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a72baafc77
* Add fluid files with superancillary data * Delete the large generated z-compressed header
4364 lines
131 KiB
JSON
4364 lines
131 KiB
JSON
{
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"ANCILLARIES": {
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"hL": {
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"A": [
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-65886.25523881183,
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194.0272776001964,
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0.7619004200926986,
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2.9757036006712477e-05,
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8.837545054249725e-11,
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-4.7077914022462224e-14
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"B": [
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1,
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],
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"Tmax": 425.025,
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"Tmin": 134.895,
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 313.9350446757544,
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"max_abs_error_units": "J/mol",
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"type": "rational_polynomial"
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},
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"hLV": {
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30831.114176364186,
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35.211964538156124,
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-2.2698131426900754,
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0.017557134029768152,
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1.7183052216652222e-07,
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1.191139086554405e-13
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],
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1,
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],
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"Tmax": 425.025,
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"Tmin": 134.895,
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"_note": "coefficients are in increasing order; input in K, output in J/mol; value is enthalpy minus hs_anchor enthalpy",
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"max_abs_error": 731.0648141534498,
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"max_abs_error_units": "J/mol",
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"type": "rational_polynomial"
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},
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"melting_line": {
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"BibTeX": "Buecker-JPCRD-2006B",
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"T_m": 135.23,
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"parts": [
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{
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"T_0": 134.895,
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"T_max": 163.9,
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"a": [
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558558236.4
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],
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"p_0": 0.653,
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"t": [
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2.206
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]
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}
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],
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"type": "polynomial_in_Tr"
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},
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"pS": {
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"T_r": 425.125,
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"Tmax": 425.124999999999,
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"description": "p'' = pc*exp(Tc/T*sum(n_i*theta^t_i))",
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0.06986482880463143,
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1.8437119133933968,
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-3.735372218319482
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"t": [
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0.743,
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0.984,
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1.886,
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2.16,
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3.286,
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4.231
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],
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"type": "pV",
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"using_tau_r": true
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},
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"rhoL": {
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"T_r": 425.125,
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"description": "rho' = rhoc*(1+sum(n_i*theta^t_i))",
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0.917,
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1.387,
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9.328,
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12.623
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],
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"type": "rhoLnoexp",
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"using_tau_r": false
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},
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"rhoV": {
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"T_r": 425.125,
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"Tmin": 134.895,
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"description": "rho'' = rhoc*exp(Tc/T*sum(n_i*theta^t_i))",
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0.448,
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1.717,
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4.443,
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7.472,
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13.095,
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14.725
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],
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"type": "rhoV",
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"using_tau_r": true
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},
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"sL": {
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"A": [
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-394.45158130058115,
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3.745969942993724,
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-0.020681251182508388,
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8.035751584028468e-05,
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3.2043400294816624e-10,
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-2.78365383538841e-13,
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1.0119011053673634e-16
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"B": [
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1,
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],
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"Tmax": 425.025,
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"Tmin": 134.895,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 0.7814542951677019,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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},
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"sLV": {
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1077.4588425840732,
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0.13927406559298747,
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2.0373227599813097e-06,
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-3.7624686405491725e-09,
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3.891129574032099e-12,
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-1.7257506057343991e-15
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"B": [
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1,
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"Tmax": 425.025,
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"Tmin": 134.895,
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"_note": "coefficients are in increasing order; input in K, output in J/mol/K; value is entropy minus hs_anchor entropy",
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"max_abs_error": 2.253246071558979,
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"max_abs_error_units": "J/mol/K",
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"type": "rational_polynomial"
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},
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"surface_tension": {
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"BibTeX": "Mulero-JPCRD-2012",
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"Tc": 425.125,
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"a": [
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0.05138
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],
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"description": "sigma = sum(a_i*(1-T/Tc)^n_i)",
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"n": [
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1.209
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]
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}
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},
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"EOS": [
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{
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"BibTeX_CP0": "",
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"BibTeX_EOS": "Buecker-JPCRD-2006B",
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"STATES": {
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"hs_anchor": {
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"T": 467.63750000000005,
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"T_units": "K",
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"hmolar": 47861.671413925265,
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"p": 6189994.483731955,
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},
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"reducing": {
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"T": 425.125,
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"T_units": "K",
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"hmolar": 40337.78928854941,
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"p": 3796000,
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"smolar": 137.36140769025366,
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},
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"sat_min_liquid": {
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"T_units": "K",
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"p": 0.6656582208078881,
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},
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"sat_min_vapor": {
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}
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},
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"T_max": 575,
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"Ttriple": 134.895,
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"acentric": 0.200810094644,
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"acentric_units": "-",
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"alpha0": [
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{
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"type": "IdealGasHelmholtzLead"
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{
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"a": 3.24680487,
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},
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{
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5.54913289,
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11.4648996,
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7.59987584,
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"t": [
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],
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"type": "IdealGasHelmholtzPlanckEinstein"
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{
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"a1": -17.9737888338978,
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"reference": "IIR",
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"type": "IdealGasHelmholtzEnthalpyEntropyOffset"
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}
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"alphar": [
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8,
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3,
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5,
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5,
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10,
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2,
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6
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3
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1.5,
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1.5,
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6,
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13
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"type": "ResidualHelmholtzPower"
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},
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{
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"beta": [
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200
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],
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"d": [
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1,
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2
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],
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"epsilon": [
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0.85,
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1
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],
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"eta": [
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10,
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10
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"gamma": [
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1.16,
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1.13
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"n": [
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0.0014904666224681
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"type": "ResidualHelmholtzGaussian"
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}
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"critical_region_splines": {
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"T_max": 425.125,
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"T_min": 425.12491360192047,
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"_note": "Coefficients for the critical cubic spline. T = c[0]*rho^3 + c[1]*rho^2 + c[2]*rho + c[3] with rho in mol/m^3 and T in K",
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"cL": [
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0.0,
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0.0,
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-5.692661766826853e-06,
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425.1473310005959
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"cV": [
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0.0,
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0.0,
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8.526909313167263e-06,
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425.0915508992536
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],
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"rhomolar_max": 3937.946709931644,
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"rhomolar_min": 3912.637210218117
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},
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"gas_constant": 8.314472,
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"gas_constant_units": "J/mol/K",
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"molar_mass": 0.0581222,
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"molar_mass_units": "kg/mol",
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"p_max": 12000000,
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"p_max_units": "Pa",
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"pseudo_pure": false,
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"SUPERANCILLARY": {
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"crit_anc": {
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"Tc / K": 425.125000000008,
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"Theta_min": 0.01,
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"_note": "coefficients are for the function like ln(|rho^A-rhoc|) = sum_i c_i ln(Theta)^i with Theta=(Tc-T)/Tc",
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"cL": [
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7.558651083650868,
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"cV": [
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7.100613592259996,
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9.69071771511066e-07,
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4.7805938938838274e-08
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],
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"rhoc / mol/m^3": 3922.769612988464
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},
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{
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"coef": [
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2.5553516802577847,
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2.36112939466491,
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0.5402157196763141,
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0.07527978425589071,
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0.00690919200782055,
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0.00042494468084906193,
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1.6734110254260704e-05,
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3.3851518307308506e-07,
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1.3750188792600655e-13,
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4.128641872824801e-16
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"xmax": 147.15290353059802,
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{
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0.00017852401122519355,
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3.0699538903873486e-08,
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1.1066714923775953e-10,
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3.3235482524138975e-15,
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4.503524071193456e-15,
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6.38378239159465e-16
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"xmax": 151.2388713741307,
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{
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} |