{ "ALIASES": [ "isobutane", "Isobutane", "ISOBUTANE", "R600A", "R600a" ], "ANCILLARIES": { "hL": { "A": [ -58829.34158938623, 170.5451796929163, 0.6162711654306408, -0.0053018559436187425, 2.0943523112936617e-05, -5.0332329315311905e-08, 6.651481526074004e-11, -3.797381783161163e-14 ], "B": [ 1, -0.002421824472244289 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 303.0532870873549, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 29860.67391574815, -6.670353030511229, -1.6393845888763268, 0.013392367462910941, -5.8029757085730367e-05, 1.4457295673686832e-07, -1.9569457108152776e-10, 1.128629830081101e-13 ], "B": [ 1, -0.0024207623619944708 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 703.6829473859673, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "Buecker-JPCRD-2006B", "T_m": 113.55, "parts": [ { "T_0": 113.73, "T_max": 127, "T_min": 113.73, "a": [ 1953637130.9 ], "p_0": 0.0219, "t": [ 6.12 ] } ], "type": "polynomial_in_Tr" }, "pL": { "T_r": 407.817, "Tmax": 407.81699999999915, "Tmin": 113.73000000000002, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.025709437298837567, "n": [ 0.4893216106119911, -6.629467799666135, 0.27190214385479383, -0.013142408151644676, -3.250782332365992, -0.43922387424664594 ], "reducing_value": 3629000.0, "t": [ 0.83, 0.964, 2.071, 2.407, 3.825, 15.511 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 407.817, "Tmax": 407.81699999999915, "Tmin": 113.73000000000002, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.019699846909193575, "n": [ -48.02915589537987, 43.34653680580028, -1.4421317283854331, -3.1322275225078413, 5.203481182010376, -6.173022897817098 ], "reducing_value": 3629000.0, "t": [ 1.082, 1.108, 1.463, 4.045, 13.157, 14.042 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 407.817, "Tmax": 407.81699999999915, "Tmin": 113.73000000000002, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.26628224832738745, "n": [ 2.0418147224188545, 0.4363922893974425, 1.915261424521202, -2.1807762762122045, 1.068664850362356, -6.816247938174933 ], "reducing_value": 3879.756788283995, "t": [ 0.356, 0.824, 3.142, 3.696, 6.863, 18.441 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 407.817, "Tmax": 407.81699999999915, "Tmin": 113.73000000000002, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.4922366156330571, "n": [ -2.8656855559386294, 0.7330458189287201, -4.254613288675131, 2.9956235180226516, -5.671641417558254, 0.14361022568133902 ], "reducing_value": 3879.756788283995, "t": [ 0.37, 0.502, 1.021, 2.003, 3.403, 10.717 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -343.0315785084629, 3.0682816312100214, -0.01632828350995562, 6.602197691846063e-05, -1.8407331130955436e-07, 3.2273113331974106e-10, -3.205767809115736e-13, 1.358686041344578e-16 ], "B": [ 1, -0.002417095837950523 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.8029163090499019, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1116.4949820862637, -19.569418706926673, 0.17278224442122414, -0.0009207053379985635, 3.058212117538665e-06, -6.1998714249116026e-09, 7.024193243467152e-12, -3.4072896284755546e-15 ], "B": [ 1, -0.0023698092291068932 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.580887010861343, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 407.81, "a": [ -0.01639, 0.06121 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 2.102, 1.304 ] } }, "CAS": "75-28-5", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 4, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "IsoButane", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Buecker-JPCRD-2006B", "STATES": { "hs_anchor": { "T": 448.59100000000007, "T_units": "K", "hmolar": 43954.8222411498, "hmolar_units": "J/mol", "p": 5887949.640936111, "p_units": "Pa", "rhomolar": 3491.7811094555955, "rhomolar_units": "mol/m^3", "smolar": 144.5636715682779, "smolar_units": "J/mol/K" }, "reducing": { "T": 407.81, "T_units": "K", "p": 3629000, "p_units": "Pa", "rhomolar": 3879.756788283995, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 113.73, "T_units": "K", "p": 0.022891027562310824, "p_units": "Pa", "rhomolar": 12737.62445835364, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 113.73, "T_units": "K", "p": 0.02289066053179942, "p_units": "Pa", "rhomolar": 2.4207430191901677e-05, "rhomolar_units": "mol/m^3" } }, "T_max": 575, "T_max_units": "K", "Ttriple": 113.73, "Ttriple_units": "K", "accentric": 0.183531783208, "accentric_units": "-", "alpha0": [ { "a1": 11.60865546, "a2": -5.29450411, "type": "IdealGasHelmholtzLead" }, { "a": 3.05956619, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 4.94641014, 4.09475197, 15.6632824, 9.73918122 ], "t": [ 0.951277902, 2.387895885, 4.346904269, 10.36885864 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -17.6081648486994, "a2": 10.3134499204439, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 4, 4, 1, 1, 2, 7, 8, 8, 1, 2, 3, 3, 4, 5, 5, 10, 2, 6 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 2, 3, 3 ], "n": [ 2.0686820727966, -3.6400098615204, 0.51968754427244, 0.17745845870123, -0.12361807851599, 0.045145314010528, 0.03047647996598, 0.75508387706302, -0.85885381015629, 0.036324009830684, -0.01954879945055, -0.004445239290496, 0.004641076366646, -0.071444097992825, -0.080765060030713, 0.15560460945053, 0.0020318752160332, -0.10624883571689, 0.039807690546305, 0.016371431292386, 0.00053212200682628, -0.0078681561156387, -0.0030981191888963 ], "t": [ 0.5, 1, 1.5, 0, 0.5, 0.5, 0.75, 2, 2.5, 2.5, 1.5, 1, 1.5, 4, 7, 3, 7, 3, 1, 6, 0, 6, 13 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 150, 200 ], "d": [ 1, 2 ], "epsilon": [ 0.85, 1 ], "eta": [ 10, 10 ], "gamma": [ 1.16, 1.13 ], "n": [ -0.042276036810382, -0.0053001044558079 ], "t": [ 2, 0 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 407.817, "T_min": 406.8534813947396, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ -9.941703745512649e-10, 1.1401780743865456e-05, -0.04357798580431196, 463.3231742084145 ], "cV": [ 0.0, -1.0815601793791963e-06, 0.00839238089576816, 391.53680162488934 ], "rhomolar_max": 4815.639002152002, "rhomolar_min": 2935.903033135107 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.0581222, "molar_mass_units": "kg/mol", "p_max": 35000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "IsoButane", "REFPROP_NAME": "ISOBUTAN", "STATES": { "critical": { "T": 407.817, "T_units": "K", "p": 3629000.0, "p_units": "Pa", "rhomolar": 3879.756788283995, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 113.73, "T_units": "K", "p": 0.022891027562310824, "p_units": "Pa", "rhomolar": 12737.62445835364, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 113.73, "T_units": "K", "p": 0.02289066053179942, "p_units": "Pa", "rhomolar": 2.4207430191901677e-05, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Perkins-JCED-2002-Isobutane", "critical": { "GAMMA": 0.0496, "R0": 1.03, "gamma": 1.239, "qD": 1520540217.5, "type": "simplified_Olchowy_Sengers", "zeta0": 1.94e-10 }, "dilute": { "A": [ -0.00237901, 0.0106601, 0.0215811 ], "B": [ 1.0 ], "T_reducing": 407.85, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ -0.0411789, 0.146805, -0.11919, 0.0410226, -0.00488704, 0.0476346, -0.128445, 0.107565, -0.0385968, 0.00520901 ], "T_reducing": 407.85, "T_reducing_units": "K", "d": [ 1, 2, 3, 4, 5, 1, 2, 3, 4, 5 ], "rhomass_reducing": 224.4, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0, 0, -1, -1, -1, -1, -1 ], "type": "polynomial" } }, "viscosity": { "BibTeX": "Vogel-IJT-1999", "dilute": { "C": 2.1357e-08, "a": [ 0.53583008, -0.4562963, 0.049911282 ], "molar_mass": 0.0581222, "molar_mass_units": "kg/mol", "t": [ 0, 1, 2 ], "type": "collision_integral" }, "epsilon_over_k": 307.55, "epsilon_over_k_units": "K", "higher_order": { "T_reduce": 407.817, "T_reduce_units": "K", "a": [ 0.000103511763411, -0.000312670896234, 0.000145253750239, -0.000210649894193, 0.000386269696509, -0.000214963015527, 0.00011258036092, -0.000223242033154, 0.000119114788598, -1.819097459e-05, 3.60438957232e-05, -2.1396018405e-05 ], "d1": [ 2, 2, 2, 3, 3, 3, 4, 4, 4, 5, 5, 5 ], "d2": [ 1 ], "f": [ 0.0019403760699 ], "g": [ 2.33859774637, 2.352551508384381 ], "gamma": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "h": [ 0, -0.5 ], "l": [ 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1 ], "p": [ 1 ], "q": [ 0 ], "rhomolar_reduce": 3860, "rhomolar_reduce_units": "mol/m^3", "t1": [ 0, 1, 2, 0, 1, 2, 0, 1, 2, 0, 1, 2 ], "t2": [ 0 ], "type": "modified_Batschinski_Hildebrand" }, "initial_density": { "b": [ -19.572881, 219.73999, -1015.3226, 2471.01251, -3375.1717, 2491.6597, -787.26086, 14.085455, -0.34664158 ], "t": [ 0, -0.25, -0.5, -0.75, -1.0, -1.25, -1.5, -2.5, -5.5 ], "type": "Rainwater-Friend" }, "sigma_eta": 4.6445e-10, "sigma_eta_units": "m" } } }