{ "ALIASES": [ "R227ea" ], "ANCILLARIES": { "hL": { "A": [ -70529.49388083724, 159.00286293881294, 1.9477112821133424, -0.015742436119680535, 6.503327374350112e-05, -1.6235079946814059e-07, 2.2440476689088385e-10, -1.3335174087849645e-13 ], "B": [ 1, -0.0026405490089791137 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 277.0109295672446, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 25017.15093182292, 342.63932739440236, -7.164716455383537, 0.05540352425415902, -0.0002410327195377668, 6.113294724271282e-07, -8.463717460177629e-10, 4.977774056045432e-13 ], "B": [ 1, -0.002641080919597314 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 680.0792870368666, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.010578535119587507, "n": [ -7.109161477135856, -0.43619976868074284, 5.934481777381213, 39.44778344273422, -41.38716737709299, -8.362365023243223 ], "reducing_value": 2925000.0, "t": [ 0.987, 1.312, 1.927, 3.476, 3.578, 2.248 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.014130102564613445, "n": [ 10.093738859898867, -16.82115838958235, -0.07297852700598685, -14.198048704342424, 50.7816690049031, -41.683491945535145 ], "reducing_value": 2925000.0, "t": [ 0.889, 0.919, 1.495, 3.227, 3.53, 3.663 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.2727146007857062, "n": [ -0.037180636267061765, 2.2565260411325867, 16.777771835065064, -22.313716095609287, 6.793310681390873, -10.89306852102585 ], "reducing_value": 3495.0, "t": [ 0.12, 0.35, 2.248, 2.467, 3.208, 12.192 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 374.9, "Tmax": 374.8999999999993, "Tmin": 146.35, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.7920968700624531, "n": [ -6.947050225285722, 123.4065348806111, -122.5651518640378, -9.994885618440552, 3.478879029818986, 245.61726193605475 ], "reducing_value": 3495.0, "t": [ 0.434, 0.676, 0.691, 4.287, 4.613, 19.251 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -474.5429739715327, 4.4728857918027725, -0.022836763290548345, 8.347157451021833e-05, -2.0462924729044817e-07, 2.9761536810986294e-10, -2.1509416378987727e-13, 4.2508932366321974e-17 ], "B": [ 1, -0.0026396149237877904 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.7552171726110544, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1215.2312109614159, -20.27820958422197, 0.16637169768810653, -0.0008193674686473394, 2.5126906259175458e-06, -4.698552937835742e-09, 4.896979029087763e-12, -2.169217117689509e-15 ], "B": [ 1, -0.002636565779250786 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.9874808798268795, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 374.9, "a": [ 0.06127, -0.009516, -0.00192 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.192, 0.9795, 1.421 ] } }, "CAS": "431-89-0", "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 0, "GWP100": 3220.0, "GWP20": 5310.0, "GWP500": 1040.0, "HH": 1, "Name": "R227EA", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "McLinden-PREPRINT-2013", "STATES": { "hs_anchor": { "T": 412.39, "T_units": "K", "hmolar": 67624.77855894624, "hmolar_units": "J/mol", "p": 4993978.5487574795, "p_units": "Pa", "rhomolar": 3145.5, "rhomolar_units": "mol/m^3", "smolar": 265.3616003859794, "smolar_units": "J/mol/K" }, "reducing": { "T": 374.9, "T_units": "K", "p": 2925000, "p_units": "Pa", "rhomolar": 3495, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 146.35, "T_units": "K", "p": 7.331568414509409, "p_units": "Pa", "rhomolar": 11046.705899800065, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 146.35, "T_units": "K", "p": 7.331567153207764, "p_units": "Pa", "rhomolar": 0.006025348183498283, "rhomolar_units": "mol/m^3" } }, "T_max": 475, "T_max_units": "K", "Ttriple": 146.35, "Ttriple_units": "K", "accentric": 0.3576047602255754, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 11.43, 12.83 ], "t": [ 1.07495332088557, 3.809015737530008 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -15.8290880642424, "a2": 11.087938006383, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 2, 2, 4, 1, 3, 6, 6, 2, 3 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 1, 2, 2 ], "n": [ 2.024341, -2.60593, 0.4957216, -0.824082, 0.06543703, -1.02461, 0.6247065, 0.2997521, -0.353917, -1.232043, -0.8824483 ], "t": [ 0.34, 0.77, 0.36, 0.9, 1, 2.82, 2.1, 0.9, 1.13, 3.8, 2.75 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 1.72, 5.2, 2.31, 1.02, 5.63, 50.9, 1.56 ], "d": [ 1, 2, 1, 1, 4, 2, 1 ], "epsilon": [ 1.13, 0.71, 1.2, 1.7, 0.546, 0.896, 0.747 ], "eta": [ 0.83, 2.19, 2.44, 3.65, 8.88, 8.23, 2.01 ], "gamma": [ 0.414, 1.051, 1.226, 1.7, 0.904, 1.42, 0.926 ], "n": [ 0.1349661, -0.2662928, 0.1764733, 0.01536163, -0.004667185, -11.70854, 0.9114512 ], "t": [ 1.5, 2.5, 2.5, 5.4, 4, 1, 3.5 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 374.90000000000003, "T_min": 374.89999999993785, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -4.848721869600648e-09, 374.90001694628296 ], "cV": [ 0.0, 0.0, 4.855705508254663e-09, 374.8999830293093 ], "rhomolar_max": 3495.0128237303156, "rhomolar_min": 3494.9871917055066 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.17002886, "molar_mass_units": "kg/mol", "p_max": 60000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R227EA", "REFPROP_NAME": "R227EA", "STATES": { "critical": { "T": 374.9, "T_units": "K", "p": 2925000.0, "p_units": "Pa", "rhomolar": 3495.0, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 146.35, "T_units": "K", "p": 7.331568414509409, "p_units": "Pa", "rhomolar": 11046.705899800065, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 146.35, "T_units": "K", "p": 7.331567153207764, "p_units": "Pa", "rhomolar": 0.006025348183498283, "rhomolar_units": "mol/m^3" } } }