{ "ALIASES": [], "ANCILLARIES": { "hL": { "A": [ -31855.62836474714, 434.21215148307016, -2.5898349992840317, -0.003955638546671772, 0.0001901388357495896, -1.2793652032725943e-06, 3.707999994516502e-09, -4.124087728287611e-12 ], "B": [ 1, -0.0043682779072460745 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 244.39478977885483, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ -34228.73227642573, 2310.106315489345, -48.10121508750445, 0.5280196155871898, -0.003423977441294175, 1.3159956320007756e-05, -2.7803141562754293e-08, 2.4975245822476904e-11 ], "B": [ 1, -0.004366824270619729 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 508.83986085067534, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 227.51, "Tmax": 227.50999999999948, "Tmin": 120.00000000000001, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.056557492124520437, "n": [ 0.008252828633147618, -0.04268492478666484, -6.191901989609247, 0.35599848378130283, -2.9637839791302523, 25.20051432671624 ], "reducing_value": 3750000.0, "t": [ 0.008, 0.571, 0.981, 1.703, 3.774, 12.925 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 227.51, "Tmax": 227.50999999999948, "Tmin": 120.00000000000001, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.330806453728516, "n": [ 0.02977525843409753, -0.18722735733648588, -172.7753199533091, 169.90412537233442, -4.8505113444549774, -0.3348515793791319 ], "reducing_value": 3750000.0, "t": [ 0.063, 0.359, 1.297, 1.319, 2.397, 5.575 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 227.51, "Tmax": 227.50999999999948, "Tmin": 120.00000000000001, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 4.396907124601834, "n": [ 5.827780226789797, -7.357043181841783, 21.151996405133726, -14035.045227608716, 101927.9835601533, -2047064.5653545645 ], "reducing_value": 7109.4194, "t": [ 0.602, 1.14, 3.047, 9.942, 12.357, 18.15 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 227.51, "Tmax": 227.50999999999948, "Tmin": 120.00000000000001, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 5.100892756019415, "n": [ -24.42524992497142, 25.211693075765005, -26.691222148617776, 157.32675143002658, -23298.685615045863, 1035275.9594118744 ], "reducing_value": 7109.4194, "t": [ 0.736, 0.901, 2.569, 5.322, 12.251, 18.19 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -450.1436449879841, 12.478903574801599, -0.178652613643015, 0.0015191396381315353, -7.783548672755807e-06, 2.350333130856377e-08, -3.83145271750308e-11, 2.565129903621309e-14 ], "B": [ 1, -0.0043669422800070475 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 1.0993469538395004, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 725.7578855937691, -16.310062715602037, 0.1668557670186865, -0.0008833775347362652, 1.8287928320112446e-06, 3.485540418463794e-09, -2.392561276123307e-11, 3.311490828238214e-14 ], "B": [ 1, -0.004366356465498869 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 2.257760271761315, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 227.51, "a": [ 0.0423 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.24 ] } }, "CAS": "75-73-0", "ENVIRONMENTAL": { "ASHRAE34": "UNKNOWN", "FH": -1, "GWP100": 7390.0, "GWP20": 5210.0, "GWP500": 11200.0, "HH": -1, "Name": "R14", "ODP": -1.0, "PH": -1 }, "EOS": [ { "BibTeX_CP0": "Platzer-BOOK-1990", "BibTeX_EOS": "Platzer-BOOK-1990", "STATES": { "hs_anchor": { "T": 250.26100000000002, "T_units": "K", "hmolar": -7511.796049668082, "hmolar_units": "J/mol", "p": 6118662.656716033, "p_units": "Pa", "rhomolar": 6398.47746, "rhomolar_units": "mol/m^3", "smolar": -26.923608741083974, "smolar_units": "J/mol/K" }, "reducing": { "T": 227.51, "T_units": "K", "p": 3750000, "p_units": "Pa", "rhomolar": 7109.4194, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 120.0, "T_units": "K", "p": 11.294329044453496, "p_units": "Pa", "rhomolar": 19669.032618775986, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 120.0, "T_units": "K", "p": 11.294329044453496, "p_units": "Pa", "rhomolar": 11.391239450518714, "rhomolar_units": "mol/m^3" } }, "T_max": 623, "T_max_units": "K", "Ttriple": 89.54, "Ttriple_units": "K", "accentric": 0.1785, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 227.51, "c": [ 3.946282613411975, -0.008858129431283382, 0.0001393877086940782, -3.005436298807747e-07, 2.050274501811892e-10 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -14.8563435687485, "a2": 20.1558709204447, "reference": "OTH", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ 1.03999039734947, -2.4579202542559, 0.799614558381524, -0.749498955282594, 0.152177772596398, -0.293408332036298, 0.717794503774445, -0.0426467444751902, 0.226562749725952, -0.39109169477402, -0.0257394805543082, 0.0554844886106659, 0.00610988262947185, -0.33469874882651, 0.586690904512625, -0.147068929694523 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 0.99832625, 0.99832625, 0.99832625, 0.99832625, 0.99832625, 0.99832625 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ -0.190315426348019, 0.716157134745809, -0.703161905301754, 0.33469874882651, -0.586690904512625, 0.147068929694523 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.0880046, "molar_mass_units": "kg/mol", "p_max": 51000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R14", "REFPROP_NAME": "R14", "STATES": { "critical": { "T": 227.51, "T_units": "K", "p": 3750000.0, "p_units": "Pa", "rhomolar": 7109.4194, "rhomolar_units": "mol/m^3" }, "triple_liquid": {}, "triple_vapor": {} } }