{ "ALIASES": [ "toluene", "TOLUENE" ], "ANCILLARIES": { "pL": { "T_r": 591.75, "Tmax": 591.7499999999987, "Tmin": 178.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.013628695855705253, "n": [ -11.639922828598088, 5.650211353764286, -2.6974053250328165, -3.164119945892499, 1.8859792463505036, -5.2234698853395525 ], "reducing_value": 4126000.0, "t": [ 1.041, 1.184, 3.013, 5.82, 8.325, 15.907 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 591.75, "Tmax": 591.7499999999987, "Tmin": 178.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.009539128608204717, "n": [ -41.682551388800405, 35.681619568443324, -2.4647898129932573, -2.2965822444409394, 1.6090346729113876, -6.971566618092907 ], "reducing_value": 4126000.0, "t": [ 1.081, 1.11, 2.974, 5.067, 13.97, 17.253 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 591.75, "Tmax": 591.7499999999987, "Tmin": 178.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.8197967086870594, "n": [ 2.731439741297877, -1.4311921172736468, 1.7220225715861872, -1.3959592517619432, 25.019574322670564, -106.28098773992355 ], "reducing_value": 3169.0, "t": [ 0.413, 1.151, 1.592, 6.141, 12.914, 18.579 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 591.75, "Tmax": 591.7499999999987, "Tmin": 178.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.610452170273057, "n": [ -2.079525851134041, -3.0632853262137703, -5.643041080974643, 3.9792497484198788, -2638.7103858281944, 2945.506923819063 ], "reducing_value": 3169.0, "t": [ 0.4, 0.697, 3.764, 8.691, 19.351, 19.782 ], "type": "rhoV", "using_tau_r": true }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 591.75, "a": [ 0.06897 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.291 ] } }, "CAS": "108-88-3", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 3, "GWP100": 3.3, "GWP20": -1.0, "GWP500": -1.0, "HH": 2, "Name": "Toluene", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Lemmon-JCED-2006", "STATES": { "reducing": { "T": 591.75, "T_units": "K", "p": 4126000, "p_units": "Pa", "rhomolar": 3169, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 178.0, "T_units": "K", "p": 3.9393478817276356e-05, "p_units": "Pa", "rhomolar": 10580.06048163071, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 178.0, "T_units": "K", "p": 3.9393478817276356e-05, "p_units": "Pa", "rhomolar": 2.661765525110245e-05, "rhomolar_units": "mol/m^3" } }, "T_max": 700, "T_max_units": "K", "Ttriple": 178, "Ttriple_units": "K", "accentric": 0.2657, "accentric_units": "-", "alpha0": [ { "a1": 3.5241174832, "a2": 1.1360823464, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 1.6994, 8.0577, 17.059, 8.4567, 8.6423 ], "t": [ 0.3210815378115758, 1.346852555978031, 2.735952682720744, 5.191381495564005, 13.37558090409801 ], "type": "IdealGasHelmholtzPlanckEinstein" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 7, 2, 5, 1, 4, 3, 4 ], "l": [ 0, 0, 0, 0, 0, 0, 1, 1, 2, 2, 3, 3 ], "n": [ 0.96464, -2.7855, 0.86712, -0.1886, 0.11804, 0.00025181, 0.57196, -0.029287, -0.43351, -0.1254, -0.028207, 0.014076 ], "t": [ 0.25, 1.125, 1.5, 1.375, 0.25, 0.875, 0.625, 1.75, 3.625, 3.625, 14.5, 12 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.09213842, "molar_mass_units": "kg/mol", "p_max": 500000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "Toluene", "REFPROP_NAME": "TOLUENE", "STATES": { "critical": { "T": 591.75, "T_units": "K", "p": 4126000.0, "p_units": "Pa", "rhomolar": 3169.0, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 178.0, "T_units": "K", "p": 3.9393478817276356e-05, "p_units": "Pa", "rhomolar": 10580.06048163071, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 178.0, "T_units": "K", "p": 3.9393478817276356e-05, "p_units": "Pa", "rhomolar": 2.661765525110245e-05, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Assael-JPCRD-2012-Toluene", "critical": { "GAMMA": 0.05, "qD": 1613000000.0, "type": "simplified_Olchowy_Sengers", "zeta0": 2.2e-10 }, "dilute": { "A": [ 0.0058808, -6.1693e-05, 3.4151e-07, -3.042e-10, 1.2868e-13, -2.1303e-17 ], "B": [ 1 ], "T_reducing": 1, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2, 3, 4, 5 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ -0.051853, 0.0517449, 0.133846, -0.121902, -0.120446, 0.137748, 0.0530211, -0.0732792, -0.0100604, 0.0172914, 0.000633457, -0.00138585 ], "T_reducing": 591.75, "T_reducing_units": "K", "d": [ 1, 1, 2, 2, 3, 3, 4, 4, 5, 5, 6, 6 ], "rhomass_reducing": 291.992, "rhomass_reducing_units": "kg/m^3", "t": [ 0, -1, 0, -1, 0, -1, 0, -1, 0, -1, 0, -1 ], "type": "polynomial" } } } }