{ "ALIASES": [ "propyne", "PROPYNE" ], "ANCILLARIES": { "hL": { "A": [ 489430.1928137043, -12559.975219640193, 127.78092168914995, -0.702707833661447, 0.00228454694348079, -4.4054846286563965e-06, 4.6747012277650505e-09, -2.1099857389849547e-12 ], "B": [ 1, -0.0024659015982872365 ], "Tmax": 402.28, "Tmin": 273.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 47.58048444295673, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -1755985.4208880162, 39763.950316042305, -379.4096795244761, 1.995812587171015, -0.006264745324056042, 1.1741545694557763e-05, -1.2174769886088845e-08, 5.3930154625143995e-12 ], "B": [ 1, -0.0024651826899615703 ], "Tmax": 402.28, "Tmin": 273.0, "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 102.20591855257635, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.012366531953733606, "n": [ 0.4371507863196512, -6.66393075926699, -0.2170324722957424, 13.288458369708717, -24.057488658628785, 1855841.7713583934 ], "reducing_value": 5626000.0, "t": [ 0.775, 0.959, 1.864, 4.493, 5.159, 19.1 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.012297710682296348, "n": [ 0.0025352410381648404, -0.03566614580246839, -6.474512126273843, 0.4178712360656155, -1.9479103016021955, -342.07305237113997 ], "reducing_value": 5626000.0, "t": [ 0.243, 0.628, 0.992, 1.949, 5.259, 11.136 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 1.7690932219500133, "n": [ 0.676908949567043, 42.124365852994195, -52.6498660929799, 148.86365466555566, -17709.824791659536, 71543.36247766066 ], "reducing_value": 6113.33, "t": [ 0.175, 1.172, 1.358, 3.662, 7.586, 9.174 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.6935914353018102, "n": [ -5.066155131330643, 1779.1130020151943, -1782.2051460501207, 4.756104080644848, -2.3713377912727562, 59.371736976095974 ], "reducing_value": 6113.33, "t": [ 0.192, 0.32, 0.321, 0.498, 1.309, 7.491 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -55.48282864066248, -6.541171541806979, 0.10950439815899796, -0.0007645831787768069, 2.8897701368065278e-06, -6.194904450400679e-09, 7.112292776005543e-12, -3.411798897167711e-15 ], "B": [ 1, -0.0024659363163960137 ], "Tmax": 402.28, "Tmin": 273.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.11807509036151664, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ -2360.5644699479662, 61.59548424216776, -0.6358948853139325, 0.003526604441275276, -1.15161985871011e-05, 2.2269984945753825e-08, -2.3687531241670788e-11, 1.0716051795126059e-14 ], "B": [ 1, -0.0024653070822556215 ], "Tmax": 402.28, "Tmin": 273.0, "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.25206463613570396, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 402.38, "a": [ 0.05801 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.205 ] } }, "CAS": "74-99-7", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 4, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "Propyne", "ODP": -1.0, "PH": 1 }, "EOS": [ { "BibTeX_CP0": "Polt-CT-1992", "BibTeX_EOS": "Polt-CT-1992", "STATES": { "hs_anchor": { "T": 442.61800000000005, "T_units": "K", "hmolar": 31492.825356715988, "hmolar_units": "J/mol", "p": 9149388.83636857, "p_units": "Pa", "rhomolar": 5501.997, "rhomolar_units": "mol/m^3", "smolar": 102.0284806898826, "smolar_units": "J/mol/K" }, "reducing": { "T": 402.38, "T_units": "K", "hmolar": 26411.964308112354, "hmolar_units": "J/mol", "p": 5626000, "p_units": "Pa", "rhomolar": 6113.33, "rhomolar_units": "mol/m^3", "smolar": 91.42663714962089, "smolar_units": "J/mol/K" }, "sat_min_liquid": { "T": 273.0, "T_units": "K", "hmolar": 7998.893547412948, "hmolar_units": "J/mol", "p": 263566.9059878346, "p_units": "Pa", "rhomolar": 16279.04180395429, "rhomolar_units": "mol/m^3", "smolar": 40.012311656383055, "smolar_units": "J/mol/K" }, "sat_min_vapor": { "T": 273.0, "T_units": "K", "hmolar": 27840.96199279927, "hmolar_units": "J/mol", "p": 263566.9059787229, "p_units": "Pa", "rhomolar": 124.13577692560153, "rhomolar_units": "mol/m^3", "smolar": 112.69388105369914, "smolar_units": "J/mol/K" } }, "T_max": 474, "T_max_units": "K", "Ttriple": 170.5, "Ttriple_units": "K", "accentric": 0.204, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 402.38, "c": [ 1.649840044261093, 0.02333952849909193, -1.673911795340558e-05, 6.980952359188388e-09, -1.29200161168108e-12 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -11.004154248087, "a2": 8.92674898200796, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ -0.986950667682466, 4.59528109357232, -8.86063623531859, 5.56346955560542, -1.57450028544218, -0.15906875357343, 0.235738270184042, 0.440755494598713, 0.196126150614333, -0.367759650330219, 0.00792931851007852, 0.00247509085735293, 0.00832903610194452, 1.02590136933231, -2.20786016506394, 1.07889905203761 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 1.65533788, 1.65533788, 1.65533788, 1.65533788, 1.65533788, 1.65533788 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ -3.821884669859, 8.30345065618981, -4.4832307260286, -1.02590136933231, 2.20786016506394, -1.07889905203761 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "gas_constant": 8.3143, "gas_constant_units": "J/mol/K", "molar_mass": 0.04006000000000001, "molar_mass_units": "kg/mol", "p_max": 31800000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "Propyne", "REFPROP_NAME": "PROPYNE", "STATES": { "critical": { "T": 402.38, "T_units": "K", "p": 5626000.0, "p_units": "Pa", "rhomolar": 6113.33, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 273.0, "T_units": "K", "hmolar": 7998.893547412948, "hmolar_units": "J/mol", "p": 263566.9059878346, "p_units": "Pa", "rhomolar": 16279.04180395429, "rhomolar_units": "mol/m^3", "smolar": 40.012311656383055, "smolar_units": "J/mol/K" }, "triple_vapor": { "T": 273.0, "T_units": "K", "hmolar": 27840.96199279927, "hmolar_units": "J/mol", "p": 263566.9059787229, "p_units": "Pa", "rhomolar": 124.13577692560153, "rhomolar_units": "mol/m^3", "smolar": 112.69388105369914, "smolar_units": "J/mol/K" } } }