{ "ALIASES": [ "H2S", "HYDROGENSULFIDE" ], "ANCILLARIES": { "pL": { "T_r": 373.1, "Tmax": 373.09999999999945, "Tmin": 187.7, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.01406124754110838, "n": [ -6.761826097619247, -0.005988209650772923, -6.882637639835571, -2.8254550876910356, 7.704835506786447, 1.7417891509345698 ], "reducing_value": 9000000.0, "t": [ 1.003, 1.146, 1.668, 4.886, 1.558, 9.098 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 373.1, "Tmax": 373.09999999999945, "Tmin": 187.7, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.019173536478978015, "n": [ 0.016005313259314074, -5.84689331691651, 0.378166392177876, -0.33675173635383543, -1.6596226528944937, -1.8779907937289753 ], "reducing_value": 9000000.0, "t": [ 0.512, 0.974, 1.577, 2.795, 3.791, 7.388 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 373.1, "Tmax": 373.09999999999945, "Tmin": 187.7, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.12757076402429846, "n": [ 51.601033693983716, -49.93595719794271, 6.987088261412919, -24.784697586038508, 84.07792676768513, -68.55133880200839 ], "reducing_value": 10190.0, "t": [ 0.572, 0.586, 2.075, 3.069, 4.223, 4.619 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 373.1, "Tmax": 373.09999999999945, "Tmin": 187.7, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.1081652393724486, "n": [ -5.046830785558678, -38.485729404620876, 41.23869786806366, -2.8100720902410004, -10.142249397446074, 21.5382763129489 ], "reducing_value": 10190.0, "t": [ 0.532, 0.681, 0.691, 1.195, 6.002, 9.033 ], "type": "rhoV", "using_tau_r": true }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 373.1, "a": [ 0.078557 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.2074 ] } }, "CAS": "7783-06-4", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 4, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 4, "Name": "HydrogenSulfide", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Lemmon-JCED-2006", "STATES": { "reducing": { "T": 373.1, "T_units": "K", "p": 9000000, "p_units": "Pa", "rhomolar": 10190, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 187.7, "T_units": "K", "p": 23.258855840736683, "p_units": "Pa", "rhomolar": 29116.326840626763, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 187.7, "T_units": "K", "p": 23.258855840736683, "p_units": "Pa", "rhomolar": 15.024228571877876, "rhomolar_units": "mol/m^3" } }, "T_max": 760, "T_max_units": "K", "Ttriple": 187.7, "Ttriple_units": "K", "accentric": 0.1005, "accentric_units": "-", "alpha0": [ { "a1": -4.0740770957, "a2": 3.7632137341, "type": "IdealGasHelmholtzLead" }, { "a": 3, "type": "IdealGasHelmholtzLogTau" }, { "n": [ -0.002753352822675789 ], "t": [ -1.5 ], "type": "IdealGasHelmholtzPower" }, { "n": [ 1.1364, 1.9721 ], "t": [ 4.886089520235862, 10.62717770034843 ], "type": "IdealGasHelmholtzPlanckEinstein" } ], "alphar": [ { "d": [ 1, 1, 1, 2, 3, 7, 2, 5, 1, 4, 3, 4 ], "l": [ 0, 0, 0, 0, 0, 0, 1, 1, 2, 2, 3, 3 ], "n": [ 0.87641, -2.0367, 0.21634, -0.050199, 0.066994, 0.00019076, 0.20227, -0.0045348, -0.2223, -0.034714, -0.014885, 0.0074154 ], "t": [ 0.25, 1.125, 1.5, 1.375, 0.25, 0.875, 0.625, 1.75, 3.625, 3.625, 14.5, 12 ], "type": "ResidualHelmholtzPower" } ], "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.03408088, "molar_mass_units": "kg/mol", "p_max": 170000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "HydrogenSulfide", "REFPROP_NAME": "H2S", "STATES": { "critical": { "T": 373.1, "T_units": "K", "p": 9000000.0, "p_units": "Pa", "rhomolar": 10190.0, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 187.7, "T_units": "K", "p": 23.258855840736683, "p_units": "Pa", "rhomolar": 29116.326840626763, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 187.7, "T_units": "K", "p": 23.258855840736683, "p_units": "Pa", "rhomolar": 15.024228571877876, "rhomolar_units": "mol/m^3" } }, "TRANSPORT": { "viscosity": { "BibTeX": "QuinonesCisneros-JCED-2012", "dilute": { "C": 8.7721e-07, "T_reducing": 276, "a": [ 0.53242, 0.93715, -0.69339, 1.16432, -0.84306, 0.20534 ], "t": [ 0, -1, -2, -3, -4, -5 ], "type": "collision_integral_powers_of_Tstar" }, "epsilon_over_k": 355.8, "epsilon_over_k_units": "K", "higher_order": { "Aa": [ 6.89659e-08, -2.20494e-08, -4.26126e-08 ], "Aaa": [ 7.8238e-13, -6.4717e-13, 1.39066e-12 ], "Ai": [ 0, 0, 0 ], "Ar": [ 1.53406e-07, 8.45198e-09, -1.13967e-07 ], "Arr": [ -9.75792e-12, -3.19303e-12, 1.24263e-11 ], "Na": 1, "Naa": 1, "Nr": 1, "Nrr": 1, "T_reduce": 373.1, "c1": 0, "c2": 0, "type": "friction_theory" }, "initial_density": { "b": [ -19.572881, 219.73999, -1015.3226, 2471.01251, -3375.1717, 2491.6597, -787.26086, 14.085455, -0.34664158 ], "t": [ 0, -0.25, -0.5, -0.75, -1.0, -1.25, -1.5, -2.5, -5.5 ], "type": "Rainwater-Friend" }, "sigma_eta": 3.565e-10, "sigma_eta_units": "m" } } }