Files
CoolProp/dev/fluids/CarbonDioxide.json
Ian Bell 24d37e0e6d Added h and s to hs_anchor state
Signed-off-by: Ian Bell <ian.h.bell@gmail.com>
2014-08-01 10:09:12 +02:00

773 lines
17 KiB
JSON

{
"ALIASES": [
"R744",
"co2",
"CO2",
"carbondioxide",
"CARBONDIOXIDE"
],
"ANCILLARIES": {
"hL": {
"A": [
2190971.5434333943,
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740.4463385275005,
-4.905899661649806,
0.019465449319376556,
-4.62736487768224e-05,
6.103354592333616e-08,
-3.446311295467467e-11
],
"B": [
1,
-0.003270600659424993
],
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
"max_abs_error": 72.6960604727883,
"max_abs_error_units": "J/mol",
"type": "rational_polynomial"
},
"hLV": {
"A": [
-5415181.173011534,
151806.8291500119,
-1815.2125799184716,
12.0318458991438,
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0.00011367971674015324,
-1.5007876164912808e-07,
8.4823767851834e-11
],
"B": [
1,
-0.003270052391971672
],
"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
"max_abs_error": 173.64280477521038,
"max_abs_error_units": "J/mol",
"type": "rational_polynomial"
},
"melting_line": {
"BibTeX": "Span-JPCRD-1996",
"T_m": 216.58,
"parts": [
{
"T_0": 216.592,
"T_max": 327.6,
"T_min": 216.592,
"a": [
1955.539,
2055.4593
],
"p_0": 517950,
"t": [
1,
2
]
}
],
"type": "polynomial_in_Theta"
},
"pL": {
"T_r": 304.1282,
"Tmax": 304.1281999999994,
"Tmin": 216.592,
"description": "p' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.0010595686337877552,
"n": [
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-7.10969550015274,
11.022781986239263,
4.8260764050219995,
-6.240803382557819,
-6.7009642572439
],
"reducing_value": 7377300.0,
"t": [
0.983,
1.322,
1.488,
2.807,
3.571,
1.941
],
"type": "pL",
"using_tau_r": true
},
"pV": {
"T_r": 304.1282,
"Tmax": 304.1281999999994,
"Tmin": 216.592,
"description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.0017511543346171443,
"n": [
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-16.600500683315147,
11.947155561272234,
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-2.3639949455719274,
-3.6534929025030847
],
"reducing_value": 7377300.0,
"t": [
0.917,
1.078,
1.146,
1.669,
3.238,
6.0
],
"type": "pV",
"using_tau_r": true
},
"rhoL": {
"T_r": 304.1282,
"Tmax": 304.1281999999994,
"Tmin": 216.592,
"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.044231974273145624,
"n": [
0.861951794789174,
5.535795098719573,
-21.766373764605415,
20.01416999278327,
-2.2218647220786862,
888.2387848519858
],
"reducing_value": 10624.906299999999,
"t": [
0.264,
0.672,
0.986,
1.092,
1.714,
9.902
],
"type": "rhoLnoexp",
"using_tau_r": false
},
"rhoV": {
"T_r": 304.1282,
"Tmax": 304.1281999999994,
"Tmin": 216.592,
"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
"max_abserror_percentage": 0.035329219540658485,
"n": [
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-3.64216164754343,
2.7773118075713237,
-3.2573848494624533,
-1.9739104682508852,
-16.057319994659142
],
"reducing_value": 10624.906299999999,
"t": [
0.306,
0.569,
0.677,
0.891,
3.206,
6.093
],
"type": "rhoV",
"using_tau_r": true
},
"sL": {
"A": [
6819.330059892228,
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2.337328791274407,
-0.015525220005143957,
6.168240255002822e-05,
-1.467364275848974e-07,
1.9360604893668228e-10,
-1.0932729404515549e-13
],
"B": [
1,
-0.0032708741683960658
],
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
"max_abs_error": 0.2359299027881363,
"max_abs_error_units": "J/mol/K",
"type": "rational_polynomial"
},
"sLV": {
"A": [
-16486.001178394985,
468.71269097628135,
-5.6468119578588185,
0.03758891519125143,
-0.00014965588399287633,
3.5669408607948615e-07,
-4.714517308435282e-10,
2.6666296892023113e-13
],
"B": [
1,
-0.0032703357514888847
],
"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
"max_abs_error": 0.5636487563435457,
"max_abs_error_units": "J/mol/K",
"type": "rational_polynomial"
},
"surface_tension": {
"BibTeX": "Mulero-JPCRD-2012",
"Tc": 304.128,
"a": [
0.07863
],
"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
"n": [
1.254
]
}
},
"CAS": "124-38-9",
"ENVIRONMENTAL": {
"ASHRAE34": "A1",
"FH": 0,
"GWP100": 1.0,
"GWP20": 1.0,
"GWP500": 1.0,
"HH": 1,
"Name": "CarbonDioxide",
"ODP": -1.0,
"PH": 0
},
"EOS": [
{
"BibTeX_CP0": "",
"BibTeX_EOS": "Span-JPCRD-1996",
"STATES": {
"hs_anchor": {
"T": 334.54102,
"T_units": "K",
"hmolar": 17160.82410570731,
"hmolar_units": "J/mol",
"p": 12034846.936049895,
"p_units": "Pa",
"rhomolar": 9562.41567,
"rhomolar_units": "mol/m^3",
"smolar": 69.6226553395358,
"smolar_units": "J/mol/K"
},
"reducing": {
"T": 304.1282,
"T_units": "K",
"p": 7377300,
"p_units": "Pa",
"rhomolar": 10624.9063,
"rhomolar_units": "mol/m^3"
},
"sat_min_liquid": {
"T": 216.592,
"T_units": "K",
"p": 517.9643433349185,
"p_units": "Pa",
"rhomolar": 26777.277860212125,
"rhomolar_units": "mol/m^3"
},
"sat_min_vapor": {
"T": 216.592,
"T_units": "K",
"p": 517.9643433349185,
"p_units": "Pa",
"rhomolar": 312.6777446892703,
"rhomolar_units": "mol/m^3"
}
},
"T_max": 1100,
"T_max_units": "K",
"Ttriple": 216.592,
"Ttriple_units": "K",
"accentric": 0.22394,
"accentric_units": "-",
"alpha0": [
{
"a1": 8.37304456,
"a2": -3.70454304,
"type": "IdealGasHelmholtzLead"
},
{
"a": 2.5,
"type": "IdealGasHelmholtzLogTau"
},
{
"n": [
1.99427042,
0.62105248,
0.41195293,
1.04028922,
0.08327678
],
"t": [
3.15163,
6.1119,
6.77708,
11.32384,
27.08792
],
"type": "IdealGasHelmholtzPlanckEinstein"
},
{
"a1": -14.4979156224319,
"a2": 8.82013935801453,
"reference": "IIR",
"type": "IdealGasHelmholtzEnthalpyEntropyOffset"
}
],
"alphar": [
{
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1,
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1,
2,
4,
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7,
8,
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"n": [
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"type": "ResidualHelmholtzPower"
},
{
"beta": [
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275,
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],
"d": [
2,
2,
2,
3,
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],
"epsilon": [
1,
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1,
1
],
"eta": [
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25,
25,
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20
],
"gamma": [
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1.25,
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],
"type": "ResidualHelmholtzGaussian"
},
{
"A": [
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0.3,
0.3,
1
],
"C": [
10,
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"D": [
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"a": [
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"b": [
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}
],
"gas_constant": 8.31451,
"gas_constant_units": "J/mol/K",
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"molar_mass_units": "kg/mol",
"p_max": 800000000,
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"pseudo_pure": false
}
],
"NAME": "CarbonDioxide",
"REFPROP_NAME": "CO2",
"STATES": {
"critical": {
"T": 304.1282,
"T_units": "K",
"p": 7377300.0,
"p_units": "Pa",
"rhomolar": 10624.906299999999,
"rhomolar_units": "mol/m^3"
},
"triple_liquid": {
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"T_units": "K",
"p": 517.9643433349185,
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"rhomolar_units": "mol/m^3"
},
"triple_vapor": {
"T": 216.592,
"T_units": "K",
"p": 517.9643433349185,
"p_units": "Pa",
"rhomolar": 312.6777446892703,
"rhomolar_units": "mol/m^3"
}
},
"TRANSPORT": {
"conductivity": {
"BibTeX": "Scalabrin-JPCRD-2006-CO2",
"critical": {
"hardcoded": "CarbonDioxideScalabrinJPCRD2006"
},
"dilute": {
"hardcoded": "none"
},
"residual": {
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0.0007696647124242399,
0.0075538113451464,
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0.078894098855904,
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2.0846013855224798e-05
],
"T_reducing": 304.1282,
"T_reducing_units": "K",
"d": [
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5.0,
1.0,
1.0,
2.0,
0.0,
5.0,
9.0,
0.0,
0.0
],
"gamma": [
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],
"l": [
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],
"rhomass_reducing": 467.6,
"rhomass_reducing_units": "kg/m^3",
"t": [
0.0,
0.0,
-1.5,
0.0,
-1.0,
-1.5,
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-1.5,
-3.5,
-5.5
],
"type": "polynomial_and_exponential"
}
},
"viscosity": {
"BibTeX": "Fenghour-JPCRD-1998",
"_note": "sigma set to 1 nm in since sigma wrapped into constant in equation in Fenghour",
"dilute": {
"C": 1.5178953643112785e-07,
"_note": "Leading coefficient was back calculated from 1.00697e-6/(44.0098)**0.5 (using sigma = 1 nm)",
"a": [
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],
"molar_mass": 0.0440098,
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"t": [
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],
"type": "collision_integral"
},
"epsilon_over_k": 251.196,
"epsilon_over_k_units": "K",
"higher_order": {
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"_note": "All of the coefficients for higher order viscosity contribution were converted to be in terms of delta and tau",
"a": [
1.9036541208525784e-06,
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6.79058431241662e-08,
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],
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],
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"rhomolar_reduce": 10624.9,
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"t1": [
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],
"type": "modified_Batschinski_Hildebrand"
},
"sigma_eta": 1e-09,
"sigma_eta_units": "m"
}
}
}