{ "ALIASES": [ "Tetradecamethylhexasiloxane", "TETRADECAMETHYLHEXASILOXANE" ], "ANCILLARIES": { "hL": { "A": [ -544247.5169136105, 965.5611099109119, 2.265108112347842, -0.011476532194468505, 2.7999666698473427e-05, -4.231440204487083e-08, 3.441345696831492e-11, -1.1698334558609737e-14 ], "B": [ 1, -0.001518466698217399 ], "Tmax": 653.1, "Tmin": 300.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 591.0445380308665, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -7170.709589363337, 2092.7477453392075, -18.058560861975767, 0.07304328411315003, -0.00016941599349062854, 2.3080363917853935e-07, -1.7251167272380725e-10, 5.4869130864878814e-14 ], "B": [ 1, -0.0015136764672033585 ], "Tmax": 653.1, "Tmin": 300.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 1633.1202791262149, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 653.2, "Tmax": 653.1999999999987, "Tmin": 300.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.05180314650858886, "n": [ 0.0015071534393996235, -9.893122006817906, 5.185077005280204, -11.792071053769893, -19.9746561375169, 17.061168452194554 ], "reducing_value": 877000.0, "t": [ 0.125, 0.991, 1.833, 2.613, 6.567, 7.481 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 653.2, "Tmax": 653.1999999999987, "Tmin": 300.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.2079082094630813, "n": [ -8.820757645392687, -0.6127877907019101, -26.27913889220715, 82.26487645325933, -215.38757534143105, 3331.0966160078788 ], "reducing_value": 877000.0, "t": [ 0.966, 2.034, 4.287, 6.824, 9.507, 17.511 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 653.2, "Tmax": 653.1999999999987, "Tmin": 300.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 1.555158530110734, "n": [ 0.4199342334140303, 3.429189550022302, -1.2153016662432385, 531.3835498635794, -2384171.350540733, 2608505.566671457 ], "reducing_value": 606.0605999999999, "t": [ 0.108, 0.596, 0.925, 11.068, 18.766, 18.948 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 653.2, "Tmax": 653.1999999999987, "Tmin": 300.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 2.5748730719093893, "n": [ 0.08238189107832351, -2.7968804624045727, -5.583554214981622, -20.6920569486233, 43.02594538959137, -1155.2598160559462 ], "reducing_value": 606.0605999999999, "t": [ 0.153, 0.35, 0.973, 4.373, 8.956, 18.867 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -1971.7334499320204, 10.161385051637275, -0.029646416313393497, 6.647705006182775e-05, -1.0261109151098012e-07, 9.564655688129383e-11, -4.78490568517415e-14, 9.43187841357287e-18 ], "B": [ 1, -0.0015180881906552309 ], "Tmax": 653.1, "Tmin": 300.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.9218271438873558, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 2019.4061050832422, -17.927674011372797, 0.07444055791521162, -0.0001786783102559166, 2.563221274862772e-07, -2.1005489691428655e-10, 8.383752672536888e-14, -9.247060475670748e-18 ], "B": [ 1, -0.001512886285582215 ], "Tmax": 653.1, "Tmin": 300.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.5577322673022085, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2014", "Tc": 653.2, "a": [ 0.040798 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.3323 ] } }, "CAS": "107-52-8", "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Colonna-FPE-2006", "STATES": { "hs_anchor": { "T": 718.5200000000001, "T_units": "K", "hmolar": 200661.8193872904, "hmolar_units": "J/mol", "p": 1706765.5807996977, "p_units": "Pa", "rhomolar": 560.1212459999996, "rhomolar_units": "mol/m^3", "smolar": 318.623193345212, "smolar_units": "J/mol/K" }, "reducing": { "T": 653.2, "T_units": "K", "hmolar": 131258.55136871376, "hmolar_units": "J/mol", "p": 877470, "p_units": "Pa", "rhomolar": 622.3569399999996, "rhomolar_units": "mol/m^3", "smolar": 219.42659313637026, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 300.0, "T_units": "K", "hmolar": -192165.54116670368, "hmolar_units": "J/mol", "p": 1.0933769828374593, "p_units": "Pa", "rhomolar": 1914.367067438578, "rhomolar_units": "mol/m^3", "smolar": -467.0281947611481, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 300.0, "T_units": "K", "hmolar": -114535.48031775115, "hmolar_units": "J/mol", "p": 1.093376953520636, "p_units": "Pa", "rhomolar": 0.0004383477380099088, "rhomolar_units": "mol/m^3", "smolar": -208.26132526448637, "smolar_units": "J/mol/K" } }, "T_max": 673, "T_max_units": "K", "Ttriple": 214.15, "Ttriple_units": "K", "accentric": 0.8246471472642924, "accentric_units": "-", "alpha0": [ { "a1": -8.139550790894862, "a2": 8.769441336438911, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 532.723355998617, "Tc": 653.2, "cp_over_R": -2.41398371417933, "type": "IdealGasHelmholtzCP0Constant" }, { "T0": 532.723355998617, "Tc": 653.2, "c": [ 0.268026640777671, -0.000157724988429812, 3.44219091723443e-08 ], "t": [ 1, 2, 3 ], "type": "IdealGasHelmholtzCP0PolyT" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 7, 2, 5, 1, 4, 3, 4 ], "l": [ 0, 0, 0, 0, 0, 0, 1, 1, 2, 2, 3, 3 ], "n": [ 1.18492421, -1.87465636, -0.06571351, -0.61812689, 0.19535804, 0.0005067874, 1.23544082, 0.049462708, -0.73685283, -0.19991438, -0.055118673, 0.028325885 ], "t": [ 0.25, 1.125, 1.5, 1.375, 0.25, 0.875, 0.625, 1.75, 3.625, 3.625, 14.5, 12 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.45899328, "molar_mass_units": "kg/mol", "p_max": 30000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "MD4M", "REFPROP_NAME": "MD4M", "STATES": { "critical": { "T": 653.2, "T_units": "K", "p": 877000.0, "p_units": "Pa", "rhomolar": 606.0605999999999, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 300.0, "T_units": "K", "hmolar": -192165.54116670368, "hmolar_units": "J/mol", "p": 1.0933769828374593, "p_units": "Pa", "rhomolar": 1914.367067438578, "rhomolar_units": "mol/m^3", "smolar": -467.0281947611481, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 300.0, "T_units": "K", "hmolar": -114535.48031775115, "hmolar_units": "J/mol", "p": 1.093376953520636, "p_units": "Pa", "rhomolar": 0.0004383477380099088, "rhomolar_units": "mol/m^3", "smolar": -208.26132526448637, "smolar_units": "J/mol/K" } } }