{ "ALIASES": [], "ANCILLARIES": { "hL": { "A": [ -575831.0218837217, 11715.330982470372, -107.92114678938239, 0.5532991180534255, -0.0016846839787413538, 3.044031424846456e-06, -3.024989894270288e-09, 1.2761771435550759e-12 ], "B": [ 1, -0.0021187281864226597 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 122.05182245537617, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "hLV": { "A": [ 532182.3229468557, -10998.69769892905, 101.10024329091402, -0.5144417392501639, 0.001553226052993154, -2.782785015801237e-06, 2.740981548826963e-09, -1.1451726850511885e-12 ], "B": [ 1, -0.002152572157503695 ], "_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy", "max_abs_error": 174.81352909447241, "max_abs_error_units": "J/mol", "type": "rational_polynomial" }, "pL": { "T_r": 451.48, "Tmax": 451.47999999999917, "Tmin": 200.0, "description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.05826785438975968, "n": [ 0.015053861978396133, 0.960309329970009, -6.9145776997149255, -2.9343265925945237, 1384.3706348421958, -2744.0923786590133 ], "reducing_value": 5181200.0, "t": [ 0.363, 0.784, 0.926, 3.236, 19.172, 19.986 ], "type": "pL", "using_tau_r": true }, "pV": { "T_r": 451.48, "Tmax": 451.47999999999917, "Tmin": 200.0, "description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 0.06815685685508388, "n": [ 0.0018788440318928358, -6.563138713373014, 4.137852310206907, -6.289887616085091, 0.10742860069097583, -79.5502994261936 ], "reducing_value": 5181200.0, "t": [ 0.091, 0.987, 2.079, 2.561, 2.725, 15.503 ], "type": "pV", "using_tau_r": true }, "rhoL": { "T_r": 451.48, "Tmax": 451.47999999999917, "Tmin": 200.0, "description": "rho' = rhoc*(1+sum(n_i*theta^t_i))", "max_abserror_percentage": 2.527142850874342, "n": [ 0.5619681997988593, 4.92151800722533, -5.5582908804962186, 30.01966721829401, -42929.54870444089, 216673.96540670822 ], "reducing_value": 5110.765599999999, "t": [ 0.122, 0.902, 1.769, 5.732, 16.703, 19.838 ], "type": "rhoLnoexp", "using_tau_r": false }, "rhoV": { "T_r": 451.48, "Tmax": 451.47999999999917, "Tmin": 200.0, "description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))", "max_abserror_percentage": 2.171498053602172, "n": [ -7.33498076512952, 12.676510112148431, -10.046553362223358, -16.99517541299311, 222.23399842968522, -1233.3931692026647 ], "reducing_value": 5110.765599999999, "t": [ 0.194, 0.256, 0.429, 4.632, 9.16, 13.215 ], "type": "rhoV", "using_tau_r": true }, "sL": { "A": [ -2972.2769928458706, 62.04946912486972, -0.5735396470302134, 0.0029481565502497064, -9.023697137181964e-06, 1.642035956666304e-08, -1.6450226183531387e-11, 7.002045573082725e-15 ], "B": [ 1, -0.0019832057412947925 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.4365708283127496, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "sLV": { "A": [ 3482.3280699751713, -69.34563513656886, 0.6194711480374648, -0.0031103170386885333, 9.361628959254205e-06, -1.68192061633453e-08, 1.667526719107901e-11, -7.033672881327671e-15 ], "B": [ 1, -0.002103652186797974 ], "_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy", "max_abs_error": 0.6194961166472908, "max_abs_error_units": "J/mol/K", "type": "rational_polynomial" }, "surface_tension": { "BibTeX": "Mulero-JPCRD-2012", "Tc": 451.48, "a": [ 0.06924 ], "description": "sigma = sum(a_i*(1-T/Tc)^n_i)", "n": [ 1.259 ] } }, "CAS": "75-43-4", "ENVIRONMENTAL": { "ASHRAE34": "B1", "FH": -1, "GWP100": 151.0, "GWP20": 530.0, "GWP500": 46.0, "HH": -1, "Name": "R21", "ODP": -1.0, "PH": -1 }, "EOS": [ { "BibTeX_CP0": "Platzer-BOOK-1990", "BibTeX_EOS": "Platzer-BOOK-1990", "STATES": { "hs_anchor": { "T": 496.62800000000004, "T_units": "K", "hmolar": 3781.6248069734543, "hmolar_units": "J/mol", "p": 8519917.917064043, "p_units": "Pa", "rhomolar": 4599.689039999999, "rhomolar_units": "mol/m^3", "smolar": 17.322586051772323, "smolar_units": "J/mol/K" }, "reducing": { "T": 451.48, "T_units": "K", "p": 5181200, "p_units": "Pa", "rhomolar": 5110.765599999999, "rhomolar_units": "mol/m^3" }, "sat_min_liquid": { "T": 200.0, "T_units": "K", "p": 0.8728349799124349, "p_units": "Pa", "rhomolar": 15359.760861872839, "rhomolar_units": "mol/m^3" }, "sat_min_vapor": { "T": 200.0, "T_units": "K", "p": 0.8728349799124349, "p_units": "Pa", "rhomolar": 0.5254904978375974, "rhomolar_units": "mol/m^3" } }, "T_max": 473, "T_max_units": "K", "Ttriple": 142.8, "Ttriple_units": "K", "accentric": 0.2061, "accentric_units": "-", "alpha0": [ { "a1": 0, "a2": 0, "type": "IdealGasHelmholtzLead" }, { "a": -1, "type": "IdealGasHelmholtzLogTau" }, { "T0": 298.15, "Tc": 451.48, "c": [ 2.941888561986215, 0.01573866857206258, 4.012367529660798e-06, -3.085298103142579e-08, 2.125677686617732e-11 ], "t": [ 0, 1, 2, 3, 4 ], "type": "IdealGasHelmholtzCP0PolyT" }, { "a1": -19.5492777147267, "a2": 12.6393155496886, "reference": "IIR", "type": "IdealGasHelmholtzEnthalpyEntropyOffset" } ], "alphar": [ { "d": [ 1, 1, 1, 1, 1, 2, 2, 2, 3, 3, 4, 4, 5, 0, 0, 0 ], "l": [ 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0 ], "n": [ 0.50467662375195, -0.732431416212257, -0.868403860880684, 0.146234705622829, -0.280576335158724, 0.864743657302055, -2.70767234069002, 3.30476391081085, -0.210878239585469, 0.449531450327333, 0.120779813434928, -0.277297954448155, 0.030544129220629, -44.3864848810647, 9.26505601085111, -0.551709104525115 ], "t": [ 0, 1, 2, 3, 4, 0, 1, 2, 0, 1, 0, 1, 1, 3, 4, 5 ], "type": "ResidualHelmholtzPower" }, { "d": [ 2, 2, 2, 0, 0, 0 ], "g": [ 0.07470252, 0.07470252, 0.07470252, 0.07470252, 0.07470252, 0.07470252 ], "l": [ 2, 2, 2, 2, 2, 2 ], "n": [ 1.21128809697908, 0.167119476809363, -0.0504876793555323, 44.3864848810647, -9.26505601085111, 0.551709104525115 ], "t": [ 3, 4, 5, 3, 4, 5 ], "type": "ResidualHelmholtzExponential" } ], "gas_constant": 8.31451, "gas_constant_units": "J/mol/K", "molar_mass": 0.1029227, "molar_mass_units": "kg/mol", "p_max": 138000000, "p_max_units": "Pa", "pseudo_pure": false } ], "NAME": "R21", "REFPROP_NAME": "R21", "STATES": { "critical": { "T": 451.48, "T_units": "K", "p": 5181200.0, "p_units": "Pa", "rhomolar": 5110.765599999999, "rhomolar_units": "mol/m^3" }, "triple_liquid": {}, "triple_vapor": {} } }