mirror of
https://github.com/CoolProp/CoolProp.git
synced 2026-01-14 16:38:00 -05:00
585 lines
13 KiB
JSON
585 lines
13 KiB
JSON
{
|
|
"ANCILLARIES": {
|
|
"hL": {
|
|
"A": [
|
|
231587.64202195988,
|
|
-7064.620260354418,
|
|
79.16613042816307,
|
|
-0.47766976664107463,
|
|
0.0017192338210446272,
|
|
-3.701275690807286e-06,
|
|
4.410205058962832e-09,
|
|
-2.244329199846041e-12
|
|
],
|
|
"B": [
|
|
1,
|
|
-0.002702653004540113
|
|
],
|
|
"Tmax": 367.75,
|
|
"Tmin": 220.0,
|
|
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
|
|
"max_abs_error": 165.7888625056321,
|
|
"max_abs_error_units": "J/mol",
|
|
"type": "rational_polynomial"
|
|
},
|
|
"hLV": {
|
|
"A": [
|
|
-570120.1484197119,
|
|
15147.697959307017,
|
|
-165.61014120991328,
|
|
0.9958047945826846,
|
|
-0.0035785199472005043,
|
|
7.689873720882333e-06,
|
|
-9.151835132244599e-09,
|
|
4.656684588471939e-12
|
|
],
|
|
"B": [
|
|
1,
|
|
-0.0027000726699845175
|
|
],
|
|
"Tmax": 367.75,
|
|
"Tmin": 220.0,
|
|
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
|
|
"max_abs_error": 402.5377116316065,
|
|
"max_abs_error_units": "J/mol",
|
|
"type": "rational_polynomial"
|
|
},
|
|
"pS": {
|
|
"T_r": 367.85,
|
|
"Tmax": 367.8499999999992,
|
|
"Tmin": 220.0,
|
|
"description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
|
|
"max_abserror_percentage": 0.006853694086594864,
|
|
"n": [
|
|
0.21867168915151047,
|
|
-6.7020534970313275,
|
|
-3.9344883544124443,
|
|
39309.745547798695,
|
|
18.183182049398066,
|
|
-3883.103380695622
|
|
],
|
|
"reducing_value": 3382200.0,
|
|
"t": [
|
|
0.728,
|
|
0.961,
|
|
3.78,
|
|
17.277,
|
|
7.967,
|
|
14.02
|
|
],
|
|
"type": "pL",
|
|
"using_tau_r": true
|
|
},
|
|
"rhoL": {
|
|
"T_r": 367.85,
|
|
"Tmax": 367.8499999999992,
|
|
"Tmin": 220.0,
|
|
"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
|
|
"max_abserror_percentage": 0.3992123482188248,
|
|
"n": [
|
|
2.321825326575359,
|
|
-3.520638555089873,
|
|
20.18646332917161,
|
|
-160.37050775728997,
|
|
147.68109685289284,
|
|
-63578.64918999199
|
|
],
|
|
"reducing_value": 4170.0,
|
|
"t": [
|
|
0.365,
|
|
1.247,
|
|
1.765,
|
|
2.484,
|
|
2.593,
|
|
16.586
|
|
],
|
|
"type": "rhoLnoexp",
|
|
"using_tau_r": false
|
|
},
|
|
"rhoV": {
|
|
"T_r": 367.85,
|
|
"Tmax": 367.8499999999992,
|
|
"Tmin": 220.0,
|
|
"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
|
|
"max_abserror_percentage": 0.332050058237221,
|
|
"n": [
|
|
-3.24158284550283,
|
|
2.612924555839616,
|
|
-26.216566273272992,
|
|
115.70400813769207,
|
|
-101.3078910128961,
|
|
9.031472717572315
|
|
],
|
|
"reducing_value": 4170.0,
|
|
"t": [
|
|
0.398,
|
|
0.952,
|
|
1.466,
|
|
2.053,
|
|
2.242,
|
|
4.989
|
|
],
|
|
"type": "rhoV",
|
|
"using_tau_r": true
|
|
},
|
|
"sL": {
|
|
"A": [
|
|
421.564864740388,
|
|
-16.085256613461063,
|
|
0.19189507567966255,
|
|
-0.0011868099650075925,
|
|
4.323172584621629e-06,
|
|
-9.376997720415709e-09,
|
|
1.1235338183077166e-11,
|
|
-5.742166546136361e-15
|
|
],
|
|
"B": [
|
|
1,
|
|
-0.0027032448069045432
|
|
],
|
|
"Tmax": 367.75,
|
|
"Tmin": 220.0,
|
|
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
|
|
"max_abs_error": 0.4388358289967158,
|
|
"max_abs_error_units": "J/mol/K",
|
|
"type": "rational_polynomial"
|
|
},
|
|
"sLV": {
|
|
"A": [
|
|
-772.270169640045,
|
|
28.027619724897413,
|
|
-0.34420770911100323,
|
|
0.0021922623878138092,
|
|
-8.147733782709826e-06,
|
|
1.790015200044322e-08,
|
|
-2.1638383604766276e-11,
|
|
1.1136866702493994e-14
|
|
],
|
|
"B": [
|
|
1,
|
|
-0.0027004272124359035
|
|
],
|
|
"Tmax": 367.75,
|
|
"Tmin": 220.0,
|
|
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
|
|
"max_abs_error": 1.0811856688804422,
|
|
"max_abs_error_units": "J/mol/K",
|
|
"type": "rational_polynomial"
|
|
},
|
|
"surface_tension": {
|
|
"BibTeX": "Mulero-JPCRD-2012",
|
|
"Tc": 367.85,
|
|
"a": [
|
|
0.06274
|
|
],
|
|
"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
|
|
"n": [
|
|
1.394
|
|
]
|
|
}
|
|
},
|
|
"EOS": [
|
|
{
|
|
"BibTeX_CP0": "",
|
|
"BibTeX_EOS": "Richter-JCED-2011",
|
|
"STATES": {
|
|
"hs_anchor": {
|
|
"T": 404.63500000000005,
|
|
"T_units": "K",
|
|
"hmolar": 48232.026932563014,
|
|
"hmolar_units": "J/mol",
|
|
"p": 5661102.092360271,
|
|
"p_units": "Pa",
|
|
"rhomolar": 3753.0,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 186.35382399002881,
|
|
"smolar_units": "J/mol/K"
|
|
},
|
|
"reducing": {
|
|
"T": 367.85,
|
|
"T_units": "K",
|
|
"hmolar": 42150.06488887152,
|
|
"hmolar_units": "J/mol",
|
|
"p": 3382200,
|
|
"p_units": "Pa",
|
|
"rhomolar": 4170,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 172.07304302572015,
|
|
"smolar_units": "J/mol/K"
|
|
},
|
|
"sat_min_liquid": {
|
|
"T": 220.0,
|
|
"T_units": "K",
|
|
"hmolar": 15520.183697391298,
|
|
"hmolar_units": "J/mol",
|
|
"p": 31507.558848475514,
|
|
"p_units": "Pa",
|
|
"rhomolar": 11633.107308831428,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 84.54897749603592,
|
|
"smolar_units": "J/mol/K"
|
|
},
|
|
"sat_min_vapor": {
|
|
"T": 220.0,
|
|
"T_units": "K",
|
|
"hmolar": 37376.03203521745,
|
|
"hmolar_units": "J/mol",
|
|
"p": 31507.558848475514,
|
|
"p_units": "Pa",
|
|
"rhomolar": 17.583605761936976,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 183.89370628814143,
|
|
"smolar_units": "J/mol/K"
|
|
}
|
|
},
|
|
"T_max": 410,
|
|
"T_max_units": "K",
|
|
"Ttriple": 220,
|
|
"Ttriple_units": "K",
|
|
"acentric": 0.276,
|
|
"acentric_units": "-",
|
|
"alpha0": [
|
|
{
|
|
"a1": -12.837928,
|
|
"a2": 8.042605,
|
|
"type": "IdealGasHelmholtzLead"
|
|
},
|
|
{
|
|
"a": 4.944,
|
|
"type": "IdealGasHelmholtzLogTau"
|
|
},
|
|
{
|
|
"n": [
|
|
7.549,
|
|
1.537,
|
|
2.03,
|
|
7.455
|
|
],
|
|
"t": [
|
|
1.951882560826424,
|
|
2.384123963572108,
|
|
12.13809976892755,
|
|
4.770966426532554
|
|
],
|
|
"type": "IdealGasHelmholtzPlanckEinstein"
|
|
}
|
|
],
|
|
"alphar": [
|
|
{
|
|
"d": [
|
|
4,
|
|
1,
|
|
1,
|
|
2,
|
|
3,
|
|
1,
|
|
3,
|
|
2,
|
|
2,
|
|
7
|
|
],
|
|
"l": [
|
|
0,
|
|
0,
|
|
0,
|
|
0,
|
|
0,
|
|
2,
|
|
2,
|
|
1,
|
|
2,
|
|
1
|
|
],
|
|
"n": [
|
|
0.04592563,
|
|
1.546958,
|
|
-2.355237,
|
|
-0.4827835,
|
|
0.1758022,
|
|
-1.210006,
|
|
-0.6177084,
|
|
0.6805262,
|
|
-0.6968555,
|
|
-0.02695779
|
|
],
|
|
"t": [
|
|
1,
|
|
0.32,
|
|
0.929,
|
|
0.94,
|
|
0.38,
|
|
2.28,
|
|
1.76,
|
|
0.97,
|
|
2.44,
|
|
1.05
|
|
],
|
|
"type": "ResidualHelmholtzPower"
|
|
},
|
|
{
|
|
"beta": [
|
|
1.42,
|
|
2.31,
|
|
0.89,
|
|
80,
|
|
108
|
|
],
|
|
"d": [
|
|
1,
|
|
1,
|
|
3,
|
|
3,
|
|
2
|
|
],
|
|
"epsilon": [
|
|
0.712,
|
|
0.91,
|
|
0.677,
|
|
0.718,
|
|
1.64
|
|
],
|
|
"eta": [
|
|
1.02,
|
|
1.336,
|
|
1.055,
|
|
5.84,
|
|
16.2
|
|
],
|
|
"gamma": [
|
|
1.13,
|
|
0.67,
|
|
0.46,
|
|
1.28,
|
|
1.2
|
|
],
|
|
"n": [
|
|
1.389966,
|
|
-0.4777136,
|
|
-0.1975184,
|
|
-1.147646,
|
|
0.0003428541
|
|
],
|
|
"t": [
|
|
1.4,
|
|
3,
|
|
3.5,
|
|
1,
|
|
3.5
|
|
],
|
|
"type": "ResidualHelmholtzGaussian"
|
|
}
|
|
],
|
|
"critical_region_splines": {
|
|
"T_max": 367.85,
|
|
"T_min": 367.84983035809745,
|
|
"_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K",
|
|
"cL": [
|
|
0.0,
|
|
0.0,
|
|
-7.28092281910778e-06,
|
|
367.8803614481557
|
|
],
|
|
"cV": [
|
|
0.0,
|
|
0.0,
|
|
7.273842039048367e-06,
|
|
367.8196680786972
|
|
],
|
|
"rhomolar_max": 4193.299505682264,
|
|
"rhomolar_min": 4146.67781322612
|
|
},
|
|
"gas_constant": 8.314472,
|
|
"gas_constant_units": "J/mol/K",
|
|
"molar_mass": 0.1140415928,
|
|
"molar_mass_units": "kg/mol",
|
|
"p_max": 30000000,
|
|
"p_max_units": "Pa",
|
|
"pseudo_pure": false
|
|
}
|
|
],
|
|
"INFO": {
|
|
"2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=2057041",
|
|
"ALIASES": [
|
|
"R1234YF"
|
|
],
|
|
"CAS": "754-12-1",
|
|
"CHEMSPIDER_ID": 2057041,
|
|
"ENVIRONMENTAL": {
|
|
"ASHRAE34": "A2L",
|
|
"FH": 2,
|
|
"GWP100": 4.0,
|
|
"GWP20": -1.0,
|
|
"GWP500": -1.0,
|
|
"HH": 1,
|
|
"Name": "R1234yf",
|
|
"ODP": -1.0,
|
|
"PH": 0
|
|
},
|
|
"FORMULA": "C_{3}F_{4}H_{2}",
|
|
"INCHI_KEY": "FXRLMCRCYDHQFW-UHFFFAOYSA-N",
|
|
"INCHI_STRING": "InChI=1S/C3H2F4/c1-2(4)3(5,6)7/h1H2",
|
|
"NAME": "R1234yf",
|
|
"REFPROP_NAME": "R1234YF",
|
|
"SMILES": "C=C(C(F)(F)F)F"
|
|
},
|
|
"STATES": {
|
|
"critical": {
|
|
"T": 367.85,
|
|
"T_units": "K",
|
|
"hmolar": 42144.616087058115,
|
|
"hmolar_units": "J/mol",
|
|
"p": 3382200.0,
|
|
"p_units": "Pa",
|
|
"rhomolar": 4170.0,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 172.05987191715886,
|
|
"smolar_units": "J/mol/K"
|
|
},
|
|
"triple_liquid": {
|
|
"T": 220.0,
|
|
"T_units": "K",
|
|
"hmolar": 15520.183697391298,
|
|
"hmolar_units": "J/mol",
|
|
"p": 31507.558848475514,
|
|
"p_units": "Pa",
|
|
"rhomolar": 11633.107308831428,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 84.54897749603592,
|
|
"smolar_units": "J/mol/K"
|
|
},
|
|
"triple_vapor": {
|
|
"T": 220.0,
|
|
"T_units": "K",
|
|
"hmolar": 37376.03203521745,
|
|
"hmolar_units": "J/mol",
|
|
"p": 31507.558848475514,
|
|
"p_units": "Pa",
|
|
"rhomolar": 17.583605761936976,
|
|
"rhomolar_units": "mol/m^3",
|
|
"smolar": 183.89370628814143,
|
|
"smolar_units": "J/mol/K"
|
|
}
|
|
},
|
|
"TRANSPORT": {
|
|
"conductivity": {
|
|
"BibTeX": "Perkins-JCED-2011",
|
|
"critical": {
|
|
"GAMMA": 0.0496,
|
|
"R0": 1.03,
|
|
"gamma": 1.239,
|
|
"qD": 1713796058.2,
|
|
"type": "simplified_Olchowy_Sengers",
|
|
"zeta0": 1.94e-10
|
|
},
|
|
"dilute": {
|
|
"A": [
|
|
-0.0102778,
|
|
0.0291098,
|
|
0.000860643
|
|
],
|
|
"B": [
|
|
1.0
|
|
],
|
|
"T_reducing": 367.85,
|
|
"T_reducing_units": "K",
|
|
"m": [
|
|
0
|
|
],
|
|
"n": [
|
|
0,
|
|
1,
|
|
2
|
|
],
|
|
"type": "ratio_of_polynomials"
|
|
},
|
|
"residual": {
|
|
"B": [
|
|
-0.0368219,
|
|
0.0883226,
|
|
-0.0705909,
|
|
0.0259026,
|
|
-0.0032295,
|
|
0.0397166,
|
|
-0.077239,
|
|
0.0664707,
|
|
-0.0249071,
|
|
0.00336228
|
|
],
|
|
"T_reducing": 367.85,
|
|
"T_reducing_units": "K",
|
|
"d": [
|
|
1,
|
|
2,
|
|
3,
|
|
4,
|
|
5,
|
|
1,
|
|
2,
|
|
3,
|
|
4,
|
|
5
|
|
],
|
|
"rhomass_reducing": 475.55,
|
|
"rhomass_reducing_units": "kg/m^3",
|
|
"t": [
|
|
0,
|
|
0,
|
|
0,
|
|
0,
|
|
0,
|
|
-1,
|
|
-1,
|
|
-1,
|
|
-1,
|
|
-1
|
|
],
|
|
"type": "polynomial"
|
|
}
|
|
},
|
|
"viscosity": [
|
|
{
|
|
"BibTeX": "Bell-PURDUE-2016-ETA",
|
|
"C": 0.87302,
|
|
"c_liq": [
|
|
0.6100913843,
|
|
0.4508958312,
|
|
-0.017063,
|
|
0.000564
|
|
],
|
|
"c_vap": [
|
|
0.0,
|
|
1.2,
|
|
-0.308598,
|
|
0.035317
|
|
],
|
|
"rhosr_critical": -54468.47741433059,
|
|
"type": "rhosr-CS",
|
|
"x_crossover": 2
|
|
},
|
|
{
|
|
"BibTeX": "BELL-PERSONAL-2015",
|
|
"_note": "Fit based on the data of Zhao, JCED, 2014: doi: 10.1021/je5001457",
|
|
"epsilon_over_k": 281.14,
|
|
"epsilon_over_k_units": "K",
|
|
"psi": {
|
|
"a": [
|
|
0.17682139,
|
|
0.74500256,
|
|
-0.16912621
|
|
],
|
|
"rhomolar_reducing": 4170.0,
|
|
"rhomolar_reducing_units": "mol/m^3",
|
|
"t": [
|
|
0,
|
|
1,
|
|
2
|
|
]
|
|
},
|
|
"reference_fluid": "R134a",
|
|
"sigma_eta": 5.328e-10,
|
|
"sigma_eta_units": "m",
|
|
"type": "ECS"
|
|
}
|
|
]
|
|
}
|
|
} |