{ "ALIASES": [ "NH3", "ammonia", "R717", "AMMONIA" ], "ANCILLARIES": { "hL": { "A": [ -14511.67269519521, -426.2450032043393, 6.050438544960786, -0.03674017898167702, 0.00013143304778043063, -2.83820004449035e-07, 3.415834428726085e-10, -1.765842845168501e-13 ], "B": [ 1, -0.002449646152368599 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 175.28887250045227, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -39724.74349433728, 1733.8562104596845, -20.203609776535263, 0.12347570471138355, -0.00044905691612715014, 9.73581734413261e-07, -1.1647653834454674e-09, 5.943013421732148e-13 ], "B": [ 1, -0.0024452582292987025 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 360.5001261748321, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 405.4, "Tmax": 405.39999999999924, "Tmin": 195.495, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.05593199097324586, "n": [ 0.26451389481308607, -0.7119993599850943, -5.639513556769752, -0.4174451206068972, -4.182083153326861, 2.5564697890820667 ], "reducing_value": 11333000.0, "t": [ 0.575, 0.731, 0.973, 1.285, 4.213, 6.264 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 405.4, "Tmax": 405.39999999999924, "Tmin": 195.495, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.05181632089212851, "n": [ 0.0016131703802769548, 0.01339903644956835, -6.4517151211338994, -4.349105787320862, 1.8295554336003688, 7.011533373126273 ], "reducing_value": 11333000.0, "t": [ 0.108, 0.435, 0.971, 4.023, 4.944, 17.494 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 405.4, "Tmax": 405.39999999999924, "Tmin": 195.495, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.8982235822398099, "n": [ 0.6217530323464998, 116.65648581323893, -116.06575843470785, 2.722640286484237, -2.6080795358675433, 18.393705416728867 ], "reducing_value": 13211.777154312385, "t": [ 0.217, 0.713, 0.724, 1.557, 3.994, 9.339 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 405.4, "Tmax": 405.39999999999924, "Tmin": 195.495, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.802513430755436, "n": [ 1.2911157089516188, -1.4201786958021996, -145.4871281248165, 140.71212306607288, -3.147462914747211, -0.9907144617787934 ], "reducing_value": 13211.777154312385, "t": [ 0.037, 0.04, 0.584, 0.585, 2.858, 6.099 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -149.6472986423074, 0.38698412571100554, 0.00592073226099686, -5.250646383816199e-05, 2.107549282034896e-07, -4.796695517326019e-10, 5.959855018673447e-13, -3.155533468794041e-16 ], "B": [ 1, -0.0024497866640834387 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.42981085973895183, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 631.3189861533599, -6.9424600092972355, 0.03318088956507414, -6.831799581326684e-05, -4.46837518362279e-08, 5.224221403947832e-10, -9.895903905526437e-13, 6.451791765806702e-16 ], "B": [ 1, -0.0024452737468107525 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.8904987645505238, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 405.4, "a": [ 0.1028, -0.09453 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.211, 5.585 ] } }, "CAS": "7664-41-7", "ENVIRONMENTAL": { "ASHRAE34": "B2", "FH": 1, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 3, "Name": "Ammonia", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "TillnerRoth-DKV-1993", "STATES": { "hs_anchor": { "T": 445.94, "T_units": "K", "hmolar": 25012.280343289814, "hmolar_units": "J/mol", "p": 18635643.933141712, "p_units": "Pa", "rhomolar": 11890.599438881152, "rhomolar_units": "mol/m^3", "smolar": 75.46262589632495, "smolar_units": "J/mol/K" }, "reducing": { "T": 405.4, "T_units": "K", "p": 11333000, "p_units": "Pa", "rhomolar": 13211.77715431239, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 195.495, "T_units": "K", "p": 6091.223107269465, "p_units": "Pa", "rhomolar": 43035.339292073215, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 195.495, "T_units": "K", "p": 6091.223107574163, "p_units": "Pa", "rhomolar": 3.763506027013325, "rhomolar_units": "mol/m^3" } }, "T_max": 700, "T_max_units": "K", "Ttriple": 195.495, "Ttriple_units": "K", "accentric": 0.25601, "accentric_units": "-", "alpha0": [ { "a1": -15.81502, "a2": 4.255726, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 11.47434, -1.296211, 0.5706757 ], "t": [ 0.3333333333333333, -1.5, -1.75 ], "type": "IdealGasHelmholtzPower" }, { "a1": -0.965940085369186, "a2": 0.723282863334932, "reference": "OTH", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 2, 1, 4, 1, 15, 3, 3, 1, 8, 2, 1, 8, 1, 2, 3, 2, 4, 3, 1, 2, 4 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 3, 3, 3, 3 ], "n": [ 0.04554431, 0.7238548, 0.0122947, -1.858814, 2.141882e-11, -0.0143002, 0.3441324, -0.2873571, 2.352589e-05, -0.03497111, 0.02397852, 0.001831117, -0.04085375, 0.2379275, -0.03548972, -0.1823729, 0.02281556, -0.006663444, -0.008847486, 0.002272635, -0.0005588655 ], "t": [ -0.5, 0.5, 1, 1.5, 3, 0, 3, 4, 4, 5, 3, 5, 6, 8, 8, 10, 10, 5, 7.5, 15, 30 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.314471, "gas_constant_units": "J/mol/K", "molar_mass": 0.01703026, "molar_mass_units": "kg/mol", "p_max": 1000000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "Ammonia", "REFPROP_NAME": "AMMONIA", "STATES": { "critical": { "T": 405.4, "T_units": "K", "p": 11333000.0, "p_units": "Pa", "rhomolar": 13211.777154312385, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 195.495, "T_units": "K", "p": 6091.223107269465, "p_units": "Pa", "rhomolar": 43035.339292073215, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 195.495, "T_units": "K", "p": 6091.223107574163, "p_units": "Pa", "rhomolar": 3.763506027013325, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Tufeu-BBPC-1984", "critical": { "hardcoded": "Ammonia" }, "dilute": { "A": [ 0.03589, -0.000175, 4.551e-07, 1.685e-10, -4.828e-13 ], "B": [ 1.0 ], "T_reducing": 1, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2, 3, 4 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ 0.03808645, 0.06647986, -0.0300295, 0.00998779 ], "T_reducing": 1, "T_reducing_units": "K", "d": [ 1, 2, 3, 4 ], "rhomass_reducing": 235, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0 ], "type": "polynomial" } }, "viscosity": { "BibTeX": "Fenghour-JPCRD-1995", "_note": "There is a mysterious factor of 100 missing from the Fenghour equation for the dilute gas. From REFPROP fluid file: !=0.021357*SQRT(MW)*(unknown factor of 100) [Chapman-Enskog term]", "dilute": { "C": 2.1357e-06, "a": [ 4.9931822, -0.61122364, 0.0, 0.18535124, -0.11160946 ], "molar_mass": 0.01703026, "molar_mass_units": "kg/mol", "t": [ 0, 1, 2, 3, 4 ], "type": "collision_integral" }, "epsilon_over_k": 386, "epsilon_over_k_units": "K", "higher_order": { "T_reduce": 405.4, "T_reduce_units": "K", "a": [ 4.005040600989671e-06, -1.4107915123955129e-05, 3.4760743039321816e-05, 4.631310990138071e-06, -3.937374461785061e-06, -1.200075068367531e-05, 1.9284977991745303e-06 ], "d1": [ 3, 3, 2, 4, 4, 2, 4 ], "d2": [ 1 ], "f": [ 0.0 ], "g": [ 1 ], "gamma": [ 0, 0, 0, 0, 0, 0, 0 ], "h": [ 0 ], "l": [ 1, 1, 1, 1, 1, 1, 1 ], "p": [ 1 ], "q": [ 0 ], "rhomolar_reduce": 13211.8, "rhomolar_reduce_units": "mol/m^3", "t1": [ 0, 1, 2, 2, 3, 4, 4 ], "t2": [ 0 ], "type": "modified_Batschinski_Hildebrand" }, "initial_density": { "b": [ -1.7999496, 46.692621, -534.60794, 3360.4074, -13019.164, 33414.23, -58711.743, 71426.686, -59834.012, 33652.741, -12027.35, 2434.8205, -208.07957 ], "t": [ -0.0, -0.5, -1.0, -1.5, -2.0, -2.5, -3.0, -3.5, -4.0, -4.5, -5.0, -5.5, -6.0 ], "type": "Rainwater-Friend" }, "sigma_eta": 2.957e-10, "sigma_eta_units": "m" } } }