{ "ANCILLARIES": { "hL": { "A": [ -20261.720734053535, -42.70805579736125, 3.2264880346770806, -0.03267795220248956, 0.00018035703880850667, -5.866213633312135e-07, 1.0502903615987737e-09, -8.045968153544473e-13 ], "B": [ 1, -0.0035034630200342855 ], "Tmax": 282.25, "Tmin": 103.989, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 127.98736341940776, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 10253.938827312402, 295.4715166785244, -7.039975386090677, 0.0697240217787294, -0.0003974161011437105, 1.3294902093934048e-06, -2.433179838969239e-09, 1.8942647209684242e-12 ], "B": [ 1, -0.0035015264817185683 ], "Tmax": 282.25, "Tmin": 103.989, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 296.84005577153016, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "Smukala-JPCRD-2000", "T_m": 169, "parts": [ { "T_0": 103.989, "T_max": 110.369, "T_min": 103.989, "a": [ 2947001.84 ], "p_0": 122.65, "t": [ 2.045 ] }, { "T_0": 110.369, "T_max": 190, "T_min": 110.369, "a": [ 6.82693421 ], "p_0": 46800000.0, "t": [ 1.089 ] } ], "type": "polynomial_in_Tr" }, "pS": { "T_r": 282.35, "Tmax": 282.3499999999994, "Tmin": 103.98900000000002, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.012376938726232911, "n": [ 30.782068035093094, -1.467121970937139, 0.09230690543250192, -2.5188888709008195, -34.95537683446643, 6.643870978349449 ], "reducing_value": 5041800.0, "t": [ 1.118, 1.461, 2.464, 4.298, 1.082, 18.676 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 282.35, "Tmax": 282.3499999999994, "Tmin": 103.98900000000002, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.08567503686368605, "n": [ 1.8464339723391994, 0.7268516869915771, -1.717280185311927, 1686.1315441396878, -3729.1628980234227, 2049.0293383014655 ], "reducing_value": 7636.76598074554, "t": [ 0.348, 0.912, 3.94, 6.912, 7.065, 7.198 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 282.35, "Tmax": 282.3499999999994, "Tmin": 103.98900000000002, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.5959122914985127, "n": [ -0.21894352062047293, -3.4266486595099503, -1.5160021065230918, -4.205648419382292, -265.8806216433561, 474.2473840272181 ], "reducing_value": 7636.76598074554, "t": [ 0.165, 0.497, 1.478, 5.546, 19.239, 19.774 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -200.08663361237868, 2.309364220148305, -0.010275588862910716, -1.6832700457156617e-07, 2.4363565882120485e-07, -1.2316882624760173e-09, 2.684111564896006e-12, -2.2873475883277924e-15 ], "B": [ 1, -0.0035054905332161093 ], "Tmax": 282.25, "Tmin": 103.989, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.437337763941132, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 782.9671485372487, -17.00700805429637, 0.18427655613068378, -0.0012069150820883461, 4.93230393555278e-06, -1.2300043914982539e-08, 1.7104822556154248e-11, -1.0111806251874025e-14 ], "B": [ 1, -0.00349499315197753 ], "Tmax": 282.25, "Tmin": 103.989, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.1621875334727756, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 282.35, "a": [ 0.0477 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.17 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Smukala-JPCRD-2000", "STATES": { "hs_anchor": { "T": 310.58500000000004, "T_units": "K", "hmolar": 13467.302769838352, "hmolar_units": "J/mol", "p": 7935253.189623128, "p_units": "Pa", "rhomolar": 6873.089382670986, "rhomolar_units": "mol/m^3", "smolar": 52.91020757486265, "smolar_units": "J/mol/K" }, "reducing": { "T": 282.35, "T_units": "K", "hmolar": 11207.797265456176, "hmolar_units": "J/mol", "p": 5041800, "p_units": "Pa", "rhomolar": 7636.76598074554, "rhomolar_units": "mol/m^3", "smolar": 46.61566511698445, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 103.989, "T_units": "K", "hmolar": -4434.994432546394, "hmolar_units": "J/mol", "p": 122.02676384261189, "p_units": "Pa", "rhomolar": 23333.806692213075, "rhomolar_units": "mol/m^3", "smolar": -33.071691143071675, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 103.989, "T_units": "K", "hmolar": 11485.96355892807, "hmolar_units": "J/mol", "p": 122.02676384261189, "p_units": "Pa", "rhomolar": 0.14116264559545175, "rhomolar_units": "mol/m^3", "smolar": 120.03058885995085, "smolar_units": "J/mol/K" } }, "T_max": 450, "T_max_units": "K", "Ttriple": 103.989, "Ttriple_units": "K", "acentric": 0.0866, "acentric_units": "-", "alpha0": [ { "a1": 8.68815523, "a2": -4.47960564, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 2.49395851, 3.0027152, 2.5126584, 3.99064217 ], "t": [ 4.43266896, 5.74840149, 7.8027825, 15.5851154 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -12.2225787966305, "a2": 7.89924916929716, "reference": "NBP", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 2, 4, 1, 1, 3, 4, 5, 7, 10, 11, 1, 1, 2, 2, 4, 4, 6, 7, 4, 5, 6, 6, 7, 8, 9, 10 ], "l": [ 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 3, 4, 4, 4, 4, 4, 4, 4, 4 ], "n": [ 1.861742910067, -3.0913708460844, -0.17384817095516, 0.08037098569284, 0.23682707317354, 0.021922786610247, 0.11827885813193, -0.021736384396776, 0.044007990661139, 0.12554058863881, -0.13167945577241, -0.0052116984575897, 0.00015236081265419, -2.4505335342756e-05, 0.28970524924022, -0.18075836674288, 0.15057272878461, -0.14093151754458, 0.022755109070253, 0.014026070529061, 0.0061697454296214, -0.00041286083451333, 0.012885388714785, -0.069128692157093, 0.10936225568483, -0.0081818875271794, -0.05641847211717, 0.0016517867750633, 0.0095904006517001, -0.0026236572984886 ], "t": [ 0.5, 1, 2.5, 0, 2, 0.5, 1, 4, 1.25, 2.75, 2.25, 1, 0.75, 0.5, 2.5, 3.5, 4, 6, 1.5, 5, 4.5, 15, 20, 23, 22, 29, 19, 15, 13, 10 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 325, 300, 300, 300, 300 ], "d": [ 2, 2, 2, 3, 3 ], "epsilon": [ 1, 1, 1, 1, 1 ], "eta": [ 25, 25, 25, 25, 25 ], "gamma": [ 1.16, 1.19, 1.19, 1.19, 1.19 ], "n": [ -50.242414011355, 7484.6420119299, -6873.4299232625, -935.77982814338, 941.33024786113 ], "t": [ 1, 0, 1, 2, 3 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 282.35, "T_min": 282.3497439583547, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -3.634935446259431e-06, 282.37775915135825 ], "cV": [ 0.0, 0.0, 3.6437107681563877e-06, 282.3221738335621 ], "rhomolar_max": 7707.205098345808, "rhomolar_min": 7566.496505023215 }, "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.02805376, "molar_mass_units": "kg/mol", "p_max": 300000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=6085", "ALIASES": [ "ethylene", "ETHYLENE", "R1150" ], "CAS": "74-85-1", "CHEMSPIDER_ID": 6085, "ENVIRONMENTAL": { "ASHRAE34": "A3", "FH": 4, "GWP100": 6.8, "GWP20": -1.0, "GWP500": -1.0, "HH": 2, "Name": "Ethylene", "ODP": -1.0, "PH": 2 }, "FORMULA": "C_{2}H_{4}", "INCHI_KEY": "VGGSQFUCUMXWEO-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/C2H4/c1-2/h1-2H2", "NAME": "Ethylene", "REFPROP_NAME": "ETHYLENE", "SMILES": "C=C" }, "STATES": { "critical": { "T": 282.35, "T_units": "K", "hmolar": 11205.622917124283, "hmolar_units": "J/mol", "p": 5041800.0, "p_units": "Pa", "rhomolar": 7636.765980745539, "rhomolar_units": "mol/m^3", "smolar": 46.60945286278082, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 103.989, "T_units": "K", "hmolar": -4434.994432546394, "hmolar_units": "J/mol", "p": 122.02676384261189, "p_units": "Pa", "rhomolar": 23333.806692213075, "rhomolar_units": "mol/m^3", "smolar": -33.071691143071675, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 103.989, "T_units": "K", "hmolar": 11485.96355892807, "hmolar_units": "J/mol", "p": 122.02676384261189, "p_units": "Pa", "rhomolar": 0.14116264559545175, "rhomolar_units": "mol/m^3", "smolar": 120.03058885995085, "smolar_units": "J/mol/K" } } }