{ "ALIASES": [ "R134A" ], "ANCILLARIES": { "hL": { "A": [ -51529.55944985408, 50.33864353229947, 2.7663766395140725, -0.023225752665323663, 0.00010276136869041563, -2.6598290728635957e-07, 3.7424760510383004e-10, -2.2250596915286053e-13 ], "B": [ 1, -0.00264918809216325 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 252.39784198293637, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -4754.471142945848, 1141.3456669145435, -16.658811229664057, 0.11778319054931755, -0.00048351125451228354, 1.1680419844297762e-06, -1.5454547499218421e-09, 8.684345855482601e-13 ], "B": [ 1, -0.0026480942567852117 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 577.732277402524, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 374.21, "Tmax": 374.20999999999935, "Tmin": 169.85, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.017350580991559728, "n": [ -7.752261946226358, 1.1077288842347188, -3.6878039562081835, 11.428865438173393, 58.41970100091463, -7.937848917436551 ], "reducing_value": 4059280.0, "t": [ 0.994, 1.193, 3.431, 11.757, 16.373, 8.838 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 374.21, "Tmax": 374.20999999999935, "Tmin": 169.85, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.00920528154990663, "n": [ 0.4331478287291047, -9.090302559074352, 2.1476074125217703, -1.557687007603464, -3.5020328972698604, 14.958442337201044 ], "reducing_value": 4059280.0, "t": [ 0.845, 0.99, 1.14, 2.651, 4.507, 17.235 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 374.21, "Tmax": 374.20999999999935, "Tmin": 169.85, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 4.694601438771184, "n": [ 18.772731940930015, -51.49939472178225, 40.793536440596085, -1481.6500471538966, 1600.534434298925, -67338.52423732559 ], "reducing_value": 5017.053, "t": [ 0.673, 0.994, 1.257, 5.783, 5.943, 19.94 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 374.21, "Tmax": 374.20999999999935, "Tmin": 169.85, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 2.5443795326392737, "n": [ -5.147386240766544, 5.34618043286371, -7.611015272838434, -28.85436432788653, -9.079306067130748, 64.0 ], "reducing_value": 5017.053, "t": [ 0.476, 0.966, 1.321, 8.491, 13.463, 13.463 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -399.07686533095074, 4.391304989695765, -0.02671688302927355, 0.00010872889126430847, -2.7674555501406144e-07, 3.953319072725693e-10, -2.5323022972830746e-13, 1.9977491693793718e-17 ], "B": [ 1, -0.002648599206785997 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.686259771424508, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1015.7440679438349, -15.282436011854726, 0.10981502535780535, -0.0004583136790622338, 1.1310586460028706e-06, -1.5501591857488956e-09, 9.520591431071518e-13, -7.45821300198014e-17 ], "B": [ 1, -0.0026473697775543756 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.5753757588779433, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 374.21, "a": [ 0.05801 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.241 ] } }, "CAS": "811-97-2", "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 1, "GWP100": 1430.0, "GWP20": 3830.0, "GWP500": 435.0, "HH": 1, "Name": "R134a", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "TillnerRoth-JPCRD-1994", "STATES": { "hs_anchor": { "T": 411.598, "T_units": "K", "hmolar": 45468.086192270304, "hmolar_units": "J/mol", "p": 6858750.808053112, "p_units": "Pa", "rhomolar": 4480.9471539000015, "rhomolar_units": "mol/m^3", "smolar": 172.44139866136513, "smolar_units": "J/mol/K" }, "reducing": { "T": 374.18, "T_units": "K", "p": 4059280, "p_units": "Pa", "rhomolar": 4978.830171000001, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 169.85, "T_units": "K", "p": 389.56378913655766, "p_units": "Pa", "rhomolar": 15594.20037993484, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 169.85, "T_units": "K", "p": 389.56378860748816, "p_units": "Pa", "rhomolar": 0.2761122800115168, "rhomolar_units": "mol/m^3" } }, "T_max": 455, "T_max_units": "K", "Ttriple": 169.85, "Ttriple_units": "K", "accentric": 0.32684, "accentric_units": "-", "alpha0": [ { "a1": -1.019535, "a2": 9.047135, "type": "IdealGasHelmholtzLead" }, { "a": -1.629789, "type": "IdealGasHelmholtzLogTau" }, { "n": [ -9.723916, -3.92717 ], "t": [ -0.5, -0.75 ], "type": "IdealGasHelmholtzPower" } ], "alphar": [ { "d": [ 2, 1, 3, 6, 6, 1, 1, 2, 5, 2, 2, 4, 1, 4, 1, 2, 4, 1, 5, 3, 10 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 2, 2, 2, 2, 2, 2, 3, 3, 3, 4 ], "n": [ 0.05586817, 0.498223, 0.02458698, 0.0008570145, 0.0004788584, -1.800808, 0.2671641, -0.04781652, 0.01423987, 0.3324062, -0.007485907, 0.0001017263, -0.5184567, -0.08692288, 0.2057144, -0.005000457, 0.0004603262, -0.003497836, 0.006995038, -0.01452184, -0.0001285458 ], "t": [ -0.5, 0, 0, 0, 1.5, 1.5, 2, 2, 1, 3, 5, 1, 5, 5, 6, 10, 10, 10, 18, 22, 50 ], "type": "ResidualHelmholtzPower" } ], "critical_region_splines": { "T_max": 374.21, "T_min": 373.5716150640238, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ -3.1676460727923154e-10, 4.632248820128229e-06, -0.022560800178147874, 410.803318485873 ], "cV": [ 3.734362612529562e-10, -5.680300209122729e-06, 0.02879764276811166, 325.5497395319938 ], "rhomolar_max": 6152.557816507652, "rhomolar_min": 3872.298405322532 }, "gas_constant": 8.314471, "gas_constant_units": "J/mol/K", "molar_mass": 0.102032, "molar_mass_units": "kg/mol", "p_max": 70000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R134a", "REFPROP_NAME": "R134A", "STATES": { "critical": { "T": 374.21, "T_units": "K", "p": 4059280.0, "p_units": "Pa", "rhomolar": 5017.053, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 169.85, "T_units": "K", "p": 389.56378913655766, "p_units": "Pa", "rhomolar": 15594.20037993484, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 169.85, "T_units": "K", "p": 389.56378860748816, "p_units": "Pa", "rhomolar": 0.2761122800115168, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "conductivity": { "BibTeX": "McLinden-IJR-2000", "critical": { "GAMMA": 0.0496, "R0": 1.03, "gamma": 1.239, "qD": 1892020000.0, "type": "simplified_Olchowy_Sengers", "zeta0": 1.94e-10 }, "dilute": { "A": [ -0.0105248, 8.00982e-05 ], "B": [ 1.0 ], "T_reducing": 1, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ 0.0037740609300000003, 0.010534223865, -0.002952794565, 0.00128672592 ], "T_reducing": 1, "T_reducing_units": "K", "_note": "from v4.x : delta = rho/(5.049886*102.032); // Does not use either the reduce.rho value or crit.rho value !!! Or the value listed in Huber, 2003 either", "d": [ 1, 2, 3, 4 ], "rhomass_reducing": 515.249968352, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0 ], "type": "polynomial" } }, "viscosity": { "BibTeX": "Huber-IECR-2003", "dilute": { "C": 2.1357e-08, "a": [ 0.355404, -0.464337, 0.0257353 ], "molar_mass": 0.102031, "molar_mass_units": "kg/mol", "t": [ 0, 1, 2 ], "type": "collision_integral" }, "epsilon_over_k": 299.363, "epsilon_over_k_units": "K", "higher_order": { "T_reduce": 374.21, "T_reduce_units": "K", "a": [ -2.06900719e-05, 3.56029549e-07, 2.11101816e-06, 1.39601415e-05, -4.5643502e-06, -3.51593275e-06 ], "d1": [ 1, 2, 2, 2, 2, 3 ], "d2": [ 0 ], "f": [ 0.00021476332 ], "g": [ 3.163695636 ], "gamma": [ 0, 0, 0, 0, 0, 0 ], "h": [ 0 ], "l": [ 1, 1, 1, 1, 1, 1 ], "p": [ 1, -0.0890173375, 0.100035295 ], "q": [ 0, -1, -2 ], "rhomolar_reduce": 5017.053, "rhomolar_reduce_units": "mol/m^3", "t1": [ 0, 6, 2, 0.5, -2, 0 ], "t2": [ 0 ], "type": "modified_Batschinski_Hildebrand" }, "initial_density": { "b": [ -19.572881, 219.73999, -1015.3226, 2471.01251, -3375.1717, 2491.6597, -787.26086, 14.085455, -0.34664158 ], "t": [ 0, -0.25, -0.5, -0.75, -1.0, -1.25, -1.5, -2.5, -5.5 ], "type": "Rainwater-Friend" }, "sigma_eta": 4.68932e-10, "sigma_eta_units": "m" } } }