{ "ALIASES": [ "methanol", "METHANOL" ], "ANCILLARIES": { "hL": { "A": [ -53375.719972235194, 35.66463263615916, 1.4353310701558266, -0.008950393787956215, 2.9337423838940063e-05, -5.499011031821811e-08, 5.51441189018401e-11, -2.327718911107427e-14 ], "B": [ 1, -0.0019141281204627732 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 61.2856370214995, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -6842.637996646017, 1219.8752160805627, -13.740406862193629, 0.07653430639346578, -0.0002466536962808615, 4.615332840950274e-07, -4.657213225109496e-10, 1.9655935040301265e-13 ], "B": [ 1, -0.0019076194007431187 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 110.86886551798398, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "melting_line": { "BibTeX": "deReuck-BOOK-1993", "T_m": 337.8, "parts": [ { "T_0": 175.61, "T_max": 245.9, "T_min": 175.61, "a": [ 5330770000.0, 4524780000.0, 38888610000.0 ], "p_0": 0.187, "t": [ 1, 1.5, 4 ] } ], "type": "polynomial_in_Theta" }, "pL": { "T_r": 512.5, "Tmax": 512.4999999999987, "Tmin": 175.61, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.616314584184563, "n": [ -0.06786072630620305, 0.37064921000560125, -3.6850178941332135, -5.531504842398972, -0.1261742218723768, -1.6655134662275959 ], "reducing_value": 8215850.0, "t": [ 0.054, 0.298, 0.728, 1.284, 3.131, 3.97 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 512.5, "Tmax": 512.4999999999987, "Tmin": 175.61, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 1.1479027322796709, "n": [ -0.0447244507994909, 2.329401753678273, -9.196622819856332, -10.174860953774617, 45.49763577474272, -39.730762470567974 ], "reducing_value": 8215850.0, "t": [ 0.061, 0.608, 0.825, 2.846, 4.042, 4.296 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 512.5, "Tmax": 512.4999999999987, "Tmin": 175.61, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 5.46722419332033, "n": [ 1.3068237510561265, 70.59427259347439, -189.29658717018955, 1579.5702126119343, -1503.171465635914, 1224.7374907070093 ], "reducing_value": 8520.024867237415, "t": [ 0.182, 2.205, 2.877, 4.603, 4.808, 17.68 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 512.5, "Tmax": 512.4999999999987, "Tmin": 175.61, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 5.061502849483923, "n": [ -1.4150575213461603, 54.70138118736733, -107.17903730678354, 3012.9973099493213, -2968.802266130763, -23.433991775839367 ], "reducing_value": 8520.024867237415, "t": [ 0.155, 0.626, 0.74, 1.164, 1.17, 15.066 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -250.33785244093633, 1.698468990250577, -0.005989579204133027, 1.1547409569288378e-05, -2.8180272642465586e-09, -3.224863238909218e-11, 5.596444454176415e-14, -3.0271372578395995e-17 ], "B": [ 1, -0.0019160965820848028 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.11022584651395562, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 1042.931836841793, -11.779265482195777, 0.06435589383886657, -0.0002002807298958015, 3.505659622088616e-07, -3.0260886058377475e-10, 6.177270734482849e-14, 4.798709485585036e-17 ], "B": [ 1, -0.0019080244468194416 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.21144768345295262, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 513.38, "a": [ 0.22421, -0.21408, 0.083233 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.3355, 1.677, 4.4402 ] } }, "CAS": "67-56-1", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 3, "GWP100": 2.8, "GWP20": -1.0, "GWP500": -1.0, "HH": 2, "Name": "Methanol", "ODP": -1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "", "BibTeX_EOS": "Piazza-FPE-2013", "STATES": { "hs_anchor": { "T": 563.75, "T_units": "K", "hmolar": 13649659.872149948, "hmolar_units": "J/mol", "p": 15029457.577355228, "p_units": "Pa", "rhomolar": 7668.022380513673, "rhomolar_units": "mol/m^3", "smolar": -82.70528168150894, "smolar_units": "J/mol/K" }, "reducing": { "T": 512.5, "T_units": "K", "p": 8215850, "p_units": "Pa", "rhomolar": 8520.024867237415, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 175.61, "T_units": "K", "p": 0.0001867637574117855, "p_units": "Pa", "rhomolar": 28227.37433284738, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 175.61, "T_units": "K", "p": 0.0001867637574117855, "p_units": "Pa", "rhomolar": 0.0001279343965397924, "rhomolar_units": "mol/m^3" } }, "T_max": 580, "T_max_units": "K", "Ttriple": 175.61, "Ttriple_units": "K", "accentric": 0.5720322, "accentric_units": "-", "alpha0": [ { "a1": 13.9864114647, "a2": 3200.6369296, "type": "IdealGasHelmholtzLead" }, { "a": 3.1950423807804, "type": "IdealGasHelmholtzLogTau" }, { "n": [ -0.585735321498174, -0.06899642310301084, 0.008650264506162275 ], "t": [ -1, -2, -3 ], "type": "IdealGasHelmholtzPower" }, { "n": [ 4.70118076896145 ], "t": [ 3.7664265756 ], "type": "IdealGasHelmholtzPlanckEinstein" }, { "a1": -18.655572723326, "a2": -3195.18522006798, "reference": "NBP", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 4, 5, 7, 1, 1, 3, 4, 5, 1, 7, 9, 2, 3, 4, 6, 7 ], "l": [ 0, 0, 0, 0, 0, 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 3, 3, 3 ], "n": [ 0.096352729792779, -1.0848826325874, 0.029919647090261, -0.0017963419593895, 4.7354317752015e-05, 1.0013578850486, -1.2555691488591, 0.854697257175, -0.058295570793694, 0.026935675584229, 0.11504892676606, -0.0051081766133636, 0.0019167368789348, -0.28618221186953, 0.48168213019845, -0.33081091251828, 0.09284208331363, -0.035936470747247 ], "t": [ -0.125, 1.5, 0, -0.875, 1.25, 0.25, 2, 1.75, 2.5, 2.375, 6.875, 5.875, 5, 18.5, 19, 17.5, 14, 12 ], "type": "ResidualHelmholtzPower" }, { "a": 2, "epsilonbar": 5.46341463, "kappabar": 0.00148852832, "m": 0.977118832, "type": "ResidualHelmholtzAssociating", "vbarn": 0.204481952 } ], "gas_constant": 8.314472, "gas_constant_units": "J/mol/K", "molar_mass": 0.03204216, "molar_mass_units": "kg/mol", "p_max": 500000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "Methanol", "REFPROP_NAME": "METHANOL", "STATES": { "critical": { "T": 512.5, "T_units": "K", "p": 8215850.0, "p_units": "Pa", "rhomolar": 8520.024867237415, "rhomolar_units": "mol/m^3" }, "triple_liquid": { "T": 175.61, "T_units": "K", "p": 0.0001867637574117855, "p_units": "Pa", "rhomolar": 28227.37433284738, "rhomolar_units": "mol/m^3" }, "triple_vapor": { "T": 175.61, "T_units": "K", "p": 0.0001867637574117855, "p_units": "Pa", "rhomolar": 0.0001279343965397924, "rhomolar_units": "mol/m^3" } } }