{ "ALIASES": [], "ANCILLARIES": { "hL": { "A": [ 271370.52232045383, -7293.1813356771345, 70.41372945306244, -0.3636298022591202, 0.0011182587497234515, -2.057307150536002e-06, 2.0965017374727104e-09, -9.135533036924116e-13 ], "B": [ 1, -0.002349997502292111 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 9.705792949329407, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -886793.6495101649, 19843.785231270766, -184.44276703240638, 0.944017157291573, -0.0028879865592337205, 5.28524134069533e-06, -5.360411517319018e-09, 2.3263526101691985e-12 ], "B": [ 1, -0.0023478891340700508 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 21.434484870742835, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 418.83, "Tmax": 418.82999999999896, "Tmin": 273.15, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.03480121499881417, "n": [ -0.03910964005249281, 0.04271700821207559, -8.460176906373917, 2.0544163414455383, -5.417387102558348, 311098.3405989305 ], "reducing_value": 3257000.0, "t": [ 0.063, 0.078, 0.997, 1.08, 4.22, 18.01 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 418.83, "Tmax": 418.82999999999896, "Tmin": 273.15, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.16711623182714685, "n": [ -0.30056837663219454, -3675.7604915544694, 3783.892467766002, -116.51203569138166, 518347803.73777616, -675455943.1429232 ], "reducing_value": 3257000.0, "t": [ 0.562, 1.474, 1.48, 1.671, 19.65, 19.907 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 418.83, "Tmax": 418.82999999999896, "Tmin": 273.15, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 0.8844499285669105, "n": [ 2.5388024373334166, -21.019533461079085, 55.36105635703546, -35.25092830572443, 5.566074608205557, -82.35558694240936 ], "reducing_value": 3393.2000000000003, "t": [ 0.168, 0.377, 0.516, 0.603, 3.002, 6.719 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 418.83, "Tmax": 418.82999999999896, "Tmin": 273.15, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 7.62170938819361, "n": [ -0.25738264700819247, -3.898251196031975, -5.896731894914288, 3484.356562302582, -1305405.1150486593, 294675355.11756265 ], "reducing_value": 3393.2000000000003, "t": [ 0.035, 0.539, 2.097, 7.751, 12.964, 18.768 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ 230.80231485533994, -11.03716247367166, 0.12188192919740198, -0.0006669130231323461, 2.1199101966568706e-06, -3.990411140284002e-09, 4.138791747225136e-12, -1.8292293745302172e-15 ], "B": [ 1, -0.002350313799828104 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.02264603440383084, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ -1088.9357625394873, 31.107642289448194, -0.320678454621214, 0.0017365288215725509, -5.506776271039314e-06, 1.0336366523181821e-08, -1.0683996170836804e-11, 4.705147914776509e-15 ], "B": [ 1, -0.0023483331076600204 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.049779854901517595, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 418.83, "a": [ 0.05239 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.258 ] } }, "CAS": "76-14-2", "ENVIRONMENTAL": { "ASHRAE34": "A1", "FH": 0, "GWP100": 10000.0, "GWP20": 8040.0, "GWP500": 8730.0, "HH": 1, "Name": "R114", "ODP": 1.0, "PH": 0 }, "EOS": [ { "BibTeX_CP0": "Platzer-BOOK-1990", "BibTeX_EOS": "Platzer-BOOK-1990", "STATES": { "hs_anchor": { "T": 460.713, "T_units": "K", "hmolar": 12344.460697435103, "hmolar_units": "J/mol", "p": 5368000.197614328, "p_units": "Pa", "rhomolar": 3053.88, "rhomolar_units": "mol/m^3", "smolar": 39.37441068743607, "smolar_units": "J/mol/K" }, "reducing": { "T": 418.83, "T_units": "K", "p": 3257000, "p_units": "Pa", "rhomolar": 3393.2, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 273.15, "T_units": "K", "p": 88.16238676245308, "p_units": "Pa", "rhomolar": 8941.873943827432, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 273.15, "T_units": "K", "p": 88.16238676245308, "p_units": "Pa", "rhomolar": 40.2224880739269, "rhomolar_units": "mol/m^3" } }, "T_max": 507, "T_max_units": "K", "Ttriple": 180.63, "Ttriple_units": "K", "accentric": 0.2523, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 418.83, "c": [ 2.007414931364566, 0.06662223065231744, -0.0001211907268430731, 1.385112968303604e-07, -7.290244178478347e-11 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -28.2691959611666, "a2": 17.4464013989786, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ 1.07938940032879, -1.99243731009857, -0.155135220175231, -0.121465858429101, -0.0165038674558161, -0.186916017480622, 0.308074956770949, 0.115861545567346, 0.027635877981389, 0.108043424159349, 0.0460684822539207, -0.174822007470687, 0.0317531741331376, -0.340776521025164, 0.323001398918284, -0.0424950543505197 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 1.21104, 1.21104, 1.21104, 1.21104, 1.21104, 1.21104 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ -1.66940287525002, 4.08693538568874, -2.4173923391137, 0.340776521025164, -0.323001398918284, 0.0424950543505197 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.170921, "molar_mass_units": "kg/mol", "p_max": 21000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R114", "REFPROP_NAME": "R114", "STATES": { "critical": { "T": 418.83, "T_units": "K", "p": 3257000.0, "p_units": "Pa", "rhomolar": 3393.2000000000003, "rhomolar_units": "mol/m^3" }, "triple_liquid": {}, "triple_vapor": {} } }