{ "ALIASES": [ "CH4", "methane", "METHANE" ], "ANCILLARIES": { "pL": { "T_r": 190.564, "Tmax": 190.56399999999954, "Tmin": 90.69410000000002, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.013146758390991664, "n": [ -4.392486530162625, -81.28318843036807, 82.94698441608203, -2.6879045537986053, -5.671070893658749, 4.700510293996553 ], "reducing_value": 4599200.0, "t": [ 0.963, 1.421, 1.438, 1.98, 6.338, 6.911 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 190.564, "Tmax": 190.56399999999954, "Tmin": 90.69410000000002, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.0043709218045084874, "n": [ -0.36511751226395045, -7.477611035699516, 2.8218785804602344, -0.3138277099613026, -14.181166200304828, 13.10811727353235 ], "reducing_value": 4599200.0, "t": [ 0.935, 1.03, 1.204, 3.176, 5.616, 5.744 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 190.564, "Tmax": 190.56399999999954, "Tmin": 90.69410000000002, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.03816630998332293, "n": [ 1.0459450372370667, 1.137482950365497, 0.25267850508364803, -0.15127345979918666, 11.30484305385285, -1807.5949062134612 ], "reducing_value": 10139.127999999999, "t": [ 0.309, 0.502, 1.402, 3.858, 10.533, 19.547 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 190.564, "Tmax": 190.56399999999954, "Tmin": 90.69410000000002, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.043503419703461166, "n": [ -3.258091004501641, 24.278993697870174, -25.256402428812585, -0.17494067187770526, 0.3375209723239743, -2.3099699792209805 ], "reducing_value": 10139.127999999999, "t": [ 0.392, 0.606, 0.631, 1.024, 2.03, 4.077 ], "type": "rhoV", "using_tau_r": true }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 190.564, "a": [ 0.03825, -0.006024, -0.0007065 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.191, 5.422, 0.6161 ] } }, "CAS": "74-82-8", "CRITICAL": { "T": 190.564, "T_units": "K", "p": 4599200.0, "p_units": "Pa", "rhomolar": 10139.127999999999, "rhomolar_units": "mol/m^3" }, "ENVIRONMENTAL": { "ASHRAE34": "A3", "FH": 4, "GWP100": 25.0, "GWP20": 72.0, "GWP500": 7.6, "HH": 0, "Name": "Methane", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Setzmann-JPCRD-1991", "T_max": 625, "T_max_units": "K", "Ttriple": 90.6941, "Ttriple_units": "K", "accentric": 0.01142, "accentric_units": "-", "alpha0": [ { "a1": 9.91243972, "a2": -6.33270087, "type": "IdealGasHelmholtzLead" }, { "a": 3.0016, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 0.008449, 4.6942, 3.4865, 1.6572, 1.4115 ], "t": [ 3.400432401, 10.26951575, 20.43932747, 29.93744884, 79.13351945 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -12.8829893867948, "a2": 9.22344625310864, "reference": "NBP", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 2, 2, 2, 3, 4, 4, 8, 9, 10, 1, 1, 1, 2, 4, 5, 6, 1, 2, 3, 4, 4, 3, 5, 5, 8, 2, 3, 4, 4, 4, 5, 6 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 3, 3, 3, 3, 4, 4, 4, 4, 4, 4, 4 ], "n": [ 0.04367901028, 0.6709236199, -1.765577859, 0.8582330241, -1.206513052, 0.512046722, -0.0004000010791, -0.01247842423, 0.03100269701, 0.001754748522, -3.171921605e-06, -2.24034684e-06, 2.947056156e-07, 0.1830487909, 0.1511883679, -0.4289363877, 0.06894002446, -0.01408313996, -0.0306305483, -0.02969906708, -0.01932040831, -0.1105739959, 0.09952548995, 0.008548437825, -0.06150555662, -0.04291792423, -0.0181320729, 0.0344590476, -0.00238591945, -0.01159094939, 0.06641693602, -0.0237154959, -0.03961624905, -0.01387292044, 0.03389489599, -0.002927378753 ], "t": [ -0.5, 0.5, 1, 0.5, 1, 1.5, 4.5, 0, 1, 3, 1, 3, 3, 0, 1, 2, 0, 0, 2, 2, 5, 5, 5, 2, 4, 12, 8, 10, 10, 10, 14, 12, 18, 22, 18, 14 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 200, 250, 250, 250 ], "d": [ 2, 0, 0, 0 ], "epsilon": [ 1, 1, 1, 1 ], "eta": [ 20, 40, 40, 40 ], "gamma": [ 1.07, 1.11, 1.11, 1.11 ], "n": [ 9.324799946e-05, -6.287171518, 12.71069467, -6.423953466 ], "t": [ 2, 0, 1, 2 ], "type": "ResidualHelmholtzGaussian" } ], "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.0160428, "molar_mass_units": "kg/mol", "p_max": 1000000000, "p_max_units": "Pa", "pseudo_pure": false, "ptriple": 11696.06412, "ptriple_units": "Pa", "reducing_state": { "T": 190.564, "T_units": "K", "p": 4599200, "p_units": "Pa", "rhomolar": 10139.128, "rhomolar_units": "mol/m^3" }, "rhoLtriple": 28141.83192295947, "rhoLtriple_units": "mol/m^3", "rhoVtriple": 15.63154286998348, "rhoVtriple_units": "mol/m^3" } ], "NAME": "Methane", "REFPROP_NAME": "METHANE" }