3.3462403796894367, -0.1634621895314305, 0.004708622333181371, -7.401436900551199e-05, 4.933882008544239e-07 ], "B": [ 1, -0.029941023516880556 ], "Tmax": 32.838, "Tmin": 13.8033, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 4.195819745866146, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "Younglove-NIST-1982", "T_m": 18.9, "parts": [ { "T_0": 1, "T_max": 22, "T_min": 13.8033, "a": 125746.643, "c": 1.955, "p_0": -21155737.752 }, { "T_0": 1, "T_max": 170, "T_min": 22, "a": 248578.596, "c": 1.764739, "p_0": -26280332.904 } ], "type": "Simon" }, "pS": { "T_r": 32.938, "Tmax": 32.93799999999992, "Tmin": 13.80330000000001, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.0025443700352290044, "n": [ 0.1490037759465196, -4.78237888041144, 1.5087203071678434, -0.880650150281499, 1.2942713948220537, -0.3877150898692146 ], "reducing_value": 1285800.0, "t": [ 0.852, 0.986, 1.827, 2.355, 3.05, 4.286 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 32.938, "Tmax": 32.93799999999992, "Tmin": 13.80330000000001, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.37627402632863793, "n": [ 2.42209314197553, -0.8105757647156946, 5.292441752641816, -801.4099838859875, 965.4158391322754, -2288.927990716296 ], "reducing_value": 15538.0, "t": [ 0.44, 0.833, 4.399, 8.501, 8.893, 17.08 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 32.938, "Tmax": 32.93799999999992, "Tmin": 13.80330000000001, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.051284406798368654, "n": [ -5.1023908882756785, 15.472633152203006, -25.539938117401427, 65.8971290411631, -53.56192274807538, -9.178291109165437 ], "reducing_value": 15538.0, "t": [ 0.533, 1.001, 1.276, 1.876, 1.958, 19.379 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -44.89761432797228, 2.193501626086088, 0.10098980971112398, -0.018028663980638335, 0.0011206398323043688, -3.701101733434696e-05, 6.37275468698258e-07, -4.532701295182819e-09 ], "B": [ 1, -0.02997702917538759 ], "Tmax": 32.838, "Tmin": 13.8033, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.055560497640446016, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 268.0870537645356, -43.283947746671224, 3.6280263421215633, -0.18365321572831045, 0.005582885120039612, -9.667997745381358e-05, 8.178864846817653e-07, -1.9757515233710936e-09 ], "B": [ 1, -0.0299306854753526 ], "Tmax": 32.838, "Tmin": 13.8033, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.13255951581111702, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 32.938, "a": [ 0.005314 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.06 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Leachman-JPCRD-2009", "STATES": { "hs_anchor": { "T": 36.23180000000001, "T_units": "K", "hmolar": 731.8813437590998, "hmolar_units": "J/mol", "p": 1845255.86490887, "p_units": "Pa", "rhomolar": 13984.2, "rhomolar_units": "mol/m^3", "smolar": 22.240779970146143, "smolar_units": "J/mol/K" }, "reducing": { "T": 32.938, "T_units": "K", "hmolar": 596.0024943222866, "hmolar_units": "J/mol", "p": 1285800, "p_units": "Pa", "rhomolar": 15538, "rhomolar_units": "mol/m^3", "smolar": 19.40392694507545, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 13.8033, "T_units": "K", "hmolar": -108.33542133735936, "hmolar_units": "J/mol", "p": 7041.086751499288, "p_units": "Pa", "rhomolar": 38185.34690822164, "rhomolar_units": "mol/m^3", "smolar": -6.216955712330463, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 13.8033, "T_units": "K", "hmolar": 798.9167188838303, "hmolar_units": "J/mol", "p": 7041.087413598502, "p_units": "Pa", "rhomolar": 62.28041214271613, "rhomolar_units": "mol/m^3", "smolar": 59.51023485704393, "smolar_units": "J/mol/K" } }, "T_max": 1000, "T_max_units": "K", "Ttriple": 13.8033, "Ttriple_units": "K", "acentric": -0.219, "acentric_units": "-", "alpha0": [ { "a1": -1.4485891134, "a2": 1.884521239, "type": "IdealGasHelmholtzLead" }, { "a": 1.5, "type": "IdealGasHelmholtzLogTau" }, { "Tcrit": 32.938, "Tcrit_units": "K", "n": [ 4.30256, 13.0289, -47.7365, 50.0013, -18.6261, 0.993973, 0.536078 ], "type": "IdealGasHelmholtzPlanckEinsteinFunctionT", "v": [ 499, 826.5, 970.8, 1166.2, 1341.4, 5395, 10185 ] } ], "alphar": [ { "d": [ 1, 4, 1, 1, 2, 2, 3, 1, 3 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 1, 1 ], "n": [ -7.33375, 0.01, 2.60375, 4.66279, 0.68239, -1.47078, 0.135801, -1.05327, 0.328239 ], "t": [ 0.6855, 1, 1, 0.489, 0.774, 1.133, 1.386, 1.619, 1.162 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 0.194, 0.2019, 0.0301, 0.2383, 0.3253 ], "d": [ 2, 1, 3, 1, 1 ], "epsilon": [ 1.5487, 0.1785, 1.28, 0.6319, 1.7104 ], "eta": [ 1.7437, 0.5516, 0.0634, 2.1341, 1.777 ], "gamma": [ 0.8048, 1.5248, 0.6648, 0.6832, 1.493 ], "n": [ -0.0577833, 0.0449743, 0.0703464, -0.0401766, 0.11951 ], "t": [ 3.96, 5.276, 0.99, 6.791, 3.19 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 32.938, "T_min": 32.93599461397884, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 4.253205081213295e-12, -2.116493776473347e-07, 0.0034966692458426726, 13.749966028178376 ], "cV": [ -3.141534424322369e-12, 1.338646257848717e-07, -0.0018846003827776433, 41.68699310689614 ], "rhomolar_max": 15953.359013823481, "rhomolar_min": 15115.765516662266 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.00201588, "molar_mass_units": "kg/mol", "p_max": 2000000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "ALIASES": [ "Parahydrogen", "parahydrogen", "PARAHYDROGEN", "PARAHYD" ], "CAS": "1333-74-0p", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": -1, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": -1, "Name": "ParaHydrogen", "ODP": -1.0, "PH": -1 }, "NAME": "ParaHydrogen", "REFPROP_NAME": "PARAHYD" }, "STATES": { "critical": { "T": 32.938, "T_units": "K", "hmolar": 595.9457155385302, "hmolar_units": "J/mol", "p": 1285800.0, "p_units": "Pa", "rhomolar": 15538.0, "rhomolar_units": "mol/m^3", "smolar": 19.403419963711762, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 13.8033, "T_units": "K", "hmolar": -108.33542133735936, "hmolar_units": "J/mol", "p": 7041.086751499288, "p_units": "Pa", "rhomolar": 38185.34690822164, "rhomolar_units": "mol/m^3", "smolar": -6.216955712330463, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 13.8033, "T_units": "K", "hmolar": 798.9167188838303, "hmolar_units": "J/mol", "p": 7041.087413598502, "p_units": "Pa", "rhomolar": 62.28041214271613, "rhomolar_units": "mol/m^3", "smolar": 59.51023485704393, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Assael-JPCRD-2011-Hydrogen", "critical": { "GAMMA": 0.052, "R0": 1.01, "gamma": 1.2415, "qD": 2000000000.0, "type": "simplified_Olchowy_Sengers", "zeta0": 1.5e-10 }, "dilute": { "A": [ -1.245, 310.212, -331.004, 246.016, -65.781, 10.826, -0.519659, 0.0143979 ], "B": [ 14230.4, -19392.2, 15837.9, -4818.12, 728.639, -35.7365, 1.0 ], "T_reducing": 32.938, "T_reducing_units": "K", "m": [ 0, 1, 2, 3, 4, 5, 6 ], "n": [ 0, 1, 2, 3, 4, 5, 6, 7 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ 0.0265975, -0.00133826, 0.0130219, -0.00567678, -9.2338e-05, -0.00121727, 0.00366663, 0.00388715, -0.00921055, 0.00400723 ], "T_reducing": 32.938, "T_reducing_units": "K", "d": [ 1, 2, 3, 4, 5, 1, 2, 3, 4, 5 ], "rhomass_reducing": 31.32274344, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0, 0, -1, -1, -1, -1, -1 ], "type": "polynomial" } } } }