{ "ANCILLARIES": { "hL": { "A": [ -14548.431641457397, -425.3097032919506, 6.040305720967621, -0.03667979513763329, 0.00013121909101221487, -2.833690304020896e-07, 3.4105973158767573e-10, -1.7632569242236018e-13 ], "B": [ 1, -0.002449612160719887 ], "Tmax": 405.3, "Tmin": 195.495, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 175.02638309168015, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -39656.441243327485, 1732.1248720835576, -20.184954966702787, 0.12336506690457887, -0.00044866664143201863, 9.727626573853517e-07, -1.1638181243435474e-09, 5.938354498744747e-13 ], "B": [ 1, -0.00244523421040168 ], "Tmax": 405.3, "Tmin": 195.495, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 360.2372587421132, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pS": { 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"J/mol", "p": 6091.2231081315085, "p_units": "Pa", "rhomolar": 43035.33929207322, "rhomolar_units": "mol/m^3", "smolar": -1.9440525067083775e-06, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 195.495, "T_units": "K", "hmolar": 25279.492873914965, "hmolar_units": "J/mol", "p": 6091.223108650368, "p_units": "Pa", "rhomolar": 3.763506027681136, "rhomolar_units": "mol/m^3", "smolar": 129.30945229032756, "smolar_units": "J/mol/K" } }, "T_max": 700, "T_max_units": "K", "Ttriple": 195.495, "Ttriple_units": "K", "acentric": 0.25601, "acentric_units": "-", "alpha0": [ { "a1": -15.81502, "a2": 4.255726, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 11.47434, -1.296211, 0.5706757 ], "t": [ 0.3333333333333333, -1.5, -1.75 ], "type": "IdealGasHelmholtzPower" }, { "a1": -0.965940085369186, "a2": 0.723282863334932, "reference": "OTH", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 2, 1, 4, 1, 15, 3, 3, 1, 8, 2, 1, 8, 1, 2, 3, 2, 4, 3, 1, 2, 4 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 3, 3, 3, 3 ], "n": [ 0.04554431, 0.7238548, 0.0122947, -1.858814, 2.141882e-11, -0.0143002, 0.3441324, -0.2873571, 2.352589e-05, -0.03497111, 0.02397852, 0.001831117, -0.04085375, 0.2379275, -0.03548972, -0.1823729, 0.02281556, -0.006663444, -0.008847486, 0.002272635, -0.0005588655 ], "t": [ -0.5, 0.5, 1, 1.5, 3, 0, 3, 4, 4, 5, 3, 5, 6, 8, 8, 10, 10, 5, 7.5, 15, 30 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.314471, "gas_constant_units": "J/mol/K", "molar_mass": 0.01703026, "molar_mass_units": "kg/mol", "p_max": 1000000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=217", "ALIASES": [ "NH3", "ammonia", "R717", "AMMONIA" ], "CAS": "7664-41-7", "CHEMSPIDER_ID": 217, "ENVIRONMENTAL": { "ASHRAE34": "B2", "FH": 1, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 3, "Name": "Ammonia", "ODP": -1.0, "PH": 0 }, "FORMULA": "H_{3}N_{1}", "INCHI_KEY": "QGZKDVFQNNGYKY-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/H3N/h1H3", "NAME": "Ammonia", "REFPROP_NAME": "AMMONIA", "SMILES": "N" }, "STATES": { "critical": { "T": 405.40000000000003, "T_units": "K", "hmolar": 21498.578924065936, "hmolar_units": "J/mol", "p": 11333000.0, "p_units": "Pa", "rhomolar": 13211.777154312384, "rhomolar_units": "mol/m^3", "smolar": 68.5595020166536, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 195.495, "T_units": "K", "hmolar": 0.14111811220522047, "hmolar_units": "J/mol", "p": 6091.2231081315085, "p_units": "Pa", "rhomolar": 43035.33929207322, "rhomolar_units": "mol/m^3", "smolar": -1.9440525067083775e-06, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 195.495, "T_units": "K", "hmolar": 25279.492873914965, "hmolar_units": "J/mol", "p": 6091.223108650368, "p_units": "Pa", "rhomolar": 3.763506027681136, "rhomolar_units": "mol/m^3", "smolar": 129.30945229032756, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Tufeu-BBPC-1984", "critical": { "hardcoded": "Ammonia" }, "dilute": { "A": [ 0.03589, -0.000175, 4.551e-07, 1.685e-10, -4.828e-13 ], "B": [ 1.0 ], "T_reducing": 1, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2, 3, 4 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ 0.03808645, 0.06647986, -0.0300295, 0.00998779 ], "T_reducing": 1, "T_reducing_units": "K", "d": [ 1, 2, 3, 4 ], "rhomass_reducing": 235, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0 ], "type": "polynomial" } }, "viscosity": { "BibTeX": "Fenghour-JPCRD-1995", "_note": "There is a mysterious factor of 100 missing from the Fenghour equation for the dilute gas. From REFPROP fluid file: !=0.021357*SQRT(MW)*(unknown factor of 100) [Chapman-Enskog term]", "dilute": { "C": 2.1357e-06, "a": [ 4.9931822, -0.61122364, 0.0, 0.18535124, -0.11160946 ], "molar_mass": 0.01703026, "molar_mass_units": "kg/mol", "t": [ 0, 1, 2, 3, 4 ], "type": "collision_integral" }, "epsilon_over_k": 386, "epsilon_over_k_units": "K", "higher_order": { "T_reduce": 405.4, "T_reduce_units": "K", "a": [ 4.005040600989671e-06, -1.4107915123955129e-05, 3.4760743039321816e-05, 4.631310990138071e-06, -3.937374461785061e-06, -1.200075068367531e-05, 1.9284977991745303e-06 ], "d1": [ 3, 3, 2, 4, 4, 2, 4 ], "d2": [ 1 ], "f": [ 0.0 ], "g": [ 1 ], "gamma": [ 0, 0, 0, 0, 0, 0, 0 ], "h": [ 0 ], "l": [ 1, 1, 1, 1, 1, 1, 1 ], "p": [ 1 ], "q": [ 0 ], "rhomolar_reduce": 13211.8, "rhomolar_reduce_units": "mol/m^3", "t1": [ 0, 1, 2, 2, 3, 4, 4 ], "t2": [ 0 ], "type": "modified_Batschinski_Hildebrand" }, "initial_density": { "b": [ -1.7999496, 46.692621, -534.60794, 3360.4074, -13019.164, 33414.23, -58711.743, 71426.686, -59834.012, 33652.741, -12027.35, 2434.8205, -208.07957 ], "t": [ -0.0, -0.5, -1.0, -1.5, -2.0, -2.5, -3.0, -3.5, -4.0, -4.5, -5.0, -5.5, -6.0 ], "type": "Rainwater-Friend" }, "sigma_eta": 2.957e-10, "sigma_eta_units": "m" } } }