{ "ALIASES": [ "nButane", "butane", "BUTANE", "N-BUTANE" ], "ANCILLARIES": { "hL": { "A": [ -65886.3988155301, 194.03150777024956, 0.7618471242184737, -0.007238665437438199, 2.975560287758703e-05, -7.011824059908797e-08, 8.837122339131426e-11, -4.707566415451115e-14 ], "B": [ 1, -0.002329305768690246 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 314.03204282103616, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 30829.44163089603, 35.261609011609515, -2.270444880862389, 0.01756146650359341, -7.263540689149082e-05, 1.7187182205949555e-07, -2.198531055967536e-10, 1.1914292060073683e-13 ], "B": [ 1, -0.0023264106088001983 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 731.8295330394551, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "Buecker-JPCRD-2006B", "T_m": 135.23, "parts": [ { "T_0": 134.895, "T_max": 163.9, "T_min": 134.895, "a": [ 558558236.4 ], "p_0": 0.653, "t": [ 2.206 ] } ], "type": "polynomial_in_Tr" }, "pL": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02500890020828983, "n": [ -5.805352213973263, -11.51448089471748, 18.238781113551752, -7.570052478022171, -1.4755071099444654, -1.328641564172384 ], "reducing_value": 3796000.0, "t": [ 0.978, 1.371, 1.499, 1.748, 4.108, 4.752 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02366371569104686, "n": [ 0.06986482880463143, -6.689091326409199, 4.774874567188075, -5.7054710938841655, 1.8437119133933968, -3.735372218319482 ], "reducing_value": 3796000.0, "t": [ 0.743, 0.984, 1.886, 2.16, 3.286, 4.231 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.21170510433432543, "n": [ 7.6544950329552, -16.928503641708495, 14.176327512939299, -2.3511736019127136, 5.431931351600508, -13.286388570143172 ], "reducing_value": 3922.7696129878086, "t": [ 0.501, 0.742, 0.917, 1.387, 9.328, 12.623 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 1.1838723681035446, "n": [ -3.756767939636941, -2.819084986331516, 2.3817493893256763, -27.835034497609627, 409.95394459399324, -539.2138907428523 ], "reducing_value": 3922.7696129878086, "t": [ 0.448, 1.717, 4.443, 7.472, 13.095, 14.725 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -394.4519347268143, 3.7459801302719535, -0.0206813795788915, 8.035838614191504e-05, -2.049673884350767e-07, 3.2044202062707795e-10, -2.7837552009214993e-13, 1.0119549511340321e-16 ], "B": [ 1, -0.0023272323951365774 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.7816889213509164, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1077.452721347132, -17.329710140771073, 0.13927213637031544, -0.000674449132643124, 2.037270680030572e-06, -3.762346262470921e-09, 3.890972571785506e-12, -1.7256655966592132e-15 ], "B": [ 1, -0.002308765436367146 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.255701017236195, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 425.125, "a": [ 0.05138 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.209 ] } }, "CAS": "106-97-8", "ENVIRONMENTAL": { "ASHRAE34": "A3", "FH": 4, "GWP100": 3.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "n-Butane", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Buecker-JPCRD-2006B", "STATES": { "hs_anchor": { "T": 467.63750000000005, "T_units": "K", "hmolar": 47861.671413925265, "hmolar_units": "J/mol", "p": 6189994.4837319525, "p_units": "Pa", "rhomolar": 3530.492651689028, "rhomolar_units": "mol/m^3", "smolar": 152.79309067928807, "smolar_units": "J/mol/K" }, "reducing": { "T": 425.125, "T_units": "K", "p": 3796000, "p_units": "Pa", "rhomolar": 3922.769612987809, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 134.895, "T_units": "K", "p": 0.6656573875403293, "p_units": "Pa", "rhomolar": 12645.062133275143, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 134.895, "T_units": "K", "p": 0.6656588871711283, "p_units": "Pa", "rhomolar": 0.0005935026998216393, "rhomolar_units": "mol/m^3" } }, "T_max": 340, "T_max_units": "K", "Ttriple": 134.895, "Ttriple_units": "K", "accentric": 0.200810094644, "accentric_units": "-", "alpha0": [ { "a1": 12.54882924, "a2": -5.46976878, "type": "IdealGasHelmholtzLead" }, { "a": 3.24680487, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 5.54913289, 11.4648996, 7.59987584, 9.66033239 ], "t": [ 0.774840445, 3.340602552, 4.970513096, 9.975553778 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -17.9737888338978, "a2": 10.3892639083242, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 4, 4, 1, 1, 2, 7, 8, 8, 1, 2, 3, 3, 4, 5, 5, 10, 2, 6 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 2, 3, 3 ], "n": [ 2.5536998241635, -4.4585951806696, 0.82425886369063, 0.11215007011442, -0.035910933680333, 0.016790508518103, 0.032734072508724, 0.95571232982005, -1.0003385753419, 0.085581548803855, -0.025147918369616, -0.0015202958578918, 0.004706068232642, -0.097845414174006, -0.04831790415876, 0.17841271865468, 0.018173836739334, -0.11399068074953, 0.019329896666669, 0.001157587740101, 0.00015253808698116, -0.043688558458471, -0.0082403190629989 ], "t": [ 0.5, 1, 1.5, 0, 0.5, 0.5, 0.75, 2, 2.5, 2.5, 1.5, 1, 1.5, 4, 7, 3, 7, 3, 1, 6, 0, 6, 13 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 150, 200 ], "d": [ 1, 2 ], "epsilon": [ 0.85, 1 ], "eta": [ 10, 10 ], "gamma": [ 1.16, 1.13 ], "n": [ -0.028390056949441, 0.0014904666224681 ], "t": [ 2, 0 ], "type": "ResidualHelmholtzGaussian" } ], "critical_region_splines": { "T_max": 425.125, "T_min": 425.12499999999653, "_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K", "cL": [ 0.0, 0.0, -1.594275970224201e-09, 425.12500625397735 ], "cV": [ 0.0, 0.0, 1.671186275109249e-09, 425.12499344432126 ], "rhomolar_max": 3922.7717979270105, "rhomolar_min": 3922.767549762673 }, "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.0581222, "molar_mass_units": "kg/mol", "p_max": 12000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "n-Butane", "REFPROP_NAME": "BUTANE", "STATES": { "critical": { "T": 425.125, "T_units": "K", "p": 3796000.0, "p_units": "Pa", "rhomolar": 3922.7696129878086, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 134.895, "T_units": "K", "p": 0.6656573875403293, "p_units": "Pa", "rhomolar": 12645.062133275143, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 134.895, "T_units": "K", "p": 0.6656588871711283, "p_units": "Pa", "rhomolar": 0.0005935026998216393, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "conductivity": { "BibTeX": "Perkins-JCED-2002-nButane", "critical": { "GAMMA": 0.0496, "R0": 1.03, "gamma": 1.239, "qD": 1142400182.0, "type": "simplified_Olchowy_Sengers", "zeta0": 1.94e-10 }, "dilute": { "A": [ 0.00162676, 0.000975703, 0.0289887 ], "B": [ 1.0 ], "T_reducing": 425.16, "T_reducing_units": "K", "m": [ 0 ], "n": [ 0, 1, 2 ], "type": "ratio_of_polynomials" }, "residual": { "B": [ -0.0304337, 0.16582, -0.148144, 0.05255, -0.00629367, 0.0418357, -0.147163, 0.133542, -0.0485489, 0.00644307 ], "T_reducing": 425.16, "T_reducing_units": "K", "d": [ 1, 2, 3, 4, 5, 1, 2, 3, 4, 5 ], "rhomass_reducing": 227.8, "rhomass_reducing_units": "kg/m^3", "t": [ 0, 0, 0, 0, 0, -1, -1, -1, -1, -1 ], "type": "polynomial" } }, "viscosity": { "BibTeX": "Vogel-HTHP-1999", "dilute": { "C": 2.1357e-08, "a": [ 0.17067154, -0.48879666, 0.039038856 ], "molar_mass": 0.0581222, "molar_mass_units": "kg/mol", "t": [ 0, 1, 2 ], "type": "collision_integral" }, "epsilon_over_k": 280.51, "epsilon_over_k_units": "K", "higher_order": { "T_reduce": 425.125, "T_reduce_units": "K", "a": [ -5.47737770846e-05, 5.80898623034e-05, 3.52658446259e-05, -3.96682203832e-05, -1.83729542151e-06, 0.0, -8.33262985358e-07, 1.93837020663e-06 ], "d1": [ 2, 2, 3, 3, 4, 4, 5, 5 ], "d2": [ 1 ], "f": [ 0.000188075903903 ], "g": [ 2.30873963359, 2.0340403725423957 ], "gamma": [ 0, 0, 0, 0, 0, 0, 0, 0 ], "h": [ 0, -0.5 ], "l": [ 1, 1, 1, 1, 1, 1, 1, 1 ], "p": [ 1 ], "q": [ 0 ], "rhomolar_reduce": 3920, "rhomolar_reduce_units": "mol/m^3", "t1": [ 0, 1, 0, 1, 0, 1, 0, 1 ], "t2": [ 0 ], "type": "modified_Batschinski_Hildebrand" }, "initial_density": { "b": [ -19.572881, 219.73999, -1015.3226, 2471.01251, -3375.1717, 2491.6597, -787.26086, 14.085455, -0.34664158 ], "t": [ 0, -0.25, -0.5, -0.75, -1.0, -1.25, -1.5, -2.5, -5.5 ], "type": "Rainwater-Friend" }, "sigma_eta": 5.7335e-10, "sigma_eta_units": "m" } } }