Conductivity for Ethanol, SF6, Toluene and Heptane

Signed-off-by: Ian Bell <ian.h.bell@gmail.com>
This commit is contained in:
Ian Bell
2014-05-23 20:05:24 +02:00
parent 3c8eb8746b
commit 7d542997b1
5 changed files with 361 additions and 2 deletions

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@@ -351,6 +351,88 @@
],
"NAME": "Ethanol",
"TRANSPORT": {
"conductivity": {
"BibTeX": "Assael-JPCRD-2013-Ethanol",
"critical": {
"GAMMA": 0.05885,
"type": "simplified_Olchowy_Sengers",
"zeta0": 1.64296e-10
},
"dilute": {
"A": [
-0.00209575,
0.0199045,
-0.053964,
0.0821223,
-0.00198864,
-0.000495513
],
"B": [
0.17223,
-0.078273,
1
],
"T_reducing": 514.71,
"T_reducing_units": "K",
"m": [
0,
1,
2
],
"n": [
0,
1,
2,
3,
4,
5
],
"type": "ratio_of_polynomials"
},
"residual": {
"B": [
0.0267222,
0.0177166,
0.148279,
-0.0893088,
-0.130429,
0.0684664,
0.0346232,
-0.0145702,
-0.00244293,
0.000809189
],
"T_reducing": 514.71,
"T_reducing_units": "K",
"d": [
1,
1,
2,
2,
3,
3,
4,
4,
5,
5
],
"rhomass_reducing": 273.186,
"rhomass_reducing_units": "kg/m^3",
"t": [
0,
-1,
0,
-1,
0,
-1,
0,
-1,
0,
-1
],
"type": "polynomial"
}
},
"viscosity": {
"BibTeX": "Kiselev-IECR-2005",
"dilute": {

View File

@@ -409,6 +409,84 @@
],
"NAME": "SulfurHexafluoride",
"TRANSPORT": {
"conductivity": {
"BibTeX": "Assael-JPCRD-2012-SF6",
"critical": {
"GAMMA": 0.052,
"type": "simplified_Olchowy_Sengers",
"zeta0": 1.9e-10
},
"dilute": {
"A": [
1461.86,
-18.5394,
0.0777891,
2.41059e-05
],
"B": [
29661.7,
505.67,
1
],
"T_reducing": 1,
"T_reducing_units": "K",
"m": [
0,
1,
2
],
"n": [
0,
1,
2,
3
],
"type": "ratio_of_polynomials"
},
"residual": {
"B": [
-0.0283746,
0.0352768,
0.0207472,
-0.0433053,
-0.0055718,
0.0512084,
0.0053289,
-0.0290262,
-0.00161688,
0.00598438
],
"T_reducing": 318.7232,
"T_reducing_units": "K",
"d": [
1,
1,
2,
2,
3,
3,
4,
4,
5,
5
],
"rhomass_reducing": 742.297,
"rhomass_reducing_units": "kg/m^3",
"t": [
0,
-1,
0,
-1,
0,
-1,
0,
-1,
0,
-1
],
"type": "polynomial"
}
},
"viscosity": {
"BibTeX": "QuinonesCisneros-JPCRD-2012",
"dilute": {

View File

@@ -254,5 +254,91 @@
"rhoVtriple_units": "mol/m^3"
}
],
"NAME": "Toluene"
"NAME": "Toluene",
"TRANSPORT": {
"conductivity": {
"BibTeX": "Assael-JPCRD-2012-Toluene",
"critical": {
"GAMMA": 0.05,
"type": "simplified_Olchowy_Sengers",
"zeta0": 2.2e-10
},
"dilute": {
"A": [
0.0058808,
-6.1693e-05,
3.4151e-07,
-3.042e-10,
1.2868e-13,
-2.1303e-17
],
"B": [
1
],
"T_reducing": 1,
"T_reducing_units": "K",
"m": [
0
],
"n": [
0,
1,
2,
3,
4,
5
],
"type": "ratio_of_polynomials"
},
"residual": {
"B": [
-0.051853,
0.0517449,
0.133846,
-0.121902,
-0.120446,
0.137748,
0.0530211,
-0.0732792,
-0.0100604,
0.0172914,
0.000633457,
-0.00138585
],
"T_reducing": 591.75,
"T_reducing_units": "K",
"d": [
1,
1,
2,
2,
3,
3,
4,
4,
5,
5,
6,
6
],
"rhomass_reducing": 291.992,
"rhomass_reducing_units": "kg/m^3",
"t": [
0,
-1,
0,
-1,
0,
-1,
0,
-1,
0,
-1,
0,
-1
],
"type": "polynomial"
}
}
}
}

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@@ -265,5 +265,89 @@
"rhoVtriple_units": "mol/m^3"
}
],
"NAME": "n-Heptane"
"NAME": "n-Heptane",
"TRANSPORT": {
"conductivity": {
"BibTeX": "Assael-JPCRD-2013-Heptane",
"critical": {
"GAMMA": 0.0586,
"type": "simplified_Olchowy_Sengers",
"zeta0": 2.45e-10
},
"dilute": {
"A": [
-0.00183367,
0.0162572,
-0.0390996,
0.0478594,
0.0151925,
-0.00339115
],
"B": [
0.250611,
-0.320871,
1
],
"T_reducing": 540.13,
"T_reducing_units": "K",
"m": [
0,
1,
2
],
"n": [
0,
1,
2,
3,
4,
5
],
"type": "ratio_of_polynomials"
},
"residual": {
"B": [
0.0517785,
-0.00772433,
-0.0924052,
0.0218899,
0.0511484,
0.00171725,
-0.00776896,
-0.00791642,
0.000121637,
0.00183379
],
"T_reducing": 540.13,
"T_reducing_units": "K",
"d": [
1,
1,
2,
2,
3,
3,
4,
4,
5,
5
],
"rhomass_reducing": 232,
"rhomass_reducing_units": "kg/m^3",
"t": [
0,
-1,
0,
-1,
0,
-1,
0,
-1,
0,
-1
],
"type": "polynomial"
}
}
}
}

View File

@@ -253,6 +253,35 @@ vel("Hexane", "T", 400, "Dmass", 2, "L", 23.558e-3, 1e-3),
vel("Hexane", "T", 400, "Dmass", 650, "L", 129.28e-3, 1e-3),
vel("Hexane", "T", 510, "Dmass", 2, "L", 36.772e-3, 1e-3),
// From Assael, JPCRD, 2013
vel("Heptane", "T", 250, "Dmass", 720, "L", 137.09e-3, 1e-4),
vel("Heptane", "T", 400, "Dmass", 2, "L", 21.794e-3, 1e-4),
vel("Heptane", "T", 400, "Dmass", 650, "L", 120.75e-3, 1e-4),
vel("Heptane", "T", 535, "Dmass", 100, "L", 51.655e-3, 1e-4),
// From Assael, JPCRD, 2013
vel("Ethanol", "T", 300, "Dmass", 850, "L", 209.68e-3, 1e-4),
vel("Ethanol", "T", 400, "Dmass", 2, "L", 26.108e-3, 1e-4),
vel("Ethanol", "T", 400, "Dmass", 690, "L", 149.21e-3, 1e-4),
vel("Ethanol", "T", 500, "Dmass", 10, "L", 39.594e-3, 1e-4),
// From Assael, JPCRD, 2012
vel("Toluene", "T", 298.15, "Dmass", 1e-15, "L", 10.749e-3, 1e-4),
vel("Toluene", "T", 298.15, "Dmass", 862.948, "L", 130.66e-3, 1e-4),
vel("Toluene", "T", 298.15, "Dmass", 876.804, "L", 136.70e-3, 1e-4),
vel("Toluene", "T", 595, "Dmass", 1e-15, "L", 40.538e-3, 1e-4),
vel("Toluene", "T", 595, "Dmass", 46.512, "L", 41.549e-3, 1e-4),
vel("Toluene", "T", 185, "Dmass", 1e-15, "L", 4.3758e-3, 1e-4),
vel("Toluene", "T", 185, "Dmass", 968.821, "L", 158.24e-3, 1e-4),
// From Assael, JPCRD, 2012
vel("SF6", "T", 298.15, "Dmass", 1e-15, "L", 12.952e-3, 1e-4),
vel("SF6", "T", 298.15, "Dmass", 100, "L", 14.127e-3, 1e-4),
vel("SF6", "T", 298.15, "Dmass", 1600, "L", 70.747e-3, 1e-4),
vel("SF6", "T", 310, "Dmass", 1e-15, "L", 13.834e-3, 1e-4),
vel("SF6", "T", 310, "Dmass", 1200, "L", 49.173e-3, 1e-4),
vel("SF6", "T", 480, "Dmass", 100, "L", 28.863e-3, 1e-4),
};
TEST_CASE_METHOD(TransportValidationFixture, "Compare thermal conductivities against published data", "[conductivity]")