{ "ALIASES": [ "propyne", "PROPYNE" ], "ANCILLARIES": { "hL": { "A": [ 27072455.61855728, -535860.0336040161, 4538.998928759383, -21.343641845290442, 0.060185446084785925, -0.00010177545026901135, 9.5566285295213e-08, -3.8440912085804694e-11 ], "B": [ 1, -0.0024710820991143126 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 23.11637136310037, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -62428650.73953163, 1233937.1893803505, -10444.157793623626, 49.08291889850264, -0.13832945734848537, 0.00023379423008505822, -2.194202771454447e-07, 8.821954927272375e-11 ], "B": [ 1, -0.0024703699259819383 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 50.10025977928581, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.012366531953733606, "n": [ 0.4371507863196512, -6.66393075926699, -0.2170324722957424, 13.288458369708717, -24.057488658628785, 1855841.7713583934 ], "reducing_value": 5626000.0, "t": [ 0.775, 0.959, 1.864, 4.493, 5.159, 19.1 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.012297710682296348, "n": [ 0.0025352410381648404, -0.03566614580246839, -6.474512126273843, 0.4178712360656155, -1.9479103016021955, -342.07305237113997 ], "reducing_value": 5626000.0, "t": [ 0.243, 0.628, 0.992, 1.949, 5.259, 11.136 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 1.7690932219500133, "n": [ 0.676908949567043, 42.124365852994195, -52.6498660929799, 148.86365466555566, -17709.824791659536, 71543.36247766066 ], "reducing_value": 6113.33, "t": [ 0.175, 1.172, 1.358, 3.662, 7.586, 9.174 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 402.38, "Tmax": 402.37999999999914, "Tmin": 273.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.6935914353018102, "n": [ -5.066155131330643, 1779.1130020151943, -1782.2051460501207, 4.756104080644848, -2.3713377912727562, 59.371736976095974 ], "reducing_value": 6113.33, "t": [ 0.192, 0.32, 0.321, 0.498, 1.309, 7.491 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ 64963.858228195495, -1286.816684457048, 10.90461482651636, -0.051290583939747815, 0.00014466122299768887, -2.4467224876841525e-07, 2.2978395914762625e-10, -9.244198409326608e-14 ], "B": [ 1, -0.0024711808277578158 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.05681951763585502, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ -150021.34384070127, 2968.2508101117655, -25.1369079218804, 0.11816723432526686, -0.00033308887018890264, 5.630297921171934e-07, -5.284530330584984e-10, 2.1247378146415853e-13 ], "B": [ 1, -0.002470479789049751 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.1230057545397818, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 402.38, "a": [ 0.05801 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.205 ] } }, "CAS": "74-99-7", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": 4, "GWP100": -1.0, "GWP20": -1.0, "GWP500": -1.0, "HH": 1, "Name": "Propyne", "ODP": -1.0, "PH": 1 }, "EOS": [ { "BibTeX_CP0": "Polt-CT-1992", "BibTeX_EOS": "Polt-CT-1992", "STATES": { "hs_anchor": { "T": 442.61800000000005, "T_units": "K", "hmolar": 1628.31491990704, "hmolar_units": "J/mol", "p": 9149388.83636857, "p_units": "Pa", "rhomolar": 5501.997, "rhomolar_units": "mol/m^3", "smolar": 10.536641025012846, "smolar_units": "J/mol/K" }, "reducing": { "T": 402.38, "T_units": "K", "p": 5626000, "p_units": "Pa", "rhomolar": 6113.33, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 273.0, "T_units": "K", "p": 263.5669059887786, "p_units": "Pa", "rhomolar": 16279.0418039543, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 273.0, "T_units": "K", "p": 263.5669059887786, "p_units": "Pa", "rhomolar": 124.13577693070359, "rhomolar_units": "mol/m^3" } }, "T_max": 474, "T_max_units": "K", "Ttriple": 170.5, "Ttriple_units": "K", "accentric": 0.204, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 402.38, "c": [ 1.649840044261093, 0.02333952849909193, -1.673911795340558e-05, 6.980952359188388e-09, -1.29200161168108e-12 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -11.004154248087, "a2": 8.92674898200796, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ -0.986950667682466, 4.59528109357232, -8.86063623531859, 5.56346955560542, -1.57450028544218, -0.15906875357343, 0.235738270184042, 0.440755494598713, 0.196126150614333, -0.367759650330219, 0.00792931851007852, 0.00247509085735293, 0.00832903610194452, 1.02590136933231, -2.20786016506394, 1.07889905203761 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 1.65533788, 1.65533788, 1.65533788, 1.65533788, 1.65533788, 1.65533788 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ -3.821884669859, 8.30345065618981, -4.4832307260286, -1.02590136933231, 2.20786016506394, -1.07889905203761 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "gas_constant": 8.3143, "gas_constant_units": "J/mol/K", "molar_mass": 0.04006000000000001, "molar_mass_units": "kg/mol", "p_max": 31800000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "Propyne", "REFPROP_NAME": "PROPYNE", "STATES": { "critical": { "T": 402.38, "T_units": "K", "p": 5626000.0, "p_units": "Pa", "rhomolar": 6113.33, "rhomolar_units": "mol/m^3" }, "triple_liquid": {}, "triple_vapor": {} } }