{ "ALIASES": [ "nButane", "butane", "BUTANE", "N-BUTANE" ], "ANCILLARIES": { "pL": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02500890020828983, "n": [ -5.805352213973263, -11.51448089471748, 18.238781113551752, -7.570052478022171, -1.4755071099444654, -1.328641564172384 ], "reducing_value": 3796000.0, "t": [ 0.978, 1.371, 1.499, 1.748, 4.108, 4.752 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.02366371569104686, "n": [ 0.06986482880463143, -6.689091326409199, 4.774874567188075, -5.7054710938841655, 1.8437119133933968, -3.735372218319482 ], "reducing_value": 3796000.0, "t": [ 0.743, 0.984, 1.886, 2.16, 3.286, 4.231 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.21170510433432543, "n": [ 7.6544950329552, -16.928503641708495, 14.176327512939299, -2.3511736019127136, 5.431931351600508, -13.286388570143172 ], "reducing_value": 3922.7696129878086, "t": [ 0.501, 0.742, 0.917, 1.387, 9.328, 12.623 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 425.125, "Tmax": 425.124999999999, "Tmin": 134.895, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 1.1838723681035446, "n": [ -3.756767939636941, -2.819084986331516, 2.3817493893256763, -27.835034497609627, 409.95394459399324, -539.2138907428523 ], "reducing_value": 3922.7696129878086, "t": [ 0.448, 1.717, 4.443, 7.472, 13.095, 14.725 ], "type": "rhoV", "using_tau_r": true }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 425.125, "a": [ 0.05138 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.209 ] } }, "CAS": "106-97-8", "ENVIRONMENTAL": { "ASHRAE34": "A3", "FH": 4, "GWP100": 3.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "n-Butane", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Buecker-JPCRD-2006B", "T_max": 340, "T_max_units": "K", "Ttriple": 134.895, "Ttriple_units": "K", "accentric": 0.200810094644, "accentric_units": "-", "alpha0": [ { "a1": 12.54882924, "a2": -5.46976878, "type": "IdealGasHelmholtzLead" }, { "a": 3.24680487, "type": "IdealGasHelmholtzLogTau" }, { "n": [ 5.54913289, 11.4648996, 7.59987584, 9.66033239 ], "t": [ 0.774840445, 3.340602552, 4.970513096, 9.975553778 ], "type": "IdealGasHelmholtzPlanckEinstein" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 4, 4, 1, 1, 2, 7, 8, 8, 1, 2, 3, 3, 4, 5, 5, 10, 2, 6 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 1, 2, 2, 2, 2, 2, 2, 2, 2, 3, 3 ], "n": [ 2.5536998241635, -4.4585951806696, 0.82425886369063, 0.11215007011442, -0.035910933680333, 0.016790508518103, 0.032734072508724, 0.95571232982005, -1.0003385753419, 0.085581548803855, -0.025147918369616, -0.0015202958578918, 0.004706068232642, -0.097845414174006, -0.04831790415876, 0.17841271865468, 0.018173836739334, -0.11399068074953, 0.019329896666669, 0.001157587740101, 0.00015253808698116, -0.043688558458471, -0.0082403190629989 ], "t": [ 0.5, 1, 1.5, 0, 0.5, 0.5, 0.75, 2, 2.5, 2.5, 1.5, 1, 1.5, 4, 7, 3, 7, 3, 1, 6, 0, 6, 13 ], "type": "ResidualHelmholtzPower" }, { "beta": [ 150, 200 ], "d": [ 1, 2 ], "epsilon": [ 0.85, 1 ], "eta": [ 10, 10 ], "gamma": [ 1.16, 1.13 ], "n": [ -0.028390056949441, 0.0014904666224681 ], "t": [ 2, 0 ], "type": "ResidualHelmholtzGaussian" } ], "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.0581222, "molar_mass_units": "kg/mol", "p_max": 12000000, "p_max_units": "Pa", "pseudo_pure": false, "ptriple": 0.6656588872, "ptriple_units": "Pa", "reducing_state": { "T": 425.125, "T_units": "K", "p": 3796000, "p_units": "Pa", "rhomolar": 3922.769612987809, "rhomolar_units": "mol/m^3" }, "rhoLtriple": 12645.04606150976, "rhoLtriple_units": "mol/m^3", "rhoVtriple": 0.0005936113826349512, "rhoVtriple_units": "mol/m^3" } ], "NAME": "n-Butane" }