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a72baafc77
* Add fluid files with superancillary data * Delete the large generated z-compressed header
4329 lines
133 KiB
JSON
4329 lines
133 KiB
JSON
{
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"ANCILLARIES": {
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"hL": {
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"A": [
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-44208.06787744796,
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83.11502451831647,
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2.2034724058299564,
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],
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"Tmax": 375.15,
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"Tmin": 130.0,
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 213.2189938015199,
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"max_abs_error_units": "J/mol",
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"type": "rational_polynomial"
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297.8019527583096,
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5.500283412737703e-07,
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4.070956348787284e-13
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 522.4684359010557,
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"type": "rational_polynomial"
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},
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"pS": {
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"T_r": 375.25,
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"Tmax": 375.2499999999994,
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"Tmin": 130.0,
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"description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
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"t": [
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0.358,
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0.979,
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2.041,
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2.312,
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7.268,
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8.389
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"type": "pL",
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"using_tau_r": true
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"rhoL": {
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"T_r": 375.25,
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"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
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183.43884409350315,
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3.341,
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6.576,
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6.669
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"type": "rhoLnoexp",
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},
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"rhoV": {
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"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
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0.148,
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0.482,
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0.891,
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2.774,
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4.26,
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6.784
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],
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"type": "rhoV",
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2.588633871448754e-10,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 0.5810079887806072,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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0.1665441887853578,
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5.773068263475169e-12,
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1,
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"Tmax": 375.15,
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"Tmin": 130.0,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 1.6327486011842343,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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},
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"surface_tension": {
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"BibTeX": "Mulero-JPCRD-2012",
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"Tc": 375.3,
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"a": [
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0.05385
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],
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"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
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"n": [
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1.111
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]
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}
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},
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"EOS": [
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{
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"BibTeX_CP0": "",
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"BibTeX_EOS": "Wu-IJT-2012",
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"STATES": {
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"hs_anchor": {
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"T": 412.77500000000003,
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"T_units": "K",
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"hmolar": 29437.268109986722,
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"p": 8287479.703515427,
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},
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"reducing": {
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"T": 375.25,
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"hmolar_units": "J/mol",
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"p": 5010000,
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"p_units": "Pa",
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"smolar_units": "J/mol/K"
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},
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"sat_min_liquid": {
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"T": 130.0,
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"T_units": "K",
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"smolar_units": "J/mol/K"
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},
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"sat_min_vapor": {
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"T": 130.0,
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"T_units": "K",
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"hmolar": 21714.078443451966,
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"p": 5.512269644056271,
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}
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},
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"T_max": 450,
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"Ttriple": 130,
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"Ttriple_units": "K",
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"acentric": 0.2162428410661867,
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"acentric_units": "-",
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"alpha0": [
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{
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"a1": -6.9187,
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"type": "IdealGasHelmholtzLead"
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{
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"a": 3,
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{
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"n": [
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2.059,
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9.253,
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6.088
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],
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"t": [
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1.11925383077948,
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4.125249833444371,
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10.34510326449034
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],
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"type": "IdealGasHelmholtzPlanckEinstein"
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},
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{
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"a1": 4.21805657510139e-05,
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"a2": -4.5424171382829e-06,
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"reference": "IIR",
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"type": "IdealGasHelmholtzEnthalpyEntropyOffset"
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}
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"alphar": [
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{
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"d": [
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1,
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1,
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2,
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3,
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4,
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2,
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7,
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1,
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2,
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3
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],
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"l": [
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0,
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0,
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0,
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0,
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0,
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1,
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1,
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2,
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2,
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2
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],
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"n": [
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1.511,
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0.1683,
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0.04133,
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0.62187,
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],
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"t": [
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0.37,
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0.97,
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1.14,
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0.744,
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1,
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1.26,
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1,
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1.8,
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3,
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2.25
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],
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"type": "ResidualHelmholtzPower"
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},
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{
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"beta": [
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2.7,
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5.2,
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3.9,
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4.7,
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413
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],
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"d": [
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1,
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1,
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3,
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3,
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3
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],
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"epsilon": [
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0.683,
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0.892,
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0.785,
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1.33,
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0.86
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],
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"eta": [
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0.96,
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1.35,
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1.26,
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1.23,
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16.8
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],
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"gamma": [
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0.9,
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0.69,
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0.67,
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0.67,
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1.15
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],
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"n": [
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0.82,
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],
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1,
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1.2,
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5.3,
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1,
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4
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"type": "ResidualHelmholtzGaussian"
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}
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"critical_region_splines": {
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"T_max": 375.25,
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"T_min": 375.2498876027567,
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"_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K",
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"cL": [
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0.0,
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0.0,
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-1.0274211653082636e-06,
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375.25645220491816
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],
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"cV": [
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0.0,
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0.0,
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6.800670480519312e-07,
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375.24572917893823
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"rhomolar_max": 6389.397438091061,
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"rhomolar_min": 6114.726232371929
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"gas_constant": 8.314472,
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"molar_mass": 0.0480595,
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"molar_mass_units": "kg/mol",
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"p_max": 5000000,
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"p_max_units": "Pa",
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"pseudo_pure": false,
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"SUPERANCILLARY": {
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"crit_anc": {
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"Tc / K": 375.24999890354485,
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"Theta_min": 0.01,
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"_note": "coefficients are for the function like ln(|rho^A-rhoc|) = sum_i c_i ln(Theta)^i with Theta=(Tc-T)/Tc",
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"cL": [
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7.914947334152314,
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-0.5565831350073962,
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-0.2027241618002835,
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-0.02258898231103376,
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-0.0012516121931142364,
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-3.276950281329413e-05,
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-3.231028009852363e-07
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],
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"cV": [
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6.069982127126412,
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-1.3774534661194944,
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-0.327565386442435,
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-0.0010401956565664287,
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-6.652425317935133e-06,
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2.3837764037461457e-07
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],
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"rhoc / mol/m^3": 6282.85772002901
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},
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{
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16.128356783410016,
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12.782294733973021,
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2.4201558764218216,
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0.2727583148881163,
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0.01969612373112176,
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0.0009103920046163704,
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2.4181188387458788e-05,
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1.646579121927087e-05,
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2.06196259012333e-06,
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2.5752555631723234e-07,
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3.339195598502547e-08,
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1.5952224312313867e-08,
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2.034028057096293e-09
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1.1771052883634543,
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0.24928549905400624,
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"meta": {
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"BrhoV / mol/m^3": -39779.186200663404,
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"Tcrit / K": 375.25,
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"Tcrittrue / K": 375.24999890354485,
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"Treducing / K": 375.25,
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}
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}
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}
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],
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"INFO": {
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"2DPNG_URL": "http://www.chemspider.com/ImagesHandler.ashx?id=9243",
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"ALIASES": [
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"Fluoroethane",
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"FLUOROETHANE"
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],
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"CAS": "353-36-6",
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"CHEMSPIDER_ID": 9243,
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"ENVIRONMENTAL": {
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"ASHRAE34": "UNKNOWN",
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"FH": -1,
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"GWP100": 10.0,
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"GWP20": -1.0,
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"GWP500": -1.0,
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"HH": -1,
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"Name": "R161",
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"ODP": -1.0,
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"PH": -1
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},
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"FORMULA": "C_{2}F_{1}H_{5}",
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"INCHI_KEY": "UHCBBWUQDAVSMS-UHFFFAOYSA-N",
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"INCHI_STRING": "InChI=1S/C2H5F/c1-2-3/h2H2,1H3",
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"NAME": "R161",
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"REFPROP_NAME": "R161",
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"SMILES": "CCF"
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|
},
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"STATES": {
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"critical": {
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"T": 375.25,
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"T_units": "K",
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"hmolar": 24704.381939700208,
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"p": 5010000.0,
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},
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"triple_liquid": {
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|
"T": 130.0,
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|
"T_units": "K",
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|
"hmolar": -4191.215377162371,
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"hmolar_units": "J/mol",
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"p": 5.512269644056271,
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"smolar_units": "J/mol/K"
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},
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"triple_vapor": {
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|
"T": 130.0,
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|
"T_units": "K",
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|
"hmolar": 21714.078443451966,
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"hmolar_units": "J/mol",
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"p": 5.512269644056271,
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"p_units": "Pa",
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"rhomolar": 0.005099846396055564,
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"rhomolar_units": "mol/m^3",
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"smolar_units": "J/mol/K"
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}
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}
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} |