#include "AbstractState.h" #include "DataStructures.h" #include "../Backends/Helmholtz/HelmholtzEOSMixtureBackend.h" // ############################################ // TESTS // ############################################ #if defined(ENABLE_CATCH) #include "crossplatform_shared_ptr.h" #include "catch.hpp" #include "CoolPropTools.h" #include "CoolProp.h" #include "CoolPropLib.h" namespace TransportValidation{ // A structure to hold the values for one validation call struct vel { public: std::string in1, in2, out, fluid; double v1, v2, tol, expected; vel(std::string fluid, std::string in1, double v1, std::string in2, double v2, std::string out, double expected, double tol) { this->in1 = in1; this->in2 = in2; this->fluid = fluid; this->v1 = v1; this->v2 = v2; this->expected = expected; this->tol = tol; }; }; vel viscosity_validation_data[] = { // From Vogel, JPCRD, 1998 vel("Propane", "T", 90, "Dmolar", 16.52e3, "V", 7388e-6, 1e-3), vel("Propane", "T", 150, "Dmolar", 15.14e3, "V", 656.9e-6, 5e-3), vel("Propane", "T", 600, "Dmolar", 10.03e3, "V", 73.92e-6, 5e-3), vel("Propane", "T", 280, "Dmolar", 11.78e3, "V", 117.4e-6,1e-3), // Huber, FPE, 2004 vel("n-Octane", "T", 300, "Dmolar", 6177.2, "V", 553.60e-6, 1e-3), vel("n-Nonane", "T", 300, "Dmolar", 5619.1, "V", 709.53e-6, 1e-3), vel("n-Decane", "T", 300, "Dmolar", 5150.4, "V", 926.44e-6, 1e-3), // Huber, Energy & Fuels, 2004 vel("n-Dodecane", "T", 300, "Dmolar", 4411.5, "V", 1484.8e-6, 1e-3), vel("n-Dodecane", "T", 500, "Dmolar", 3444.7, "V", 183.76e-6, 1e-3), // Huber, I&ECR, 2006 vel("R125", "T", 300, "Dmolar", 10596.9998, "V", 177.37e-6, 1e-3), vel("R125", "T", 400, "Dmolar", 30.631, "V", 17.070e-6, 1e-3), // From REFPROP 9.1 since Huber I&ECR 2003 does not provide validation data vel("R134a", "T", 185, "Q", 0, "V", 0.0012698376398294414, 1e-3), vel("R134a", "T", 185, "Q", 1, "V", 7.4290821400170869e-006, 1e-3), vel("R134a", "T", 360, "Q", 0, "V", 7.8146319978982133e-005, 1e-3), vel("R134a", "T", 360, "Q", 1, "V", 1.7140264998576107e-005, 1e-3), // From REFPROP 9.1 since Kiselev, IECR, 2005 does not provide validation data vel("Ethanol", "T", 300, "Q", 0, "V", 0.0010439017679191723, 1e-3), vel("Ethanol", "T", 300, "Q", 1, "V", 8.8293820936046416e-006, 1e-3), vel("Ethanol", "T", 500, "Q", 0, "V", 6.0979347125450671e-005, 1e-3), vel("Ethanol", "T", 500, "Q", 1, "V", 1.7229157141572511e-005, 1e-3), // From CoolProp v5 implementation of correlation - more or less agrees with REFPROP // Errata in BibTeX File vel("Hydrogen", "T", 35, "Dmass", 100, "V", 5.47889e-005, 1e-3), // From Meng 2012 experimental data (note erratum in BibTeX file) vel("DimethylEther", "T", 253.146, "Dmass", 734.28, "V", 0.20444e-3, 3e-3), vel("DimethylEther", "T", 373.132, "Dmass", 613.78, "V", 0.09991e-3, 3e-3), // From Fenghour, JPCRD, 1995 vel("Ammonia", "T", 200, "Dmolar", 3.9, "V", 6.95e-6, 1e-3), vel("Ammonia", "T", 200, "Dmolar", 42754.4, "V", 507.28e-6, 1e-3), vel("Ammonia", "T", 398, "Dmolar", 7044.7, "V", 17.67e-6, 1e-3), vel("Ammonia", "T", 398, "Dmolar", 21066.7, "V", 43.95e-6, 1e-3), // From Lemmon and Jacobsen, JPCRD, 2004 vel("Nitrogen", "T", 100, "Dmolar", 1e-14, "V", 6.90349e-6, 1e-3), vel("Nitrogen", "T", 300, "Dmolar", 1e-14, "V", 17.8771e-6, 1e-3), vel("Nitrogen", "T", 100, "Dmolar", 25000, "V", 79.7418e-6, 1e-3), vel("Nitrogen", "T", 200, "Dmolar", 10000, "V", 21.0810e-6, 1e-3), vel("Nitrogen", "T", 300, "Dmolar", 5000, "V", 20.7430e-6, 1e-3), vel("Nitrogen", "T", 126.195, "Dmolar", 11180, "V", 18.2978e-6, 1e-3), vel("Argon", "T", 100, "Dmolar", 1e-14, "V", 8.18940e-6, 1e-3), vel("Argon", "T", 300, "Dmolar", 1e-14, "V", 22.7241e-6, 1e-3), vel("Argon", "T", 100, "Dmolar", 33000, "V", 184.232e-6, 1e-3), vel("Argon", "T", 200, "Dmolar", 10000, "V", 25.5662e-6, 1e-3), vel("Argon", "T", 300, "Dmolar", 5000, "V", 26.3706e-6, 1e-3), vel("Argon", "T", 150.69, "Dmolar", 13400, "V", 27.6101e-6, 1e-3), vel("Oxygen", "T", 100, "Dmolar", 1e-14, "V", 7.70243e-6, 1e-3), vel("Oxygen", "T", 300, "Dmolar", 1e-14, "V", 20.6307e-6, 1e-3), vel("Oxygen", "T", 100, "Dmolar", 35000, "V", 172.136e-6, 1e-3), vel("Oxygen", "T", 200, "Dmolar", 10000, "V", 22.4445e-6, 1e-3), vel("Oxygen", "T", 300, "Dmolar", 5000, "V", 23.7577e-6, 1e-3), vel("Oxygen", "T", 154.6, "Dmolar", 13600, "V", 24.7898e-6, 1e-3), vel("Air", "T", 100, "Dmolar", 1e-14, "V", 7.09559e-6, 1e-3), vel("Air", "T", 300, "Dmolar", 1e-14, "V", 18.5230e-6, 1e-3), vel("Air", "T", 100, "Dmolar", 28000, "V", 107.923e-6, 1e-3), vel("Air", "T", 200, "Dmolar", 10000, "V", 21.1392e-6, 1e-3), vel("Air", "T", 300, "Dmolar", 5000, "V", 21.3241e-6, 1e-3), vel("Air", "T", 132.64, "Dmolar", 10400, "V", 17.7623e-6, 1e-3), // From Michailidou, JPCRD, 2013 vel("Hexane", "T", 250, "Dmass", 1e-14, "V", 5.2584e-6, 1e-3), vel("Hexane", "T", 400, "Dmass", 1e-14, "V", 8.4149e-6, 1e-3), vel("Hexane", "T", 550, "Dmass", 1e-14, "V", 11.442e-6, 1e-3), vel("Hexane", "T", 250, "Dmass", 700, "V", 528.2e-6, 1e-3), vel("Hexane", "T", 400, "Dmass", 600, "V", 177.62e-6, 1e-3), vel("Hexane", "T", 550, "Dmass", 500, "V", 95.002e-6, 1e-3), // From Assael, JPCRD, 2014 vel("Heptane", "T", 250, "Dmass", 1e-14, "V", 4.9717e-6, 1e-3), vel("Heptane", "T", 400, "Dmass", 1e-14, "V", 7.8361e-6, 1e-3), vel("Heptane", "T", 550, "Dmass", 1e-14, "V", 10.7394e-6, 1e-3), vel("Heptane", "T", 250, "Dmass", 720, "V", 725.69e-6, 1e-3), vel("Heptane", "T", 400, "Dmass", 600, "V", 175.94e-6, 1e-3), vel("Heptane", "T", 550, "Dmass", 500, "V", 95.105e-6, 1e-3), // From Fenghour, JPCRD, 1998 vel("CO2", "T", 220, "Dmass", 2.440, "V", 11.06e-6, 1e-3), vel("CO2", "T", 300, "Dmass", 1.773, "V", 15.02e-6, 1e-3), vel("CO2", "T", 800, "Dmass", 0.662, "V", 35.09e-6, 1e-3), vel("CO2", "T", 304, "Dmass", 254.320, "V", 20.99e-6, 1e-2), // no critical enhancement vel("CO2", "T", 220, "Dmass", 1194.86, "V", 269.37e-6, 1e-3), vel("CO2", "T", 300, "Dmass", 1029.27, "V", 132.55e-6, 1e-3), vel("CO2", "T", 800, "Dmass", 407.828, "V", 48.74e-6, 1e-3), // Tanaka, IJT, 1996 vel("R123", "T", 265, "Dmass", 1545.8, "V", 627.1e-6, 1e-3), vel("R123", "T", 265, "Dmass", 1.614, "V", 9.534e-6, 1e-3), vel("R123", "T", 415, "Dmass", 1079.4, "V", 121.3e-6, 1e-3), vel("R123", "T", 415, "Dmass", 118.9, "V", 15.82e-6, 1e-3), // Krauss, IJT, 1996 vel("R152A", "T", 242, "Dmass", 1025.5, "V", 347.3e-6, 1e-3), vel("R152A", "T", 242, "Dmass", 2.4868, "V", 8.174e-6, 1e-3), vel("R152A", "T", 384, "Dmass", 504.51, "V", 43.29e-6, 5e-3), vel("R152A", "T", 384, "Dmass", 239.35, "V", 21.01e-6, 10e-3), // Huber, JPCRD, 2008 and IAPWS vel("Water", "T", 298.15, "Dmass", 998, "V", 889.735100e-6, 1e-7), vel("Water", "T", 298.15, "Dmass", 1200, "V", 1437.649467e-6, 1e-7), vel("Water", "T", 373.15, "Dmass", 1000, "V", 307.883622e-6, 1e-7), vel("Water", "T", 433.15, "Dmass", 1, "V", 14.538324e-6, 1e-7), vel("Water", "T", 433.15, "Dmass", 1000, "V", 217.685358e-6, 1e-7), vel("Water", "T", 873.15, "Dmass", 1, "V", 32.619287e-6, 1e-7), vel("Water", "T", 873.15, "Dmass", 100, "V", 35.802262e-6, 1e-7), vel("Water", "T", 873.15, "Dmass", 600, "V", 77.430195e-6, 1e-7), vel("Water", "T", 1173.15, "Dmass", 1, "V", 44.217245e-6, 1e-7), vel("Water", "T", 1173.15, "Dmass", 100, "V", 47.640433e-6, 1e-7), vel("Water", "T", 1173.15, "Dmass", 400, "V", 64.154608e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 122, "V", 25.520677e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 222, "V", 31.337589e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 272, "V", 36.228143e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 322, "V", 42.961579e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 372, "V", 45.688204e-6, 1e-7), vel("Water", "T", 647.35, "Dmass", 422, "V", 49.436256e-6, 1e-7), // Quinones-Cisneros, JPCRD, 2012 vel("SF6", "T", 300, "Dmass", 1e-14, "V", 15.2887e-6, 1e-4), vel("SF6", "T", 300, "Dmass", 5.92, "V", 15.3043e-6, 1e-4), vel("SF6", "T", 300, "Dmass", 1345.1, "V", 117.417e-6, 1e-4), vel("SF6", "T", 400, "Dmass", 1e-14, "V", 19.6796e-6, 1e-4), vel("SF6", "T", 400, "Dmass", 278.47, "V", 24.4272e-6, 1e-4), vel("SF6", "T", 400, "Dmass", 1123.8, "V", 84.7835e-6, 1e-4), // Quinones-Cisneros, JCED, 2012, data from validation vel("H2S", "T", 200, "P", 1000e5, "V", 0.000460287, 1e-3), vel("H2S", "T", 200, "P", 0.251702e5, "V", 8.02322E-06, 1e-3), vel("H2S", "T", 596.961, "P", 1000e5, "V", 6.94741E-05, 1e-3), vel("H2S", "T", 596.961, "P", 1e5, "V", 2.38654E-05, 1e-3), // Geller, Purdue Conference, 2000 //vel("R410A", "T", 243.15, "Q", 0, "V", 238.61e-6, 5e-2), //vel("R410A", "T", 243.15, "Q", 1, "V", 10.37e-6, 5e-2), //vel("R410A", "T", 333.15, "Q", 0, "V", 70.71e-6, 5e-2), //vel("R410A", "T", 333.15, "Q", 1, "V", 19.19e-6, 5e-2), //vel("R407C", "T", 243.15, "Q", 0, "V", 304.18e-6, 1e-2), //vel("R407C", "T", 243.15, "Q", 1, "V", 9.83e-6, 1e-2), //vel("R407C", "T", 333.15, "Q", 0, "V", 95.96e-6, 1e-2), //vel("R407C", "T", 333.15, "Q", 1, "V", 16.38e-6, 1e-2), //vel("R404A", "T", 243.15, "Q", 0, "V", 264.67e-6, 1e-2), //vel("R404A", "T", 243.15, "Q", 1, "V", 10.13e-6, 1e-2), //vel("R404A", "T", 333.15, "Q", 0, "V", 73.92e-6, 1e-2), //vel("R404A", "T", 333.15, "Q", 1, "V", 18.56e-6, 1e-2), //vel("R507A", "T", 243.15, "Q", 0, "V", 284.59e-6, 3e-2), //vel("R507A", "T", 243.15, "Q", 1, "V", 9.83e-6, 1e-2), //vel("R507A", "T", 333.15, "Q", 0, "V", 74.37e-6, 1e-2), //vel("R507A", "T", 333.15, "Q", 1, "V", 19.35e-6, 1e-2), // From Arp, NIST, 1998 vel("Helium", "T", 3.6, "P", 0.180e6, "V", 3.745e-6, 1e-2), vel("Helium", "T", 50, "P", 0.180e6, "V", 6.376e-6, 1e-2), vel("Helium", "T", 400, "P", 0.180e6, "V", 24.29e-6, 1e-2), // From Shan, ASHRAE, 2000 vel("R23", "T", 180, "Dmolar", 21097, "V", 353.88e-6, 1e-4), vel("R23", "T", 420, "Dmolar", 7564, "V", 39.459e-6, 1e-4), vel("R23", "T", 370, "Dmolar", 32.62, "V", 18.213e-6, 1e-4), // From Friend, JPCRD, 1991 vel("Ethane", "T", 100, "Dmolar", 21330, "V", 878.6e-6, 1e-2), vel("Ethane", "T", 430, "Dmolar", 12780, "V", 58.70e-6, 1e-2), vel("Ethane", "T", 500, "Dmolar", 11210, "V", 48.34e-6, 1e-2), // From Xiang, JPCRD, 2006 vel("Methanol", "T", 600, "Dmass", 800.23, "V", 0.1888e-3, 1e-4), vel("Methanol", "T", 600, "Dmass", 833.20, "V", 0.2092e-3, 1e-4), vel("Methanol", "T", 600, "Dmass", 861.37, "V", 0.2279e-3, 1e-4), vel("Methanol", "T", 600, "Dmass", 908.33, "V", 0.2634e-3, 1e-4), vel("Methanol", "T", 620, "Dmass", 788.58, "V", 0.1779e-3, 1e-4), vel("Methanol", "T", 620, "Dmass", 822.14, "V", 0.1972e-3, 1e-4), vel("Methanol", "T", 620, "Dmass", 850.77, "V", 0.2148e-3, 1e-4), vel("Methanol", "T", 620, "Dmass", 898.48, "V", 0.2477e-3, 1e-4), vel("Methanol", "T", 630, "Dmass", 782.76, "V", 0.1729e-3, 1e-4), vel("Methanol", "T", 630, "Dmass", 811.06, "V", 0.1917e-3, 1e-4), vel("Methanol", "T", 630, "Dmass", 840.11, "V", 0.2088e-3, 1e-4), vel("Methanol", "T", 630, "Dmass", 888.50, "V", 0.2405e-3, 1e-4), // From REFPROP 9.1 since no data provided vel("n-Butane", "T", 150, "Q", 0, "V", 0.0013697657668, 1e-4), vel("n-Butane", "T", 400, "Q", 1, "V", 1.2027464524762453e-005, 1e-4), vel("IsoButane", "T", 120, "Q", 0, "V", 0.0060558450757844271, 1e-4), vel("IsoButane", "T", 400, "Q", 1, "V", 1.4761041187617117e-005, 2e-4), vel("R134a", "T", 175, "Q", 0, "V", 0.0017558494524138289, 1e-4), vel("R134a", "T", 360, "Q", 1, "V", 1.7140264998576107e-005, 1e-4), // From Tariq, JPCRD, 2014 vel("Cyclohexane", "T", 300, "Dmolar", 1e-10, "V", 7.058e-6, 1e-4), vel("Cyclohexane", "T", 300, "Dmolar", 0.0430e3, "V", 6.977e-6, 1e-4), vel("Cyclohexane", "T", 300, "Dmolar", 9.1756e3, "V", 863.66e-6, 1e-4), vel("Cyclohexane", "T", 300, "Dmolar", 9.9508e3, "V", 2850.18e-6, 1e-4), vel("Cyclohexane", "T", 500, "Dmolar", 1e-10, "V", 11.189e-6, 1e-4), vel("Cyclohexane", "T", 500, "Dmolar", 6.0213e3, "V", 94.842e-6, 1e-4), vel("Cyclohexane", "T", 500, "Dmolar", 8.5915e3, "V", 380.04e-6, 1e-4), vel("Cyclohexane", "T", 700, "Dmolar", 1e-10, "V", 15.093e-6, 1e-4), vel("Cyclohexane", "T", 700, "Dmolar", 7.4765e3, "V", 176.749e-6, 1e-4), }; class TransportValidationFixture { protected: long double actual, x1, x2; shared_ptr pState; CoolProp::input_pairs pair; public: TransportValidationFixture(){ } ~TransportValidationFixture(){ } void set_backend(std::string backend, std::string fluid_name){ pState.reset(CoolProp::AbstractState::factory(backend, fluid_name)); } void set_pair(std::string &in1, double v1, std::string &in2, double v2){ double o1, o2; long iin1 = CoolProp::get_parameter_index(in1); long iin2 = CoolProp::get_parameter_index(in2); CoolProp::input_pairs pair = CoolProp::generate_update_pair(iin1, v1, iin2, v2, o1, o2); pState->update(pair, o1, o2); } void get_value(long key) { actual = pState->keyed_output(key); } }; TEST_CASE_METHOD(TransportValidationFixture, "Compare viscosities against published data", "[viscosity],[transport]") { int inputsN = sizeof(viscosity_validation_data)/sizeof(viscosity_validation_data[0]); for (int i = 0; i < inputsN; ++i) { vel el = viscosity_validation_data[i]; CHECK_NOTHROW(set_backend("HEOS", el.fluid)); CAPTURE(el.fluid); CAPTURE(el.in1); CAPTURE(el.v1); CAPTURE(el.in2); CAPTURE(el.v2); CHECK_NOTHROW(set_pair(el.in1, el.v1, el.in2, el.v2)); CHECK_NOTHROW(get_value(CoolProp::iviscosity)); CAPTURE(el.expected); CAPTURE(actual); CHECK(std::abs(actual/el.expected-1) < el.tol); } } vel conductivity_validation_data[] = { ///\todo Re-enable the conductivity tests that fail due to not having viscosity correlation // From Assael, JPCRD, 2013 vel("Hexane", "T", 250, "Dmass", 700, "L", 137.62e-3, 1e-4), vel("Hexane", "T", 400, "Dmass", 2, "L", 23.558e-3, 1e-4), vel("Hexane", "T", 400, "Dmass", 650, "L", 129.28e-3, 2e-4), vel("Hexane", "T", 510, "Dmass", 2, "L", 36.772e-3, 1e-4), // From Assael, JPCRD, 2013 vel("Heptane", "T", 250, "Dmass", 720, "L", 137.09e-3, 1e-4), vel("Heptane", "T", 400, "Dmass", 2, "L", 21.794e-3, 1e-4), vel("Heptane", "T", 400, "Dmass", 650, "L", 120.75e-3, 1e-4), vel("Heptane", "T", 535, "Dmass", 100, "L", 51.655e-3, 3e-3), // Relaxed tolerance because conductivity was fit using older viscosity correlation // From Assael, JPCRD, 2013 vel("Ethanol", "T", 300, "Dmass", 850, "L", 209.68e-3, 1e-4), vel("Ethanol", "T", 400, "Dmass", 2, "L", 26.108e-3, 1e-4), vel("Ethanol", "T", 400, "Dmass", 690, "L", 149.21e-3, 1e-4), vel("Ethanol", "T", 500, "Dmass", 10, "L", 39.594e-3, 1e-4), //// From Assael, JPCRD, 2012 //vel("Toluene", "T", 298.15, "Dmass", 1e-15, "L", 10.749e-3, 1e-4), //vel("Toluene", "T", 298.15, "Dmass", 862.948, "L", 130.66e-3, 1e-4), //vel("Toluene", "T", 298.15, "Dmass", 876.804, "L", 136.70e-3, 1e-4), //vel("Toluene", "T", 595, "Dmass", 1e-15, "L", 40.538e-3, 1e-4), //vel("Toluene", "T", 595, "Dmass", 46.512, "L", 41.549e-3, 1e-4), //vel("Toluene", "T", 185, "Dmass", 1e-15, "L", 4.3758e-3, 1e-4), //vel("Toluene", "T", 185, "Dmass", 968.821, "L", 158.24e-3, 1e-4), // From Assael, JPCRD, 2012 vel("SF6", "T", 298.15, "Dmass", 1e-13, "L", 12.952e-3, 1e-4), vel("SF6", "T", 298.15, "Dmass", 100, "L", 14.126e-3, 1e-4), vel("SF6", "T", 298.15, "Dmass", 1600, "L", 69.729e-3, 1e-4), vel("SF6", "T", 310, "Dmass", 1e-13, "L", 13.834e-3, 1e-4), vel("SF6", "T", 310, "Dmass", 1200, "L", 48.705e-3, 1e-4), vel("SF6", "T", 480, "Dmass", 100, "L", 28.847e-3, 1e-4), //// From Assael, JPCRD, 2012 //vel("Benzene", "T", 290, "Dmass", 890, "L", 147.66e-3, 1e-4), //vel("Benzene", "T", 500, "Dmass", 2, "L", 30.174e-3, 1e-4), //vel("Benzene", "T", 500, "Dmass", 32, "L", 32.175e-3, 1e-4), //vel("Benzene", "T", 500, "Dmass", 800, "L", 141.24e-3, 1e-4), //vel("Benzene", "T", 575, "Dmass", 1.7, "L", 37.763e-3, 1e-4), // From Assael, JPCRD, 2011 vel("Hydrogen", "T", 298.15, "Dmass", 1e-13, "L", 185.67e-3, 1e-4), vel("Hydrogen", "T", 298.15, "Dmass", 0.80844, "L", 186.97e-3, 1e-4), vel("Hydrogen", "T", 298.15, "Dmass", 14.4813, "L", 201.35e-3, 1e-4), vel("Hydrogen", "T", 35, "Dmass", 1e-13, "L", 26.988e-3, 1e-4), vel("Hydrogen", "T", 35, "Dmass", 30, "L", 0.0770177, 1e-4), // Updated since Assael uses a different viscosity correlation vel("Hydrogen", "T", 18, "Dmass", 1e-13, "L", 13.875e-3, 1e-4), vel("Hydrogen", "T", 18, "Dmass", 75, "L", 104.48e-3, 1e-4), /*vel("ParaHydrogen", "T", 298.15, "Dmass", 1e-13, "L", 192.38e-3, 1e-4), vel("ParaHydrogen", "T", 298.15, "Dmass", 0.80844, "L", 192.81e-3, 1e-4), vel("ParaHydrogen", "T", 298.15, "Dmass", 14.4813, "L", 207.85e-3, 1e-4), vel("ParaHydrogen", "T", 35, "Dmass", 1e-13, "L", 27.222e-3, 1e-4), vel("ParaHydrogen", "T", 35, "Dmass", 30, "L", 70.335e-3, 1e-4), vel("ParaHydrogen", "T", 18, "Dmass", 1e-13, "L", 13.643e-3, 1e-4), vel("ParaHydrogen", "T", 18, "Dmass", 75, "L", 100.52e-3, 1e-4),*/ // Some of these don't work vel("R125", "T", 341, "Dmass", 600, "L", 0.0565642978494, 2e-4), vel("R125", "T", 200, "Dmass", 1e-13, "L", 0.007036843623086, 2e-4), vel("IsoButane", "T", 390, "Dmass", 387.09520158645068, "L", 0.063039, 2e-4), vel("IsoButane", "T", 390, "Dmass", 85.76703973869482, "L", 0.036603, 2e-4), vel("n-Butane", "T", 415, "Dmass", 360.01895129934866, "L", 0.067045, 2e-4), vel("n-Butane", "T", 415, "Dmass", 110.3113177144, "L", 0.044449, 1e-4), // From Huber, FPE, 2005 vel("n-Octane", "T", 300, "Dmolar", 6177.2, "L", 0.12836, 1e-4), vel("n-Nonane", "T", 300, "Dmolar", 5619.4, "L", 0.13031, 1e-4), //vel("n-Decane", "T", 300, "Dmass", 5150.4, "L", 0.13280, 1e-4), // no viscosity // From Huber, EF, 2004 vel("n-Dodecane", "T", 300, "Dmolar", 4411.5, "L", 0.13829, 1e-4), vel("n-Dodecane", "T", 500, "Dmolar", 3444.7, "L", 0.09384, 1e-4), vel("n-Dodecane", "T", 660, "Dmolar", 1500.98, "L", 0.090346, 1e-4), // From REFPROP 9.1 since no data provided in Marsh, 2002 vel("n-Propane", "T", 368, "Q", 0, "L", 0.07282154952457,1e-3), vel("n-Propane", "T", 368, "Dmolar", 1e-10, "L", 0.0266135388745317,1e-4), // From Perkins, JCED, 2011 //vel("R1234yf", "T", 250, "Dmass", 2.80006, "L", 0.0098481, 1e-4), //vel("R1234yf", "T", 300, "Dmass", 4.671556, "L", 0.013996, 1e-4), //vel("R1234yf", "T", 250, "Dmass", 1299.50, "L", 0.088574, 1e-4), //vel("R1234yf", "T", 300, "Dmass", 1182.05, "L", 0.075245, 1e-4), //vel("R1234ze(E)", "T", 250, "Dmass", 2.80451, "L", 0.0098503, 1e-4), //vel("R1234ze(E)", "T", 300, "Dmass", 4.67948, "L", 0.013933, 1e-4), //vel("R1234ze(E)", "T", 250, "Dmass", 1349.37, "L", 0.10066, 1e-4), //vel("R1234ze(E)", "T", 300, "Dmass", 1233.82, "L", 0.085389, 1e-4), // From Laesecke, IJR 1995 vel("R123", "T", 180, "Dmass", 1739, "L", 110.9e-3, 2e-4), vel("R123", "T", 180, "Dmass", 0.2873e-2, "L", 2.473e-3, 1e-3), vel("R123", "T", 430, "Dmass", 996.35, "L", 45.62e-3, 1e-3), vel("R123", "T", 430, "Dmass", 166.9, "L", 21.03e-3, 1e-3), // From Scalabrin, JPCRD, 2006 vel("CO2", "T", 218, "Q", 0, "L", 181.09e-3, 1e-4), vel("CO2", "T", 218, "Q", 1, "L", 10.837e-3, 1e-4), vel("CO2", "T", 304, "Q", 0, "L", 140.3e-3, 1e-4), vel("CO2", "T", 304, "Q", 1, "L", 217.95e-3, 1e-4), vel("CO2", "T", 225, "Dmass", 0.23555, "L", 11.037e-3, 1e-4), vel("CO2", "T", 275, "Dmass", 1281.64, "L", 238.44e-3, 1e-4), // From Friend, JPCRD, 1991 vel("Ethane", "T", 100, "Dmass", 1e-13, "L", 3.46e-3, 1e-2), vel("Ethane", "T", 230, "Dmolar", 16020, "L", 126.2e-3, 1e-2), vel("Ethane", "T", 440, "Dmolar", 1520, "L", 45.9e-3, 1e-2), vel("Ethane", "T", 310, "Dmolar", 4130, "L", 45.4e-3, 1e-2), // From Lemmon and Jacobsen, JPCRD, 2004 vel("Nitrogen", "T", 100, "Dmolar", 1e-14, "L", 9.27749e-3, 1e-4), vel("Nitrogen", "T", 300, "Dmolar", 1e-14, "L", 25.9361e-3, 1e-4), vel("Nitrogen", "T", 100, "Dmolar", 25000, "L", 103.834e-3, 1e-4), vel("Nitrogen", "T", 200, "Dmolar", 10000, "L", 36.0099e-3, 1e-4), vel("Nitrogen", "T", 300, "Dmolar", 5000, "L", 32.7694e-3, 1e-4), vel("Nitrogen", "T", 126.195, "Dmolar", 11180, "L", 675.800e-3, 1e-4), vel("Argon", "T", 100, "Dmolar", 1e-14, "L", 6.36587e-3, 1e-4), vel("Argon", "T", 300, "Dmolar", 1e-14, "L", 17.8042e-3, 1e-4), vel("Argon", "T", 100, "Dmolar", 33000, "L", 111.266e-3, 1e-4), vel("Argon", "T", 200, "Dmolar", 10000, "L", 26.1377e-3, 1e-4), vel("Argon", "T", 300, "Dmolar", 5000, "L", 23.2302e-3, 1e-4), vel("Argon", "T", 150.69, "Dmolar", 13400, "L", 856.793e-3, 1e-4), vel("Oxygen", "T", 100, "Dmolar", 1e-14, "L", 8.94334e-3, 1e-4), vel("Oxygen", "T", 300, "Dmolar", 1e-14, "L", 26.4403e-3, 1e-4), vel("Oxygen", "T", 100, "Dmolar", 35000, "L", 146.044e-3, 1e-4), vel("Oxygen", "T", 200, "Dmolar", 10000, "L", 34.6124e-3, 1e-4), vel("Oxygen", "T", 300, "Dmolar", 5000, "L", 32.5491e-3, 1e-4), vel("Oxygen", "T", 154.6, "Dmolar", 13600, "L", 377.476e-3, 1e-4), vel("Air", "T", 100, "Dmolar", 1e-14, "L", 9.35902e-3, 1e-4), vel("Air", "T", 300, "Dmolar", 1e-14, "L", 26.3529e-3, 1e-4), vel("Air", "T", 100, "Dmolar", 28000, "L", 119.221e-3, 1e-4), vel("Air", "T", 200, "Dmolar", 10000, "L", 35.3185e-3, 1e-4), vel("Air", "T", 300, "Dmolar", 5000, "L", 32.6062e-3, 1e-4), vel("Air", "T", 132.64, "Dmolar", 10400, "L", 75.6231e-3, 1e-4), // Huber, JPCRD, 2012 vel("Water", "T", 298.15, "Dmass", 1e-14, "L", 18.4341883e-3, 1e-6), vel("Water", "T", 298.15, "Dmass", 998, "L", 607.712868e-3, 1e-6), vel("Water", "T", 298.15, "Dmass", 1200, "L", 799.038144e-3, 1e-6), vel("Water", "T", 873.15, "Dmass", 1e-14, "L", 79.1034659e-3, 1e-6), vel("Water", "T", 647.35, "Dmass", 1, "L", 51.9298924e-3, 1e-6), vel("Water", "T", 647.35, "Dmass", 122, "L", 130.922885e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 222, "L", 367.787459e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 272, "L", 757.959776e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 322, "L", 1443.75556e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 372, "L", 650.319402e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 422, "L", 448.883487e-3, 2e-4), vel("Water", "T", 647.35, "Dmass", 750, "L", 600.961346e-3, 2e-4), // From Shan, ASHRAE, 2000 vel("R23", "T", 180, "Dmolar", 21097, "L", 143.19e-3, 1e-4), vel("R23", "T", 420, "Dmolar", 7564, "L", 50.19e-3, 2e-4), vel("R23", "T", 370, "Dmolar", 32.62, "L", 17.455e-3, 1e-4), // From REFPROP 9.1 since no sample data provided in Tufeu vel("Ammonia", "T", 310, "Dmolar", 34320, "L", 0.45223303481784971, 1e-4), vel("Ammonia", "T", 395, "Q", 0, "L", 0.2264480769301, 1e-4), // From Hands, Cryogenics, 1981 vel("Helium", "T", 800, "P", 1e5, "L", 0.3085, 1e-2), vel("Helium", "T", 300, "P", 1e5, "L", 0.1560, 1e-2), vel("Helium", "T", 20, "P", 1e5, "L", 0.0262, 1e-2), vel("Helium", "T", 8, "P", 1e5, "L", 0.0145, 1e-2), vel("Helium", "T", 4, "P", 20e5, "L", 0.0255, 1e-2), vel("Helium", "T", 8, "P", 20e5, "L", 0.0308, 1e-2), vel("Helium", "T", 20, "P", 20e5, "L", 0.0328, 1e-2), vel("Helium", "T", 4, "P", 100e5, "L", 0.0385, 3e-2), vel("Helium", "T", 8, "P", 100e5, "L", 0.0566, 3e-2), vel("Helium", "T", 20, "P", 100e5, "L", 0.0594, 1e-2), vel("Helium", "T", 4, "P", 1e5, "L", 0.0186, 1e-2), vel("Helium", "T", 4, "P", 2e5, "L", 0.0194, 1e-2), vel("Helium", "T", 5.180, "P", 2.3e5, "L", 0.0195, 1e-1), vel("Helium", "T", 5.2, "P", 2.3e5, "L", 0.0202, 1e-1), vel("Helium", "T", 5.230, "P", 2.3e5, "L", 0.0181, 1e-1), vel("Helium", "T", 5.260, "P", 2.3e5, "L", 0.0159, 1e-1), vel("Helium", "T", 5.3, "P", 2.3e5, "L", 0.0149, 1e-1), // Geller, IJT, 2001 - based on experimental data, no validation data provided //vel("R404A", "T", 253.03, "P", 0.101e6, "L", 0.00991, 0.03), //vel("R404A", "T", 334.38, "P", 2.176e6, "L", 19.93e-3, 0.03), //vel("R407C", "T", 253.45, "P", 0.101e6, "L", 0.00970, 0.03), //vel("R407C", "T", 314.39, "P", 0.458e6, "L", 14.87e-3, 0.03), //vel("R410A", "T", 260.32, "P", 0.101e6, "L", 0.01043, 0.03), //vel("R410A", "T", 332.09, "P", 3.690e6, "L", 22.76e-3, 0.03), //vel("R507A", "T", 254.85, "P", 0.101e6, "L", 0.01007, 0.03), //vel("R507A", "T", 333.18, "P", 2.644e6, "L", 21.31e-3, 0.03), // From REFPROP 9.1 since no data provided vel("R134a", "T", 240, "D", 1e-10, "L", 0.008698768 , 1e-4), vel("R134a", "T", 330, "D", 1e-10, "L", 0.015907606 , 1e-4), vel("R134a", "T", 330, "Q", 0, "L", 0.06746432253 , 1e-4), vel("R134a", "T", 240, "Q", 1, "L", 0.00873242359, 1e-4), }; TEST_CASE_METHOD(TransportValidationFixture, "Compare thermal conductivities against published data", "[conductivity],[transport]") { int inputsN = sizeof(conductivity_validation_data)/sizeof(conductivity_validation_data[0]); for (int i = 0; i < inputsN; ++i) { vel el = conductivity_validation_data[i]; CHECK_NOTHROW(set_backend("HEOS", el.fluid)); CAPTURE(el.fluid); CAPTURE(el.in1); CAPTURE(el.v1); CAPTURE(el.in2); CAPTURE(el.v2); CHECK_NOTHROW(set_pair(el.in1, el.v1, el.in2, el.v2)); get_value(CoolProp::iconductivity); CAPTURE(el.expected); CAPTURE(actual); CHECK(std::abs(actual/el.expected-1) < el.tol); } } }; /* namespace TransportValidation */ static CoolProp::input_pairs inputs[] = { CoolProp::DmolarT_INPUTS, //CoolProp::SmolarT_INPUTS, //CoolProp::HmolarT_INPUTS, //CoolProp::TUmolar_INPUTS, CoolProp::DmolarP_INPUTS, CoolProp::DmolarHmolar_INPUTS, CoolProp::DmolarSmolar_INPUTS, CoolProp::DmolarUmolar_INPUTS, CoolProp::HmolarP_INPUTS, CoolProp::PSmolar_INPUTS, CoolProp::PUmolar_INPUTS, /* CoolProp::HmolarSmolar_INPUTS, CoolProp::HmolarUmolar_INPUTS, CoolProp::SmolarUmolar_INPUTS */ }; class ConsistencyFixture { protected: long double hmolar, pmolar, smolar, umolar, rhomolar, T, p, x1, x2; shared_ptr pState; CoolProp::input_pairs pair; public: ConsistencyFixture(){} ~ConsistencyFixture(){} void set_backend(std::string backend, std::string fluid_name){ pState.reset(CoolProp::AbstractState::factory(backend, fluid_name)); } void set_pair(CoolProp::input_pairs pair){ this->pair = pair; } void set_TP(long double T, long double p) { this->T = T; this->p = p; CoolProp::AbstractState &State = *pState; // Start with T,P as inputs, cycle through all the other pairs that are supported State.update(CoolProp::PT_INPUTS, p, T); // Set the other state variables rhomolar = State.rhomolar(); hmolar = State.hmolar(); smolar = State.smolar(); umolar = State.umolar(); } void get_variables() { switch (pair) { /// In this group, T is one of the known inputs, iterate for the other one (easy) case CoolProp::HmolarT_INPUTS: x1 = hmolar; x2 = T; break; case CoolProp::SmolarT_INPUTS: x1 = smolar; x2 = T; break; case CoolProp::TUmolar_INPUTS: x1 = T; x2 = umolar; break; case CoolProp::DmolarT_INPUTS: x1 = rhomolar; x2 = T; break; /// In this group, D is one of the known inputs, iterate for the other one (a little bit harder) case CoolProp::DmolarHmolar_INPUTS: x1 = rhomolar; x2 = hmolar; break; case CoolProp::DmolarSmolar_INPUTS: x1 = rhomolar; x2 = smolar; break; case CoolProp::DmolarUmolar_INPUTS: x1 = rhomolar; x2 = umolar; break; case CoolProp::DmolarP_INPUTS: x1 = rhomolar; x2 = p; break; /// In this group, p is one of the known inputs (a little less easy) case CoolProp::HmolarP_INPUTS: x1 = hmolar; x2 = p; break; case CoolProp::PSmolar_INPUTS: x1 = p; x2 = smolar; break; case CoolProp::PUmolar_INPUTS: x1 = p; x2 = umolar; break; case CoolProp::HmolarSmolar_INPUTS: x1 = hmolar; x2 = smolar; break; case CoolProp::SmolarUmolar_INPUTS: x1 = smolar; x2 = umolar; break; default: throw CoolProp::ValueError(); } } void single_phase_consistency_check() { CoolProp::AbstractState &State = *pState; State.update(pair, x1, x2); // Make sure we end up back at the same temperature and pressure we started out with if(std::abs(T-State.T()) > 1e-2) throw CoolProp::ValueError(format("Error on T [%g K] is greater than 1e-2",std::abs(State.T()-T))); if(std::abs(p-State.p())/p*100 > 1e-2) throw CoolProp::ValueError(format("Error on p [%g %%] is greater than 1e-2 %%",std::abs(p-State.p())/p )); } }; TEST_CASE_METHOD(ConsistencyFixture, "Test all input pairs for CO2 using all valid backends", "[]") { CHECK_NOTHROW(set_backend("HEOS", "CO2")); int inputsN = sizeof(inputs)/sizeof(inputs[0]); for (double p = 600000; p < 800000000.0; p *= 5) { for (double T = 220; T < pState->Tmax(); T += 5) { CHECK_NOTHROW(set_TP(T, p)); for (int i = 0; i < inputsN; ++i) { CoolProp::input_pairs pair = inputs[i]; std::string pair_desc = CoolProp::get_input_pair_short_desc(pair); set_pair(pair); CAPTURE(pair_desc); CAPTURE(T); CAPTURE(p); get_variables(); CAPTURE(x1); CAPTURE(x2); CHECK_NOTHROW(single_phase_consistency_check()); } } } } TEST_CASE("Test saturation properties for a few fluids", "[saturation],[slow]") { SECTION("sat_p") { std::vector pv = linspace(Props1SI("CO2", "ptriple"), Props1SI("CO2", "pcrit")-1e-6,5); SECTION("All pressures are ok" ) for (std::size_t i = 0; i < pv.size(); ++i) { CAPTURE(pv[i]); double T = CoolProp::PropsSI("T","P",pv[i],"Q",0,"CO2"); } } } TEST_CASE("Tests for solvers in P,T flash using Water", "[flash],[PT]") { SECTION("Check that T,P for saturated state yields error") { double Ts, ps, rho; CHECK_NOTHROW(Ts = PropsSI("T","P",101325,"Q",0,"Water")); CHECK(ValidNumber(Ts)); CAPTURE(Ts); CHECK_NOTHROW(rho = PropsSI("D","T",Ts,"P",101325,"Water")); CAPTURE(rho); CHECK(!ValidNumber(rho)); } SECTION("Subcritical p slightly subcooled should be ok") { double Ts, ps, rho, dT = 1e-8; CHECK_NOTHROW(Ts = PropsSI("T","P",101325,"Q",0,"Water")); CAPTURE(Ts); CHECK(ValidNumber(Ts)); CAPTURE(dT); CHECK_NOTHROW(rho = PropsSI("D","T",Ts-dT,"P",101325,"Water")); CAPTURE(rho); CHECK(ValidNumber(rho)); } SECTION("Subcritical p slightly superheated should be ok") { double Ts, ps, rho, dT = 1e-8; CHECK_NOTHROW(Ts = PropsSI("T","P",101325,"Q",0,"Water")); CAPTURE(Ts); CHECK(ValidNumber(Ts)); CAPTURE(dT); CHECK_NOTHROW(rho = PropsSI("D","T",Ts+dT,"P",101325,"Water")); CAPTURE(rho); CHECK(ValidNumber(rho)); } } TEST_CASE("Tests for solvers in P,Y flash using Water", "[flash],[PH],[PS],[PU]") { double Ts, y, T2; // See https://groups.google.com/forum/?fromgroups#!topic/catch-forum/mRBKqtTrITU std::string Ykeys[] = {"H","S","U","Hmass","Smass","Umass","Hmolar","Smolar","Umolar"}; for (int i = 0; i < 9; ++i) { const char *ykey = Ykeys[i].c_str(); std::ostringstream ss1; ss1 << "Subcritical superheated P," << ykey; SECTION(ss1.str(),"") { double dT = 10; CHECK_NOTHROW(Ts=PropsSI("T","P",101325,"Q",0,"Water")); CHECK(ValidNumber(Ts)); CAPTURE(Ts); CHECK_NOTHROW(y=PropsSI(ykey,"T",Ts+dT,"P",101325,"Water")); CAPTURE(dT); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",101325,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss2; ss2 << "Subcritical barely superheated P," << ykey; SECTION(ss2.str(), "") { double dT = 1e-6; CHECK_NOTHROW(Ts=PropsSI("T","P",101325,"Q",0,"Water")); CHECK(ValidNumber(Ts)); CAPTURE(Ts); CHECK_NOTHROW(y=PropsSI(ykey,"T",Ts+dT,"P",101325,"Water")); CAPTURE(dT); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",101325,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss3; ss3 << "Subcritical subcooled P," << ykey; SECTION(ss3.str(), "") { double dT = -10; CHECK_NOTHROW(Ts=PropsSI("T","P",101325,"Q",0,"Water")); CHECK(ValidNumber(Ts)); CAPTURE(Ts); CHECK_NOTHROW(y=PropsSI(ykey,"T",Ts+dT,"P",101325,"Water")); CAPTURE(dT); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",101325,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss4; ss4 << "Subcritical barely subcooled P," << ykey; SECTION(ss4.str(), "") { double dT = -1e-6; CHECK_NOTHROW(Ts=PropsSI("T","P",101325,"Q",0,"Water")); CHECK(ValidNumber(Ts)); CAPTURE(Ts); CHECK_NOTHROW(y=PropsSI(ykey,"T",Ts+dT,"P",101325,"Water")); CAPTURE(dT); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",101325,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss5; ss5 << "Supercritical P," << ykey; SECTION(ss5.str(), "") { double Tc = Props1SI("Water","Tcrit"); double pc = Props1SI("Water","pcrit"); double p = pc*1.3; double T = Tc*1.3; CAPTURE(T); CAPTURE(p); CHECK(ValidNumber(T)); CHECK(ValidNumber(p)); CHECK_NOTHROW(y=PropsSI(ykey,"P",p,"T",T,"Water")); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",p,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss6; ss6 << "Supercritical \"gas\" P," << ykey; SECTION(ss6.str(), "") { double Tc = Props1SI("Water","Tcrit"); double pc = Props1SI("Water","pcrit"); double p = pc*0.7; double T = Tc*1.3; CAPTURE(T); CAPTURE(p); CHECK(ValidNumber(T)); CHECK(ValidNumber(p)); CHECK_NOTHROW(y=PropsSI(ykey,"P",p,"T",T,"Water")); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",p,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } std::ostringstream ss7; ss7 << "Supercritical \"liquid\" P," << ykey; SECTION(ss7.str(), "") { double Tc = Props1SI("Water","Tcrit"); double pc = Props1SI("Water","pcrit"); double p = pc*2; double T = Tc*0.5; CAPTURE(T); CAPTURE(p); CHECK(ValidNumber(T)); CHECK(ValidNumber(p)); CHECK_NOTHROW(y=PropsSI(ykey,"P",p,"T",T,"Water")); CAPTURE(y); CHECK(ValidNumber(y)); CHECK_NOTHROW(T2=PropsSI("T",ykey,y,"P",p,"Water")); CAPTURE(CoolProp::get_global_param_string("errstring")); CAPTURE(T2); CHECK(ValidNumber(T2)); } } } TEST_CASE("Tests for solvers in P,H flash using Propane", "[flashdups],[flash],[PH],[consistency]") { double hmolar, hmass; SECTION("5 times PH with HEOS AbstractState yields same results every time","") { shared_ptr AS(CoolProp::AbstractState::factory("HEOS", "n-Propane")); CHECK_NOTHROW(AS->update(CoolProp::PT_INPUTS, 101325, 300)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); } } TEST_CASE("Multiple calls to state class are consistent", "[flashdups],[flash],[PH],[consistency]") { double hmolar, hmass; SECTION("3 times PH with HEOS AbstractState yields same results every time","") { shared_ptr AS(CoolProp::AbstractState::factory("HEOS", "n-Propane")); CHECK_NOTHROW(AS->update(CoolProp::PT_INPUTS, 101325, 300)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); hmolar = AS->hmolar(); hmass = AS->hmass(); CHECK_NOTHROW(AS->update(CoolProp::HmassP_INPUTS, hmass, 101325)); CHECK_NOTHROW(AS->update(CoolProp::HmolarP_INPUTS, hmolar, 101325)); } } TEST_CASE("Test partial derivatives using PropsSI", "[derivatives]") { double hmolar, hmass, T = 300; SECTION("Check drhodp|T 3 ways","") { shared_ptr AS(CoolProp::AbstractState::factory("HEOS", "n-Propane")); AS->update(CoolProp::PT_INPUTS, 101325, 300); double drhomolardp__T_AbstractState = AS->first_partial_deriv(CoolProp::iDmolar, CoolProp::iP, CoolProp::iT); double drhomolardp__T_PropsSI_num = (PropsSI("Dmolar","T",T,"P",101325+1e-3,"n-Propane") - PropsSI("Dmolar","T",T,"P",101325-1e-3,"n-Propane"))/(2*1e-3); double drhomolardp__T_PropsSI = PropsSI("d(Dmolar)/d(P)|T","T",T,"P",101325,"n-Propane"); CAPTURE(drhomolardp__T_AbstractState); CAPTURE(drhomolardp__T_PropsSI_num); CAPTURE(drhomolardp__T_PropsSI); double rel_err_exact = std::abs(drhomolardp__T_AbstractState-drhomolardp__T_PropsSI)/drhomolardp__T_PropsSI; double rel_err_approx = std::abs(drhomolardp__T_PropsSI_num-drhomolardp__T_PropsSI)/drhomolardp__T_PropsSI; CHECK(rel_err_exact < 0.001); CHECK(rel_err_approx < 0.001); } SECTION("Invalid first partial derivatives","") { CHECK(!ValidNumber(PropsSI("d()/d(P)|T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Dmolar)/d()|T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Dmolar)/d(P)|","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(XXXX)/d(P)|T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Dmolar)d(P)|T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Dmolar)/d(P)T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Bvirial)/d(P)T","T",300,"P",101325,"n-Propane"))); CHECK(!ValidNumber(PropsSI("d(Tcrit)/d(P)T","T",300,"P",101325,"n-Propane"))); } } TEST_CASE("Ancillary functions", "[ancillary]") { std::vector fluids = strsplit(CoolProp::get_global_param_string("fluids_list"),','); for (std::size_t i = 0; i < fluids.size(); ++i){ shared_ptr AS(CoolProp::AbstractState::factory("HEOS", fluids[i])); double Tc = AS->T_critical(); double Tt = AS->Ttriple(); for (double f = 0.1; f < 1; f += 0.4) { double T = f*Tc + (1-f)*Tt; std::ostringstream ss1; ss1 << "Pressure error < 2% for fluid " << fluids[i] << " at " << T << " K"; SECTION(ss1.str(), "") { AS->update(CoolProp::QT_INPUTS, 0, T); double p_EOS = AS->p(); double p_anc = AS->saturation_ancillary(CoolProp::iP, 0, CoolProp::iT, T); double err = std::abs(p_EOS-p_anc)/p_anc; CAPTURE(p_EOS); CAPTURE(p_anc); CAPTURE(T); CHECK(err < 0.02); } std::ostringstream ss2; ss2 << "Liquid density error < 3% for fluid " << fluids[i] << " at " << T << " K"; SECTION(ss2.str(), "") { AS->update(CoolProp::QT_INPUTS, 0, T); double rho_EOS = AS->rhomolar(); double rho_anc = AS->saturation_ancillary(CoolProp::iDmolar, 0, CoolProp::iT, T); double err = std::abs(rho_EOS-rho_anc)/rho_anc; CAPTURE(rho_EOS); CAPTURE(rho_anc); CAPTURE(T); CHECK(err < 0.03); } std::ostringstream ss3; ss3 << "Vapor density error < 3% for fluid " << fluids[i] << " at " << T << " K"; SECTION(ss3.str(), "") { AS->update(CoolProp::QT_INPUTS, 1, T); double rho_EOS = AS->rhomolar(); double rho_anc = AS->saturation_ancillary(CoolProp::iDmolar, 1, CoolProp::iT, T); double err = std::abs(rho_EOS-rho_anc)/rho_anc; CAPTURE(rho_EOS); CAPTURE(rho_anc); CAPTURE(T); CHECK(err < 0.03); } } } } TEST_CASE("Triple point checks", "[triple_point]") { std::vector fluids = strsplit(CoolProp::get_global_param_string("fluids_list"),','); for (std::size_t i = 0; i < fluids.size(); ++i){ std::ostringstream ss1; ss1 << "Triple point pressures matches for pure " << fluids[i]; SECTION(ss1.str(), "") { std::vector names(1,fluids[i]); shared_ptr HEOS(new CoolProp::HelmholtzEOSMixtureBackend(names)); REQUIRE_NOTHROW(HEOS->update(CoolProp::QT_INPUTS, 0, HEOS->Ttriple());); double p_EOS = HEOS->p(); double p_sat_min_liquid = HEOS->get_components()[0]->pEOS->sat_min_liquid.p; double p_sat_min_vapor = HEOS->get_components()[0]->pEOS->sat_min_vapor.p; double err_sat_min_liquid = std::abs(p_EOS-p_sat_min_liquid)/p_sat_min_liquid; double err_sat_min_vapor = std::abs(p_EOS-p_sat_min_vapor)/p_sat_min_vapor; double p_triple_liquid = HEOS->get_components()[0]->triple_liquid.p; double p_triple_vapor = HEOS->get_components()[0]->triple_liquid.p; double err_triple_liquid = std::abs(p_EOS-p_triple_liquid)/p_triple_liquid; double err_triple_vapor = std::abs(p_EOS-p_triple_vapor)/p_triple_vapor; CAPTURE(err_sat_min_liquid); CAPTURE(err_sat_min_vapor); CHECK(err_sat_min_liquid < 1e-3); CHECK(err_sat_min_vapor < 1e-3); CHECK(err_triple_liquid < 1e-3); CHECK(err_triple_vapor < 1e-3); } // std::ostringstream ss2; // ss2 << "Liquid density error < 3% for fluid " << fluids[i] << " at " << T << " K"; // SECTION(ss2.str(), "") // { // double rho_EOS = AS->rhomolar(); // double rho_anc = AS->saturation_ancillary(CoolProp::iDmolar, 0, CoolProp::iT, T); // double err = std::abs(rho_EOS-rho_anc)/rho_anc; // CAPTURE(rho_EOS); // CAPTURE(rho_anc); // CAPTURE(T); // CHECK(err < 0.03); // } // std::ostringstream ss3; // ss3 << "Vapor density error < 3% for fluid " << fluids[i] << " at " << T << " K"; // SECTION(ss3.str(), "") // { // double rho_EOS = AS->rhomolar(); // double rho_anc = AS->saturation_ancillary(CoolProp::iDmolar, 1, CoolProp::iT, T); // double err = std::abs(rho_EOS-rho_anc)/rho_anc; // CAPTURE(rho_EOS); // CAPTURE(rho_anc); // CAPTURE(T); // CHECK(err < 0.03); // } } } //TEST_CASE("Test that states agree with CoolProp", "[states]") //{ // std::vector fluids = strsplit(CoolProp::get_global_param_string("fluids_list"),','); // for (std::size_t i = 0; i < fluids.size(); ++i) // { // shared_ptr AS(CoolProp::AbstractState::factory("HEOS",fluids[i])); // // CoolProp::SimpleState &triple_liquid = AS->get_state("triple_liquid"); // CoolProp::SimpleState &triple_vapor = AS->get_state("triple_vapor"); // // // See https://groups.google.com/forum/?fromgroups#!topic/catch-forum/mRBKqtTrITU // std::ostringstream ss1; // ss1 << "Check state for triple_liquid for " << fluids[i]; // SECTION(ss1.str(),"") // { // std::string note = "The enthalpy and entropy are hardcoded in the fluid JSON files. They MUST agree with the values calculated by the EOS"; // AS->update(CoolProp::DmolarT_INPUTS, hs_anchor.rhomolar, hs_anchor.T); // CAPTURE(hs_anchor.hmolar); // CAPTURE(hs_anchor.smolar); // double EOS_hmolar = AS->hmolar(); // double EOS_smolar = AS->smolar(); // CHECK( std::abs(EOS_hmolar - hs_anchor.hmolar) < 1e-3); // CHECK( std::abs(EOS_smolar - hs_anchor.smolar) < 1e-3); // } // // // See https://groups.google.com/forum/?fromgroups#!topic/catch-forum/mRBKqtTrITU // std::ostringstream ss2; // ss2 << "Check state for triple_vapor for " << fluids[i]; // SECTION(ss2.str(),"") // { // std::string note = "The enthalpy and entropy are hardcoded in the fluid JSON files. They MUST agree with the values calculated by the EOS"; // AS->update(CoolProp::DmolarT_INPUTS, hs_anchor.rhomolar, hs_anchor.T); // CAPTURE(hs_anchor.hmolar); // CAPTURE(hs_anchor.smolar); // double EOS_hmolar = AS->hmolar(); // double EOS_smolar = AS->smolar(); // CHECK( std::abs(EOS_hmolar - hs_anchor.hmolar) < 1e-3); // CHECK( std::abs(EOS_smolar - hs_anchor.smolar) < 1e-3); // } // } //} #endif