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a72baafc77
* Add fluid files with superancillary data * Delete the large generated z-compressed header
4766 lines
143 KiB
JSON
4766 lines
143 KiB
JSON
{
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"ANCILLARIES": {
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"hL": {
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"A": [
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-78528.42581794098,
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241.74029024533226,
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-0.24915312827909075,
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0.0006704587769436075,
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-3.3425931745093963e-06,
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1.0726098413722431e-08,
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-1.734165916803351e-11,
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1.0253093528655403e-14
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],
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"B": [
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1,
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-0.0019192498924755234
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],
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"Tmax": 514.61,
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"Tmin": 159.10000000000002,
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 253.0918978591635,
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"max_abs_error_units": "J/mol",
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"type": "rational_polynomial"
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},
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"hLV": {
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"A": [
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51357.68589743386,
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-79.15383458692652,
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-0.4794460040867968,
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0.0021455323836419584,
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-2.5360622479546228e-06,
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-5.683528592262342e-09,
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1.677674923773602e-11,
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-1.0948757631874753e-14
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],
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"B": [
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1,
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-0.0019256056788626934
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],
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"Tmax": 514.61,
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"Tmin": 159.10000000000002,
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 447.8436475123028,
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"max_abs_error_units": "J/mol",
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"type": "rational_polynomial"
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},
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"melting_line": {
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"BibTeX": "Sun-BBPC-1988",
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"T_m": 158.8,
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"_note": "Modified coefficients to make minimum state agree with triple point",
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"parts": [
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{
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"T_0": 158.37,
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"T_max": 10000,
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"T_min": 158.37,
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"a": 436900000.0,
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"c": 2.6432,
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"p_0": 0.0007350470774722485
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}
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],
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"type": "Simon"
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},
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"pS": {
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"T_r": 514.71,
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"Tmax": 514.7099999999989,
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"Tmin": 159.1,
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"description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
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"max_abserror_percentage": 0.033827061431446204,
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"n": [
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-7.689152382102059,
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6.6239961045380715,
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-7.827481023390803,
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3.1386332149218172,
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-6.712235308208619
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],
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"reducing_value": 6268000.0,
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"t": [
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0.971,
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2.322,
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3.072,
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3.934,
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4.465,
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19.972
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],
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"type": "pL",
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"using_tau_r": true
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},
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"rhoL": {
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"T_r": 514.71,
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"Tmax": 514.7099999999989,
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"Tmin": 159.1,
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"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
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"max_abserror_percentage": 0.7371174097769773,
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"n": [
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7.824518623386008,
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-338.93732001583646,
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368.3422016038343,
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-90.14206962630433,
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80.35347134933373,
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-26.00710239571597
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],
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"reducing_value": 5930.0,
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"t": [
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0.596,
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1.495,
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1.561,
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2.737,
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3.606,
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4.943
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],
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"type": "rhoLnoexp",
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"using_tau_r": false
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},
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"rhoV": {
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"T_r": 514.71,
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"Tmax": 514.7099999999989,
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"Tmin": 159.1,
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"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
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"max_abserror_percentage": 6.337867778240303,
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"n": [
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-4.698337259111072,
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-10.953380258011986,
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12.92351305172882,
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-1017.0017776259273,
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1604.552160868234,
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-1439.9265562459323
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],
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"reducing_value": 5930.0,
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"t": [
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0.443,
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2.304,
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4.146,
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11.027,
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12.113,
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17.485
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],
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"type": "rhoV",
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"using_tau_r": true
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},
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"sL": {
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"A": [
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-323.5986202184598,
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2.1858528149760836,
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-0.00860017240111237,
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2.3595406210866773e-05,
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-4.025357789948479e-08,
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4.1095280268612255e-11,
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-2.631210716080906e-14,
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9.31615991118147e-18
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],
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"B": [
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1,
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-0.0019214952835844615
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],
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"Tmax": 514.61,
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"Tmin": 159.10000000000002,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 0.4507619556283693,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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},
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"sLV": {
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"A": [
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1359.073842024734,
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-17.68749614670452,
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0.11717583766893273,
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-0.00047257148253925657,
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1.1974398203676172e-06,
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-1.868778464772557e-09,
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1.6449065289944747e-12,
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-6.244931899106718e-16
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],
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"B": [
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1,
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-0.0019177068751613513
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],
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"Tmax": 514.61,
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"Tmin": 159.10000000000002,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 1.7238877516035611,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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},
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"surface_tension": {
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"BibTeX": "Mulero-JPCRD-2012",
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"Tc": 513.9,
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"a": [
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0.05
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],
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"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
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"n": [
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0.952
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]
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}
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},
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"EOS": [
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{
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"BibTeX_CP0": "",
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"BibTeX_EOS": "Schroeder-JPCRD-2014",
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"STATES": {
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"hs_anchor": {
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"T": 566.181,
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"T_units": "K",
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"hmolar": 44873.309545025724,
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"hmolar_units": "J/mol",
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"p": 11475786.665305058,
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"p_units": "Pa",
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"rhomolar": 5337.0,
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"rhomolar_units": "mol/m^3",
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"smolar": 94.07877545514242,
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"smolar_units": "J/mol/K"
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},
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"reducing": {
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"T": 514.71,
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"T_units": "K",
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"hmolar": 34962.29457297125,
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"hmolar_units": "J/mol",
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"p": 6268000,
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"p_units": "Pa",
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"rhomolar": 5930,
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"smolar": 77.42274717172617,
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"smolar_units": "J/mol/K"
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},
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"sat_min_liquid": {
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"T": 159.10000000000002,
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"T_units": "K",
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"hmolar": -19858.228464275544,
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"hmolar_units": "J/mol",
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"p": 0.0007353928225172699,
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"p_units": "Pa",
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"rhomolar": 19729.112579315857,
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"smolar": -79.40115445686752,
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"smolar_units": "J/mol/K"
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},
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"sat_min_vapor": {
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"T": 159.10000000000002,
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"T_units": "K",
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"hmolar": 28149.405903876126,
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"hmolar_units": "J/mol",
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"p": 0.0007350470774722485,
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"p_units": "Pa",
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"rhomolar": 5.556614984608756e-07,
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"rhomolar_units": "mol/m^3",
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"smolar": 222.34387614119467,
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"smolar_units": "J/mol/K"
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}
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},
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"T_max": 650,
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"T_max_units": "K",
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"Ttriple": 159.0,
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"Ttriple_units": "K",
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"acentric": 0.644,
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"acentric_units": "-",
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"alpha0": [
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{
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"a1": -12.7531,
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"a2": 9.39094,
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"type": "IdealGasHelmholtzLead"
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},
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{
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"a": 3.43069,
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"type": "IdealGasHelmholtzLogTau"
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},
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{
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"n": [
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2.14326,
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5.09206,
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6.60138,
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5.70777
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],
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"t": [
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0.816771,
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2.59175,
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3.80408,
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8.58736
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],
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"type": "IdealGasHelmholtzPlanckEinstein"
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},
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{
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"a1": 9.10869959576363,
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"a2": -4.32013218872146,
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"reference": "NBP",
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"type": "IdealGasHelmholtzEnthalpyEntropyOffset"
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}
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],
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"alphar": [
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{
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"d": [
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4,
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1,
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1,
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2,
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2,
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3,
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1,
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1,
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1,
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3,
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3,
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2,
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2,
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6,
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6,
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8
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],
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"l": [
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0,
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0,
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0,
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0,
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1,
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1,
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1,
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1,
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2,
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1,
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1,
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1
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],
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"n": [
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0.55359038,
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0.21055146,
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"t": [
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1,
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1.174,
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2.5,
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0.86
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],
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"type": "ResidualHelmholtzPower"
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},
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{
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"beta": [
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1.207,
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0.0895,
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0.581,
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0.947,
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2.356,
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27.01,
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4.542,
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1.287,
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3.09
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"d": [
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1,
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1,
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2,
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3,
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3,
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2,
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2,
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2,
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1
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],
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"epsilon": [
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0.779,
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0.805,
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1.869,
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0.694,
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1.312,
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2.054,
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0.441,
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0.793,
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0.313
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],
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"eta": [
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1.075,
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0.463,
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0.876,
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1.108,
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0.741,
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4.032,
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2.453,
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2.3,
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3.143
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],
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"gamma": [
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1.194,
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1.986,
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1.583,
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0.756,
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0.495,
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1.002,
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1.077,
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1.493,
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1.542
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],
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"n": [
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0.75564749,
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0.1069411,
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0.027177891,
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-0.12310953,
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-0.08977971,
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],
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"t": [
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2.5,
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3.72,
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1.19,
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3.25,
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3,
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2,
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2,
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1,
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1
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],
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"type": "ResidualHelmholtzGaussian"
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}
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],
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"critical_region_splines": {
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"T_max": 514.71,
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"T_min": 514.622869613147,
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"_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K",
|
|
"cL": [
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-4.321404777621795e-11,
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|
-1.7076779247457985e-07,
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|
0.006584159024686301,
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490.68230210427
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],
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"cV": [
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-2.864544233706444e-10,
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|
4.144580667152323e-06,
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-0.01893530325526736,
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540.986310635042
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],
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"rhomolar_max": 6232.430871796149,
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"rhomolar_min": 5611.7525953516915
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},
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"gas_constant": 8.314472,
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"gas_constant_units": "J/mol/K",
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"molar_mass": 0.04606844,
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"molar_mass_units": "kg/mol",
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|
"p_max": 280000000,
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"p_max_units": "Pa",
|
|
"pseudo_pure": false,
|
|
"SUPERANCILLARY": {
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"crit_anc": {
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|
"Tc / K": 514.7092848812961,
|
|
"Theta_min": 0.01,
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|
"_note": "coefficients are for the function like ln(|rho^A-rhoc|) = sum_i c_i ln(Theta)^i with Theta=(Tc-T)/Tc",
|
|
"cL": [
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10.611490901662444,
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0.6505984355078613,
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0.011283743228741127,
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-0.0005887559311649563,
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-0.00011511332542889521,
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-5.251058957636204e-06,
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|
-7.928311853500369e-08
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],
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"cV": [
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2.425586481920172,
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-0.006546983939880749,
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|
-0.00019280325844015748,
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|
-2.270631675536073e-06
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|
],
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|
"rhoc / mol/m^3": 5930.686348978992
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|
},
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|
"jexpansions_p": [
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{
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"coef": [
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0.0034379152311620215,
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0.003484800418840742,
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0.0009206502273483959,
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0.0001556535674408284,
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1.8466808220432585e-05,
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|
1.6116853576818781e-06,
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1.0581674469090042e-07,
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|
5.244727598651531e-09,
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1.9265058445564988e-10,
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4.940318073580381e-12,
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7.244785847306277e-14,
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-8.530524056880923e-17,
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|
-2.782333825140926e-17
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|
],
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"xmax": 170.36440489093073,
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"xmin": 159.10000000000002
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},
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{
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"coef": [
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0.0119189107498517,
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0.004238273999873663,
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0.000356535448255936,
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1.861671772106565e-05,
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6.709373624343763e-07,
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1.7556377717025738e-08,
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3.408627692520797e-10,
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|
4.9051171843344565e-12,
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|
5.0731697978140266e-14,
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"t2": [
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0
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|
],
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"type": "modified_Batschinski_Hildebrand"
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},
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"initial_density": {
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"b": [
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-19.572881,
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219.73999,
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2471.01251,
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-3375.1717,
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2491.6597,
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14.085455,
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-0.34664158
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],
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"t": [
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0,
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],
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"type": "Rainwater-Friend"
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},
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"sigma_eta": 4.53e-10,
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"sigma_eta_units": "m"
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}
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}
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} |