{ "ANCILLARIES": { "hL": { "A": [ -70529.53520320434, 159.0041029159524, 1.9476919265101391, -0.01574228452570786, 6.503258359604608e-05, -1.623489423720381e-07, 2.244020333222034e-10, -1.3335003919459013e-13 ], "B": [ 1, -0.0026405470860530996 ], "Tmax": 374.8, "Tmin": 146.35, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 277.0991544024728, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 25018.01911136847, 342.61416892013045, -7.164406017227476, 0.05540143470547363, -0.0002410243902529792, 6.113097460884039e-07, -8.463459729590336e-10, 4.977630280488809e-13 ], "B": [ 1, -0.002641077587922539 ], "Tmax": 374.8, "Tmin": 146.35, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 680.2046953885297, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pS": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.010578535119587507, "n": [ -7.109161477135856, -0.43619976868074284, 5.934481777381213, 39.44778344273422, -41.38716737709299, -8.362365023243223 ], "reducing_value": 2925000.0, "t": [ 0.987, 1.312, 1.927, 3.476, 3.578, 2.248 ], "type": "pL", "using_tau_r": true }, "rhoL": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.2727146007857062, "n": [ -0.037180636267061765, 2.2565260411325867, 16.777771835065064, -22.313716095609287, 6.793310681390873, -10.89306852102585 ], "reducing_value": 3495.0, "t": [ 0.12, 0.35, 2.248, 2.467, 3.208, 12.192 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.7920968700624531, "n": [ -6.947050225285722, 123.4065348806111, -122.5651518640378, -9.994885618440552, 3.478879029818986, 245.61726193605475 ], "reducing_value": 3495.0, "t": [ 0.434, 0.676, 0.691, 4.287, 4.613, 19.251 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -474.54288184336224, 4.472882529623101, -0.022836730272613126, 8.34713881045167e-05, -2.0462863919604783e-07, 2.9761429584136244e-10, -2.1509331903931825e-13, 4.250881744993166e-17 ], "B": [ 1, -0.002639613315118132 ], "Tmax": 374.8, "Tmin": 146.35, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.7554251786648507, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1215.2639853142118, -20.27913368777666, 0.16638268212047175, -0.0008194386546987785, 2.5129625680628097e-06, -4.699166166025172e-09, 4.897735924046916e-12, -2.169612203006422e-15 ], "B": [ 1, -0.0026365616295222242 ], "Tmax": 374.8, "Tmin": 146.35, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.9878057326133707, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 374.9, "a": [ 0.06127, -0.009516, -0.00192 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.192, 0.9795, 1.421 ] } }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Lemmon-JCED-2016-365227", "STATES": { "hs_anchor": { "T": 412.39, "T_units": "K", "hmolar": 67624.73852891507, "hmolar_units": "J/mol", "p": 4993972.60245234, "p_units": "Pa", "rhomolar": 3145.5, "rhomolar_units": "mol/m^3", "smolar": 265.36148687389857, "smolar_units": "J/mol/K" }, "reducing": { "T": 374.9, "T_units": "K", "hmolar": 59607.50629875647, "hmolar_units": "J/mol", "p": 2925242.234115973, "p_units": "Pa", "rhomolar": 3495, "rhomolar_units": "mol/m^3", "smolar": 246.5494357452648, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 146.35, "T_units": "K", "hmolar": 12304.215340872486, "hmolar_units": "J/mol", "p": 7.331559169108263, "p_units": "Pa", "rhomolar": 11046.70589980008, "rhomolar_units": "mol/m^3", "smolar": 64.34702582016915, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 146.35, "T_units": "K", "hmolar": 42043.4604638721, "hmolar_units": "J/mol", "p": 7.331559169108263, "p_units": "Pa", "rhomolar": 0.0060253481834979875, "rhomolar_units": "mol/m^3", "smolar": 267.5533471252583, "smolar_units": "J/mol/K" } }, "T_max": 475, "T_max_units": "K", "Ttriple": 146.35, "Ttriple_units": "K", "acentric": 0.3576412419532815, "acentric_units": "-", "alpha0": [ { "a1": -15.8291124137, "a2": 11.0879509962, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 11.43, 12.83 ], "t": [ 1.07495332088557, 3.809015737530008 ], "type": "IdealGasHelmholtzPlanckEinstein" } ], "alphar": [ { "d": [ 1, 1, 2, 2, 4, 1, 3, 6, 6, 2, 3 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 1, 2, 2 ], "n": [ 2.024341, -2.60593, 0.4957216, -0.824082, 0.06543703, -1.02461, 0.6247065, 0.2997521, -0.353917, -1.232043, -0.8824483 ], "t": [ 0.34, 0.77, 0.36, 0.9, 1, 2.82, 2.1, 0.9, 1.13, 3.8, 2.75 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 1.72, 5.2, 2.31, 1.02, 5.63, 50.9, 1.56 ], "d": [ 1, 2, 1, 1, 4, 2, 1 ], "epsilon": [ 1.13, 0.71, 1.2, 1.7, 0.546, 0.896, 0.747 ], "eta": [ 0.83, 2.19, 2.44, 3.65, 8.88, 8.23, 2.01 ], "gamma": [ 0.414, 1.051, 1.226, 1.7, 0.904, 1.42, 0.926 ], "n": [ 0.1349661, -0.2662928, 0.1764733, 0.01536163, -0.004667185, -11.70854, 0.9114512 ], "t": [ 1.5, 2.5, 2.5, 5.4, 4, 1, 3.5 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 374.90000000000003, "T_min": 374.8931050613274, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ -5.875126621910152e-10, 5.780632973589872e-06, -0.01887717891595377, 395.3469681114307 ], "cV": [ 1.1730303150524067e-10, -1.607222079285808e-06, 0.006935903946970884, 365.2834297632339 ], "rhomolar_max": 3618.508261092158, "rhomolar_min": 3362.517912603551 }, "gas_constant": 8.3144621, "gas_constant_units": "J/mol/K", "molar_mass": 0.17002886, "molar_mass_units": "kg/mol", "p_max": 60000000, "p_max_units": "Pa", "pseudo_pure": false } ], "INFO": { "2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=61257", "ALIASES": [ "R227ea" ], "CAS": "431-89-0", "CHEMSPIDER_ID": 61257, "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 0, "GWP100": 3220.0, "GWP20": 5310.0, "GWP500": 1040.0, "HH": 1, "Name": "R227EA", "ODP": -1.0, "PH": 0 }, "FORMULA": "C_{3}F_{7}H_{1}", "INCHI_KEY": "YFMFNYKEUDLDTL-UHFFFAOYSA-N", "INCHI_STRING": "InChI=1S/C3HF7/c4-1(2(5,6)7)3(8,9)10/h1H", "NAME": "R227EA", "REFPROP_NAME": "R227EA", "SMILES": "C(C(F)(F)F)(C(F)(F)F)F" }, "STATES": { "critical": { "T": 374.90000000000003, "T_units": "K", "hmolar": 59607.506298756474, "hmolar_units": "J/mol", "p": 2925242.2339447653, "p_units": "Pa", "rhomolar": 3495.0, "rhomolar_units": "mol/m^3", "smolar": 246.5494357452648, "smolar_units": "J/mol/K" }, "triple_liquid": { "T": 146.35, "T_units": "K", "hmolar": 12304.215340872486, "hmolar_units": "J/mol", "p": 7.331559169108263, "p_units": "Pa", "rhomolar": 11046.70589980008, "rhomolar_units": "mol/m^3", "smolar": 64.34702582016915, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 146.35, "T_units": "K", "hmolar": 42043.4604638721, "hmolar_units": "J/mol", "p": 7.331559169108263, "p_units": "Pa", "rhomolar": 0.0060253481834979875, "rhomolar_units": "mol/m^3", "smolar": 267.5533471252583, "smolar_units": "J/mol/K" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Huber-IECR-2003", "f_int": { "T_reducing": 1.0, "T_reducing_units": "K", "a": [ 0.00142313, 8.31496e-09 ], "t": [ 0, 1 ] }, "psi": { "a": [ 1.3122, -0.0874448 ], "rhomolar_reducing": 3370.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1 ] }, "q_D": 1999999999.9999998, "q_D_units": "m", "reference_fluid": "Propane", "type": "ECS" }, "viscosity": { "BibTeX": "Huber-IECR-2003", "epsilon_over_k": 289.34, "epsilon_over_k_units": "K", "psi": { "a": [ 0.76758, 0.254482, -0.0533748 ], "rhomolar_reducing": 3370.0, "rhomolar_reducing_units": "mol/m^3", "t": [ 0, 1, 2 ] }, "reference_fluid": "Propane", "sigma_eta": 5.746000000000001e-10, "sigma_eta_units": "m", "type": "ECS" } } }