Files
CoolProp/dev/fluids/HydrogenSulfide.json

496 lines
11 KiB
JSON

{
"ANCILLARIES": {
"hL": {
"A": [
-2512.979879109487,
-703.55070918563,
10.150521090469136,
-0.06796058516090335,
0.00026436009375351954,
-6.098639311350994e-07,
7.75194183710175e-10,
-4.2017278925376e-13
],
"B": [
1,
-0.0026576978556386356
],
"Tmax": 373.0,
"Tmin": 187.70000000000002,
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
"max_abs_error": 147.15437612672258,
"max_abs_error_units": "J/mol",
"type": "rational_polynomial"
},
"hLV": {
"A": [
-53372.19267937265,
2125.9106086754664,
-26.43630190812571,
0.17356701906425817,
-0.0006745602684261167,
1.55778324935064e-06,
-1.982577010969642e-09,
1.0756137006411702e-12
],
"B": [
1,
-0.002654906827922634
],
"Tmax": 373.0,
"Tmin": 187.70000000000002,
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
"max_abs_error": 318.12649274478827,
"max_abs_error_units": "J/mol",
"type": "rational_polynomial"
},
"pS": {
"T_r": 373.1,
"Tmax": 373.09999999999945,
"Tmin": 187.7,
"description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.01406124754110838,
"n": [
-6.761826097619247,
-0.005988209650772923,
-6.882637639835571,
-2.8254550876910356,
7.704835506786447,
1.7417891509345698
],
"reducing_value": 9000000.0,
"t": [
1.003,
1.146,
1.668,
4.886,
1.558,
9.098
],
"type": "pL",
"using_tau_r": true
},
"rhoL": {
"T_r": 373.1,
"Tmax": 373.09999999999945,
"Tmin": 187.7,
"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.12757076402429846,
"n": [
51.601033693983716,
-49.93595719794271,
6.987088261412919,
-24.784697586038508,
84.07792676768513,
-68.55133880200839
],
"reducing_value": 10190.0,
"t": [
0.572,
0.586,
2.075,
3.069,
4.223,
4.619
],
"type": "rhoLnoexp",
"using_tau_r": false
},
"rhoV": {
"T_r": 373.1,
"Tmax": 373.09999999999945,
"Tmin": 187.7,
"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.1081652393724486,
"n": [
-5.046830785558678,
-38.485729404620876,
41.23869786806366,
-2.8100720902410004,
-10.142249397446074,
21.5382763129489
],
"reducing_value": 10190.0,
"t": [
0.532,
0.681,
0.691,
1.195,
6.002,
9.033
],
"type": "rhoV",
"using_tau_r": true
},
"sL": {
"A": [
-165.1137699576359,
0.7099712841197781,
0.007060185874105087,
-8.670401222512094e-05,
4.1835496340800596e-07,
-1.0830453891155858e-09,
1.4799927370323627e-12,
-8.428150335021316e-16
],
"B": [
1,
-0.0026580487859094444
],
"Tmax": 373.0,
"Tmin": 187.70000000000002,
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
"max_abs_error": 0.3900517424811447,
"max_abs_error_units": "J/mol/K",
"type": "rational_polynomial"
},
"sLV": {
"A": [
541.5753746287403,
-6.028719018099555,
0.02456974882193629,
-6.027712235738192e-08,
-3.811887111312869e-07,
1.4746391222525634e-09,
-2.4207510874923276e-12,
1.53586474984037e-15
],
"B": [
1,
-0.0026550266818023416
],
"Tmax": 373.0,
"Tmin": 187.70000000000002,
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
"max_abs_error": 0.850903723438392,
"max_abs_error_units": "J/mol/K",
"type": "rational_polynomial"
},
"surface_tension": {
"BibTeX": "Mulero-JPCRD-2012",
"Tc": 373.1,
"a": [
0.078557
],
"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
"n": [
1.2074
]
}
},
"EOS": [
{
"BibTeX_CP0": "",
"BibTeX_EOS": "Lemmon-JCED-2006",
"STATES": {
"hs_anchor": {
"T": 410.4100000000001,
"T_units": "K",
"hmolar": 17978.612588857857,
"hmolar_units": "J/mol",
"p": 14150339.756136104,
"p_units": "Pa",
"rhomolar": 9171.0,
"rhomolar_units": "mol/m^3",
"smolar": 54.72626070119076,
"smolar_units": "J/mol/K"
},
"reducing": {
"T": 373.1,
"T_units": "K",
"hmolar": 15354.56284866059,
"hmolar_units": "J/mol",
"p": 9000000,
"p_units": "Pa",
"rhomolar": 10190,
"rhomolar_units": "mol/m^3",
"smolar": 49.376520663316796,
"smolar_units": "J/mol/K"
},
"sat_min_liquid": {
"T": 187.7,
"T_units": "K",
"hmolar": -1720.1750502299365,
"hmolar_units": "J/mol",
"p": 23258.855838991203,
"p_units": "Pa",
"rhomolar": 29116.326840626723,
"rhomolar_units": "mol/m^3",
"smolar": -8.587703261137086,
"smolar_units": "J/mol/K"
},
"sat_min_vapor": {
"T": 187.7,
"T_units": "K",
"hmolar": 17876.163932083127,
"hmolar_units": "J/mol",
"p": 23258.868399596802,
"p_units": "Pa",
"rhomolar": 15.024236750641014,
"rhomolar_units": "mol/m^3",
"smolar": 95.81473758279512,
"smolar_units": "J/mol/K"
}
},
"T_max": 760,
"T_max_units": "K",
"Ttriple": 187.7,
"Ttriple_units": "K",
"acentric": 0.1005,
"acentric_units": "-",
"alpha0": [
{
"a1": -4.0740770957,
"a2": 3.7632137341,
"type": "IdealGasHelmholtzLead"
},
{
"a": 3,
"type": "IdealGasHelmholtzLogTau"
},
{
"n": [
-0.002753352822675789
],
"t": [
-1.5
],
"type": "IdealGasHelmholtzPower"
},
{
"n": [
1.1364,
1.9721
],
"t": [
4.886089520235862,
10.62717770034843
],
"type": "IdealGasHelmholtzPlanckEinstein"
}
],
"alphar": [
{
"d": [
1,
1,
1,
2,
3,
7,
2,
5,
1,
4,
3,
4
],
"l": [
0,
0,
0,
0,
0,
0,
1,
1,
2,
2,
3,
3
],
"n": [
0.87641,
-2.0367,
0.21634,
-0.050199,
0.066994,
0.00019076,
0.20227,
-0.0045348,
-0.2223,
-0.034714,
-0.014885,
0.0074154
],
"t": [
0.25,
1.125,
1.5,
1.375,
0.25,
0.875,
0.625,
1.75,
3.625,
3.625,
14.5,
12
],
"type": "ResidualHelmholtzPower"
}
],
"gas_constant": 8.314472,
"gas_constant_units": "J/mol/K",
"molar_mass": 0.03408088,
"molar_mass_units": "kg/mol",
"p_max": 170000000,
"p_max_units": "Pa",
"pseudo_pure": false
}
],
"INFO": {
"2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=391",
"ALIASES": [
"H2S",
"HYDROGENSULFIDE"
],
"CAS": "7783-06-4",
"CHEMSPIDER_ID": 391,
"ENVIRONMENTAL": {
"ASHRAE34": "UNKNOWN",
"FH": 4,
"GWP100": -1.0,
"GWP20": -1.0,
"GWP500": -1.0,
"HH": 4,
"Name": "HydrogenSulfide",
"ODP": -1.0,
"PH": 0
},
"FORMULA": "H_{2}S_{1}",
"INCHI_KEY": "RWSOTUBLDIXVET-UHFFFAOYSA-N",
"INCHI_STRING": "InChI=1S/H2S/h1H2",
"NAME": "HydrogenSulfide",
"REFPROP_NAME": "H2S",
"SMILES": "S"
},
"STATES": {
"critical": {
"T": 373.1,
"T_units": "K",
"hmolar": 15352.955577738963,
"hmolar_units": "J/mol",
"p": 9000000.0,
"p_units": "Pa",
"rhomolar": 10190.0,
"rhomolar_units": "mol/m^3",
"smolar": 49.373749178706824,
"smolar_units": "J/mol/K"
},
"triple_liquid": {
"T": 187.7,
"T_units": "K",
"hmolar": -1720.1750502299365,
"hmolar_units": "J/mol",
"p": 23258.855838991203,
"p_units": "Pa",
"rhomolar": 29116.326840626723,
"rhomolar_units": "mol/m^3",
"smolar": -8.587703261137086,
"smolar_units": "J/mol/K"
},
"triple_vapor": {
"T": 187.7,
"T_units": "K",
"hmolar": 17876.163932083127,
"hmolar_units": "J/mol",
"p": 23258.868399596802,
"p_units": "Pa",
"rhomolar": 15.024236750641014,
"rhomolar_units": "mol/m^3",
"smolar": 95.81473758279512,
"smolar_units": "J/mol/K"
}
},
"TRANSPORT": {
"viscosity": {
"BibTeX": "QuinonesCisneros-JCED-2012",
"dilute": {
"C": 8.7721e-07,
"T_reducing": 276,
"a": [
0.53242,
0.93715,
-0.69339,
1.16432,
-0.84306,
0.20534
],
"t": [
0,
-1,
-2,
-3,
-4,
-5
],
"type": "collision_integral_powers_of_Tstar"
},
"epsilon_over_k": 355.8,
"epsilon_over_k_units": "K",
"higher_order": {
"Aa": [
6.89659e-08,
-2.20494e-08,
-4.26126e-08
],
"Aaa": [
7.8238e-13,
-6.4717e-13,
1.39066e-12
],
"Ai": [
0,
0,
0
],
"Ar": [
1.53406e-07,
8.45198e-09,
-1.13967e-07
],
"Arr": [
-9.75792e-12,
-3.19303e-12,
1.24263e-11
],
"Na": 1,
"Naa": 1,
"Nr": 1,
"Nrr": 1,
"T_reduce": 373.1,
"c1": 0,
"c2": 0,
"type": "friction_theory"
},
"initial_density": {
"b": [
-19.572881,
219.73999,
-1015.3226,
2471.01251,
-3375.1717,
2491.6597,
-787.26086,
14.085455,
-0.34664158
],
"t": [
0,
-0.25,
-0.5,
-0.75,
-1.0,
-1.25,
-1.5,
-2.5,
-5.5
],
"type": "Rainwater-Friend"
},
"sigma_eta": 3.565e-10,
"sigma_eta_units": "m"
}
}
}