{ "ANCILLARIES": { "hL": { "A": [ 231587.64202195988, -7064.620260354418, 79.16613042816307, -0.47766976664107463, 0.0017192338210446272, -3.701275690807286e-06, 4.410205058962832e-09, -2.244329199846041e-12 ], "B": [ 1, -0.002702653004540113 ], "Tmax": 367.75, "Tmin": 220.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 165.7888625056321, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -570120.1484197119, 15147.697959307017, -165.61014120991328, 0.9958047945826846, -0.0035785199472005043, 7.689873720882333e-06, -9.151835132244599e-09, 4.656684588471939e-12 ], "B": [ 1, -0.0027000726699845175 ], "Tmax": 367.75, "Tmin": 220.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 402.5377116316065, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pS": { "T_r": 367.85, "Tmax": 367.8499999999992, "Tmin": 220.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.006853694086594864, "n": [ 0.21867168915151047, -6.7020534970313275, -3.9344883544124443, 39309.745547798695, 18.183182049398066, -3883.103380695622 ], "reducing_value": 3382200.0, "t": [ 0.728, 0.961, 3.78, 17.277, 7.967, 14.02 ], "type": "pL", "using_tau_r": true }, "rhoL": { "T_r": 367.85, "Tmax": 367.8499999999992, "Tmin": 220.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.3992123482188248, "n": [ 2.321825326575359, -3.520638555089873, 20.18646332917161, -160.37050775728997, 147.68109685289284, -63578.64918999199 ], "reducing_value": 4170.0, "t": [ 0.365, 1.247, 1.765, 2.484, 2.593, 16.586 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 367.85, "Tmax": 367.8499999999992, "Tmin": 220.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.332050058237221, "n": [ -3.24158284550283, 2.612924555839616, -26.216566273272992, 115.70400813769207, -101.3078910128961, 9.031472717572315 ], "reducing_value": 4170.0, "t": [ 0.398, 0.952, 1.466, 2.053, 2.242, 4.989 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ 421.564864740388, -16.085256613461063, 0.19189507567966255, -0.0011868099650075925, 4.323172584621629e-06, -9.376997720415709e-09, 1.1235338183077166e-11, -5.742166546136361e-15 ], "B": [ 1, -0.0027032448069045432 ], "Tmax": 367.75, "Tmin": 220.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.4388358289967158, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ -772.270169640045, 28.027619724897413, -0.34420770911100323, 0.0021922623878138092, -8.147733782709826e-06, 1.790015200044322e-08, -2.1638383604766276e-11, 1.1136866702493994e-14 ], "B": [ 1, -0.0027004272124359035 ], "Tmax": 367.75, "Tmin": 220.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.0811856688804422, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 367.85, "a": [ 0.06274 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.394 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Richter-JCED-2011", "STATES": { "hs_anchor": { "T": 404.63500000000005, "T_units": "K", "hmolar": 48232.026932563014, "hmolar_units": "J/mol", "p": 5661102.092360271, "p_units": "Pa", "rhomolar": 3753.0, "rhomolar_units": "mol/m^3", "smolar": 186.35382399002881, "smolar_units": "J/mol/K" }, "reducing": { "T": 367.85, "T_units": "K", "hmolar": 42150.06488887152, "hmolar_units": "J/mol", "p": 3382200, "p_units": "Pa", "rhomolar": 4170, "rhomolar_units": "mol/m^3", "smolar": 172.07304302572015, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 220.0, "T_units": "K", "hmolar": 15520.183697391298, "hmolar_units": "J/mol", "p": 31507.558848475514, "p_units": "Pa", "rhomolar": 11633.107308831428, "rhomolar_units": "mol/m^3", "smolar": 84.54897749603592, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 220.0, "T_units": "K", "hmolar": 37376.03203521745, "hmolar_units": "J/mol", "p": 31507.558848475514, "p_units": "Pa", "rhomolar": 17.583605761936976, "rhomolar_units": "mol/m^3", "smolar": 183.89370628814143, "smolar_units": "J/mol/K" } }, "T_max": 410, "T_max_units": "K", "Ttriple": 220, "Ttriple_units": "K", "acentric": 0.276, "acentric_units": "-", "alpha0": [ { "a1": -12.837928, "a2": 8.042605, "type": "IdealGasHelmholtzLead" }, { "a": 4.944, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 7.549, 1.537, 2.03, 7.455 ], "t": [ 1.951882560826424, 2.384123963572108, 12.13809976892755, 4.770966426532554 ], "type": "IdealGasHelmholtzPlanckEinstein" } ], "alphar": [ { "d": [ 4, 1, 1, 2, 3, 1, 3, 2, 2, 7 ], "l": [ 0, 0, 0, 0, 0, 2, 2, 1, 2, 1 ], "n": [ 0.04592563, 1.546958, -2.355237, -0.4827835, 0.1758022, -1.210006, -0.6177084, 0.6805262, -0.6968555, -0.02695779 ], "t": [ 1, 0.32, 0.929, 0.94, 0.38, 2.28, 1.76, 0.97, 2.44, 1.05 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 1.42, 2.31, 0.89, 80, 108 ], "d": [ 1, 1, 3, 3, 2 ], "epsilon": [ 0.712, 0.91, 0.677, 0.718, 1.64 ], "eta": [ 1.02, 1.336, 1.055, 5.84, 16.2 ], "gamma": [ 1.13, 0.67, 0.46, 1.28, 1.2 ], "n": [ 1.389966, -0.4777136, -0.1975184, -1.147646, 0.0003428541 ], "t": [ 1.4, 3, 3.5, 1, 3.5 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 367.85, "T_min": 367.84983035809745, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -7.28092281910778e-06, 367.8803614481557 ], "cV": [ 0.0, 0.0, 7.273842039048367e-06, 367.8196680786972 ], "rhomolar_max": 4193.299505682264, "rhomolar_min": 4146.67781322612 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.1140415928, "molar_mass_units": "kg/mol", "p_max": 30000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=2057041", "ALIASES": [ "R1234YF" ], "CAS": "754-12-1", "CHEMSPIDER_ID": 2057041, "ENVIRONMENTAL": { "ASHRAE34": "A2L", "FH": 2, "GWP100": 4.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "R1234yf", "ODP": -1.0, "PH": 0 }, "FORMULA": "C_{3}F_{4}H_{2}", "INCHI_KEY": "FXRLMCRCYDHQFW-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/C3H2F4/c1-2(4)3(5,6)7/h1H2", "NAME": "R1234yf", "REFPROP_NAME": "R1234YF", "SMILES": "C=C(C(F)(F)F)F" }, "STATES": { "critical": { "T": 367.85, "T_units": "K", "hmolar": 42144.616087058115, "hmolar_units": "J/mol", "p": 3382200.0, "p_units": "Pa", "rhomolar": 4170.0, "rhomolar_units": "mol/m^3", "smolar": 172.05987191715886, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 220.0, "T_units": "K", "hmolar": 15520.183697391298, "hmolar_units": "J/mol", "p": 31507.558848475514, "p_units": "Pa", "rhomolar": 11633.107308831428, "rhomolar_units": "mol/m^3", "smolar": 84.54897749603592, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 220.0, "T_units": "K", "hmolar": 37376.03203521745, "hmolar_units": "J/mol", "p": 31507.558848475514, "p_units": "Pa", "rhomolar": 17.583605761936976, "rhomolar_units": "mol/m^3", "smolar": 183.89370628814143, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Perkins-JCED-2011", "critical": { "GAMMA": 0.0496, "R0": 1.03, "gamma": 1.239, "qD": 1713796058.2, "type": "simplified_Olchowy_Sengers", "zeta0": 1.94e-10 }, "dilute": { "A": [ -0.0102778, 0.0291098, 0.000860643 ], "B": [ 1.0 ], "T_reducing": 367.85, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ -0.0368219, 0.0883226, -0.0705909, 0.0259026, -0.0032295, 0.0397166, -0.077239, 0.0664707, -0.0249071, 0.00336228 ], "T_reducing": 367.85, "T_reducing_units": "K", "d": [ 1, 2, 3, 4, 5, 1, 2, 3, 4, 5 ], "rhomass_reducing": 475.55, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0, 0, -1, -1, -1, -1, -1 ], "type": "polynomial" } }, "viscosity": [ { "BibTeX": "Bell-PURDUE-2016-ETA", "C": 0.87302, "c_liq": [ 0.6100913843, 0.4508958312, -0.017063, 0.000564 ], "c_vap": [ 0.0, 1.2, -0.308598, 0.035317 ], "rhosr_critical": -54468.47741433059, "type": "rhosr-CS", "x_crossover": 2 }, { "BibTeX": "BELL-PERSONAL-2015", "_note": "Fit based on the data of Zhao, JCED, 2014: doi: 10.1021/je5001457", "epsilon_over_k": 281.14, "epsilon_over_k_units": "K", "psi": { "a": [ 0.17682139, 0.74500256, -0.16912621 ], "rhomolar_reducing": 4170.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1, 2 ] }, "reference_fluid": "R134a", "sigma_eta": 5.328e-10, "sigma_eta_units": "m", "type": "ECS" } ] } }